Organic electroluminescent materials and devices

ABSTRACT

This invention discloses iridium complexes with benzothienoquinoline, benzofuroquinoline, benzoselenophenoquinoline, and benzosiloloquinoline ligands. These complexes can be used as phosphorescent emitters in OLEDs.

CROSS-REFERENCE TO RELATED APPLICATIONS

This application claims priority from U.S. Provisional Patent Application Ser. No. 62/206,325 filed Aug. 18, 2015, the entire contents of which is incorporated herein by reference.

PARTIES TO A JOINT RESEARCH AGREEMENT

The claimed invention was made by, on behalf of, and/or in connection with one or more of the following parties to a joint university corporation research agreement: The Regents of the University of Michigan, Princeton University, University of Southern California, and the Universal Display Corporation. The agreement was in effect on and before the date the claimed invention was made, and the claimed invention was made as a result of activities undertaken within the scope of the agreement.

FIELD

The present invention relates to compounds for use as emitters, and devices, such as organic light emitting diodes, including the same.

BACKGROUND

Opto-electronic devices that make use of organic materials are becoming increasingly desirable for a number of reasons. Many of the materials used to make such devices are relatively inexpensive, so organic opto-electronic devices have the potential for cost advantages over inorganic devices. In addition, the inherent properties of organic materials, such as their flexibility, may make them well suited for particular applications such as fabrication on a flexible substrate. Examples of organic opto-electronic devices include organic light emitting diodes/devices (OLEDs), organic phototransistors, organic photovoltaic cells, and organic photodetectors. For OLEDs, the organic materials may have performance advantages over conventional materials. For example, the wavelength at which an organic emissive layer emits light may generally be readily tuned with appropriate dopants.

OLEDs make use of thin organic films that emit light when voltage is applied across the device. OLEDs are becoming an increasingly interesting technology for use in applications such as flat panel displays, illumination, and backlighting. Several OLED materials and configurations are described in U.S. Pat. Nos. 5,844,363, 6,303,238, and 5,707,745, which are incorporated herein by reference in their entirety.

One application for phosphorescent emissive molecules is a full color display. Industry standards for such a display call for pixels adapted to emit particular colors, referred to as “saturated” colors. In particular, these standards call for saturated red, green, and blue pixels. Alternatively the OLED can be designed to emit white light. In conventional liquid crystal displays emission from a white backlight is filtered using absorption filters to produce red, green and blue emission. The same technique can also be used with OLEDs. The white OLED can be either a single EML device or a stack structure. Color may be measured using CIE coordinates, which are well known to the art.

One example of a green emissive molecule is tris(2-phenylpyridine) iridium, denoted Ir(ppy)₃, which has the following structure:

In this, and later figures herein, we depict the dative bond from nitrogen to metal (here, Ir) as a straight line.

As used herein, the term “organic” includes polymeric materials as well as small molecule organic materials that may be used to fabricate organic opto-electronic devices. “Small molecule” refers to any organic material that is not a polymer, and “small molecules” may actually be quite large. Small molecules may include repeat units in some circumstances. For example, using a long chain alkyl group as a substituent does not remove a molecule from the “small molecule” class. Small molecules may also be incorporated into polymers, for example as a pendent group on a polymer backbone or as a part of the backbone. Small molecules may also serve as the core moiety of a dendrimer, which consists of a series of chemical shells built on the core moiety. The core moiety of a dendrimer may be a fluorescent or phosphorescent small molecule emitter. A dendrimer may be a “small molecule,” and it is believed that all dendrimers currently used in the field of OLEDs are small molecules.

As used herein, “top” means furthest away from the substrate, while “bottom” means closest to the substrate. Where a first layer is described as “disposed over” a second layer, the first layer is disposed further away from substrate. There may be other layers between the first and second layer, unless it is specified that the first layer is “in contact with” the second layer. For example, a cathode may be described as “disposed over” an anode, even though there are various organic layers in between.

As used herein, “solution processible” means capable of being dissolved, dispersed, or transported in and/or deposited from a liquid medium, either in solution or suspension form.

A ligand may be referred to as “photoactive” when it is believed that the ligand directly contributes to the photoactive properties of an emissive material. A ligand may be referred to as “ancillary” when it is believed that the ligand does not contribute to the photoactive properties of an emissive material, although an ancillary ligand may alter the properties of a photoactive ligand.

As used herein, and as would be generally understood by one skilled in the art, a first “Highest Occupied Molecular Orbital” (HOMO) or “Lowest Unoccupied Molecular Orbital” (LUMO) energy level is “greater than” or “higher than” a second HOMO or LUMO energy level if the first energy level is closer to the vacuum energy level. Since ionization potentials (IP) are measured as a negative energy relative to a vacuum level, a higher HOMO energy level corresponds to an IP having a smaller absolute value (an IP that is less negative). Similarly, a higher LUMO energy level corresponds to an electron affinity (EA) having a smaller absolute value (an EA that is less negative). On a conventional energy level diagram, with the vacuum level at the top, the LUMO energy level of a material is higher than the HOMO energy level of the same material. A “higher” HOMO or LUMO energy level appears closer to the top of such a diagram than a “lower” HOMO or LUMO energy level.

As used herein, and as would be generally understood by one skilled in the art, a first work function is “greater than” or “higher than” a second work function if the first work function has a higher absolute value. Because work functions are generally measured as negative numbers relative to vacuum level, this means that a “higher” work function is more negative. On a conventional energy level diagram, with the vacuum level at the top, a “higher” work function is illustrated as further away from the vacuum level in the downward direction. Thus, the definitions of HOMO and LUMO energy levels follow a different convention than work functions.

More details on OLEDs, and the definitions described above, can be found in U.S. Pat. No. 7,279,704, which is incorporated herein by reference in its entirety.

There is a need in the art for novel iridium complexes with benzothienoquinoline, benzofuroquinoline, benzoselenophenoquinoline, and benzosiloloquinoline ligands. This invention fulfils this need.

SUMMARY

In one aspect, the invention relates to a compound of formula M(L_(A))_(x)(L_(B))_(y)(L_(C))_(z),

wherein ligand L_(A) is:

wherein ligand L_(B) is:

wherein ligand L_(C) is:

wherein M is a metal having an atomic number greater than 40;

wherein x is 1, 2, or 3; wherein y is 0, 1, or 2;

wherein z is 0, 1, or 2;

wherein x+y+z is the oxidation state of the metal M;

wherein Y¹ to Y⁶ are carbon or nitrogen;

wherein Y is selected from the group consisting of S, Se, and SiRR′;

wherein rings C and D are each independently a 5 or 6-membered carbocyclic or heterocyclic ring;

wherein R^(A), R^(D), R^(C), and R^(D) each independently represent mono to the maximum possible number of substitution, or no substitution;

wherein each of R^(A), R^(B), R^(C), R^(D), R^(X), R^(Y), and R^(Z) is independently selected from the group consisting of hydrogen, deuterium, halide, alkyl, cycloalkyl, heteroalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carbonyl, carboxylic acids, ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, and combinations thereof; and

wherein any adjacent substituents are optionally joined or fused into a ring.

According to another embodiment, an organic light emitting diode/device (OLED) is also provided. The OLED can include an anode, a cathode, and an organic layer, disposed between the anode and the cathode. The organic layer can include a compound of formula M(L_(A))_(x)(L_(B))_(y)(L_(C))_(z). According to yet another embodiment, the organic light emitting device is incorporated into a device selected from a consumer product, an electronic component module, and/or a lighting panel.

According to another embodiment, the invention provides a formulation comprising a compound of formula M(L_(A))_(x)(L_(B))_(y)(L_(C))_(z).

BRIEF DESCRIPTION OF THE DRAWINGS

FIG. 1 shows an organic light emitting device.

FIG. 2 shows an inverted organic light emitting device that does not have a separate electron transport layer.

DETAILED DESCRIPTION

Generally, an OLED comprises at least one organic layer disposed between and electrically connected to an anode and a cathode. When a current is applied, the anode injects holes and the cathode injects electrons into the organic layer(s). The injected holes and electrons each migrate toward the oppositely charged electrode. When an electron and hole localize on the same molecule, an “exciton,” which is a localized electron-hole pair having an excited energy state, is formed. Light is emitted when the exciton relaxes via a photoemissive mechanism. In some cases, the exciton may be localized on an excimer or an exciplex. Non-radiative mechanisms, such as thermal relaxation, may also occur, but are generally considered undesirable.

The initial OLEDs used emissive molecules that emitted light from their singlet states (“fluorescence”) as disclosed, for example, in U.S. Pat. No. 4,769,292, which is incorporated by reference in its entirety. Fluorescent emission generally occurs in a time frame of less than 10 nanoseconds.

More recently, OLEDs having emissive materials that emit light from triplet states (“phosphorescence”) have been demonstrated. Baldo et al., “Highly Efficient Phosphorescent Emission from Organic Electroluminescent Devices,” Nature, vol. 395, 151-154, 1998; (“Baldo-I”) and Baldo et al., “Very high-efficiency green organic light-emitting devices based on electrophosphorescence,” Appl. Phys. Lett., vol. 75, No. 3, 4-6 (1999) (“Baldo-II”), are incorporated by reference in their entireties. Phosphorescence is described in more detail in U.S. Pat. No. 7,279,704 at cols. 5-6, which are incorporated by reference.

FIG. 1 shows an organic light emitting device 100. The figures are not necessarily drawn to scale. Device 100 may include a substrate 110, an anode 115, a hole injection layer 120, a hole transport layer 125, an electron blocking layer 130, an emissive layer 135, a hole blocking layer 140, an electron transport layer 145, an electron injection layer 150, a protective layer 155, a cathode 160, and a barrier layer 170. Cathode 160 is a compound cathode having a first conductive layer 162 and a second conductive layer 164. Device 100 may be fabricated by depositing the layers described, in order. The properties and functions of these various layers, as well as example materials, are described in more detail in U.S. Pat. No. 7,279,704 at cols. 6-10, which are incorporated by reference.

More examples for each of these layers are available. For example, a flexible and transparent substrate-anode combination is disclosed in U.S. Pat. No. 5,844,363, which is incorporated by reference in its entirety. An example of a p-doped hole transport layer is m-MTDATA doped with F₄-TCNQ at a molar ratio of 50:1, as disclosed in U.S. Patent Application Publication No. 2003/0230980, which is incorporated by reference in its entirety. Examples of emissive and host materials are disclosed in U.S. Pat. No. 6,303,238 to Thompson et al., which is incorporated by reference in its entirety. An example of an n-doped electron transport layer is BPhen doped with Li at a molar ratio of 1:1, as disclosed in U.S. Patent Application Publication No. 2003/0230980, which is incorporated by reference in its entirety. U.S. Pat. Nos. 5,703,436 and 5,707,745, which are incorporated by reference in their entireties, disclose examples of cathodes including compound cathodes having a thin layer of metal such as Mg:Ag with an overlying transparent, electrically-conductive, sputter-deposited ITO layer. The theory and use of blocking layers is described in more detail in U.S. Pat. No. 6,097,147 and U.S. Patent Application Publication No. 2003/0230980, which are incorporated by reference in their entireties. Examples of injection layers are provided in U.S. Patent Application Publication No. 2004/0174116, which is incorporated by reference in its entirety. A description of protective layers may be found in U.S. Patent Application Publication No. 2004/0174116, which is incorporated by reference in its entirety.

FIG. 2 shows an inverted OLED 200. The device includes a substrate 210, a cathode 215, an emissive layer 220, a hole transport layer 225, and an anode 230. Device 200 may be fabricated by depositing the layers described, in order. Because the most common OLED configuration has a cathode disposed over the anode, and device 200 has cathode 215 disposed under anode 230, device 200 may be referred to as an “inverted” OLED. Materials similar to those described with respect to device 100 may be used in the corresponding layers of device 200. FIG. 2 provides one example of how some layers may be omitted from the structure of device 100.

The simple layered structure illustrated in FIGS. 1 and 2 is provided by way of non-limiting example, and it is understood that embodiments of the invention may be used in connection with a wide variety of other structures. The specific materials and structures described are exemplary in nature, and other materials and structures may be used. Functional OLEDs may be achieved by combining the various layers described in different ways, or layers may be omitted entirely, based on design, performance, and cost factors. Other layers not specifically described may also be included. Materials other than those specifically described may be used. Although many of the examples provided herein describe various layers as comprising a single material, it is understood that combinations of materials, such as a mixture of host and dopant, or more generally a mixture, may be used. Also, the layers may have various sublayers. The names given to the various layers herein are not intended to be strictly limiting. For example, in device 200, hole transport layer 225 transports holes and injects holes into emissive layer 220, and may be described as a hole transport layer or a hole injection layer. In one embodiment, an OLED may be described as having an “organic layer” disposed between a cathode and an anode. This organic layer may comprise a single layer, or may further comprise multiple layers of different organic materials as described, for example, with respect to FIGS. 1 and 2.

Structures and materials not specifically described may also be used, such as OLEDs comprised of polymeric materials (PLEDs) such as disclosed in U.S. Pat. No. 5,247,190 to Friend et al., which is incorporated by reference in its entirety. By way of further example, OLEDs having a single organic layer may be used. OLEDs may be stacked, for example as described in U.S. Pat. No. 5,707,745 to Forrest et al, which is incorporated by reference in its entirety. The OLED structure may deviate from the simple layered structure illustrated in FIGS. 1 and 2. For example, the substrate may include an angled reflective surface to improve out-coupling, such as a mesa structure as described in U.S. Pat. No. 6,091,195 to Forrest et al., and/or a pit structure as described in U.S. Pat. No. 5,834,893 to Bulovic et al., which are incorporated by reference in their entireties.

Unless otherwise specified, any of the layers of the various embodiments may be deposited by any suitable method. For the organic layers, preferred methods include thermal evaporation, ink-jet, such as described in U.S. Pat. Nos. 6,013,982 and 6,087,196, which are incorporated by reference in their entireties, organic vapor phase deposition (OVPD), such as described in U.S. Pat. No. 6,337,102 to Forrest et al., which is incorporated by reference in its entirety, and deposition by organic vapor jet printing (OVJP), such as described in U.S. Pat. No. 7,431,968, which is incorporated by reference in its entirety. Other suitable deposition methods include spin coating and other solution based processes. Solution based processes are preferably carried out in nitrogen or an inert atmosphere. For the other layers, preferred methods include thermal evaporation. Preferred patterning methods include deposition through a mask, cold welding such as described in U.S. Pat. Nos. 6,294,398 and 6,468,819, which are incorporated by reference in their entireties, and patterning associated with some of the deposition methods such as ink-jet and OVJD. Other methods may also be used. The materials to be deposited may be modified to make them compatible with a particular deposition method. For example, substituents such as alkyl and aryl groups, branched or unbranched, and preferably containing at least 3 carbons, may be used in small molecules to enhance their ability to undergo solution processing. Substituents having 20 carbons or more may be used, and 3-20 carbons is a preferred range. Materials with asymmetric structures may have better solution processibility than those having symmetric structures, because asymmetric materials may have a lower tendency to recrystallize. Dendrimer substituents may be used to enhance the ability of small molecules to undergo solution processing.

Devices fabricated in accordance with embodiments of the present invention may further optionally comprise a barrier layer. One purpose of the barrier layer is to protect the electrodes and organic layers from damaging exposure to harmful species in the environment including moisture, vapor and/or gases, etc. The barrier layer may be deposited over, under or next to a substrate, an electrode, or over any other parts of a device including an edge. The barrier layer may comprise a single layer, or multiple layers. The barrier layer may be formed by various known chemical vapor deposition techniques and may include compositions having a single phase as well as compositions having multiple phases. Any suitable material or combination of materials may be used for the barrier layer. The barrier layer may incorporate an inorganic or an organic compound or both. The preferred barrier layer comprises a mixture of a polymeric material and a non-polymeric material as described in U.S. Pat. No. 7,968,146, PCT Pat. Application Nos. PCT/US2007/023098 and PCT/US2009/042829, which are herein incorporated by reference in their entireties. To be considered a “mixture”, the aforesaid polymeric and non-polymeric materials comprising the barrier layer should be deposited under the same reaction conditions and/or at the same time. The weight ratio of polymeric to non-polymeric material may be in the range of 95:5 to 5:95. The polymeric material and the non-polymeric material may be created from the same precursor material. In one example, the mixture of a polymeric material and a non-polymeric material consists essentially of polymeric silicon and inorganic silicon.

Devices fabricated in accordance with embodiments of the invention can be incorporated into a wide variety of electronic component modules (or units) that can be incorporated into a variety of electronic products or intermediate components. Examples of such electronic products or intermediate components include display screens, lighting devices such as discrete light source devices or lighting panels, etc. that can be utilized by the end-user product manufacturers. Such electronic component modules can optionally include the driving electronics and/or power source(s). Devices fabricated in accordance with embodiments of the invention can be incorporated into a wide variety of consumer products that have one or more of the electronic component modules (or units) incorporated therein. Such consumer products would include any kind of products that include one or more light source(s) and/or one or more of some type of visual displays. Some examples of such consumer products include flat panel displays, computer monitors, medical monitors, televisions, billboards, lights for interior or exterior illumination and/or signaling, heads-up displays, fully or partially transparent displays, flexible displays, laser printers, telephones, cell phones, tablets, phablets, personal digital assistants (PDAs), wearable device, laptop computers, digital cameras, camcorders, viewfinders, micro-displays, 3-D displays, vehicles, a large area wall, theater or stadium screen, or a sign. Various control mechanisms may be used to control devices fabricated in accordance with the present invention, including passive matrix and active matrix. Many of the devices are intended for use in a temperature range comfortable to humans, such as 18 degrees C. to 30 degrees C., and more preferably at room temperature (20-25 degrees C.), but could be used outside this temperature range, for example, from −40 degree C. to +80 degree C.

The materials and structures described herein may have applications in devices other than OLEDs. For example, other optoelectronic devices such as organic solar cells and organic photodetectors may employ the materials and structures. More generally, organic devices, such as organic transistors, may employ the materials and structures.

The term “halo,” “halogen,” or “halide” as used herein includes fluorine, chlorine, bromine, and iodine.

The term “alkyl” as used herein contemplates both straight and branched chain alkyl radicals. Preferred alkyl groups are those containing from one to fifteen carbon atoms and includes methyl, ethyl, propyl, 1-methylethyl, butyl, 1-methylpropyl, 2-methylpropyl, pentyl, 1-methylbutyl, 2-methylbutyl, 3-methylbutyl, 1,1-dimethylpropyl, 1,2-dimethylpropyl, 2,2-dimethylpropyl, and the like. Additionally, the alkyl group may be optionally substituted.

The term “cycloalkyl” as used herein contemplates cyclic alkyl radicals. Preferred cycloalkyl groups are those containing 3 to 10 ring carbon atoms and includes cyclopropyl, cyclopentyl, cyclohexyl, adamantyl, and the like. Additionally, the cycloalkyl group may be optionally substituted.

The term “alkenyl” as used herein contemplates both straight and branched chain alkene radicals. Preferred alkenyl groups are those containing two to fifteen carbon atoms. Additionally, the alkenyl group may be optionally substituted.

The term “alkynyl” as used herein contemplates both straight and branched chain alkyne radicals. Preferred alkynyl groups are those containing two to fifteen carbon atoms. Additionally, the alkynyl group may be optionally substituted.

The terms “aralkyl” or “arylalkyl” as used herein are used interchangeably and contemplate an alkyl group that has as a substituent an aromatic group. Additionally, the aralkyl group may be optionally substituted.

The term “heterocyclic group” as used herein contemplates aromatic and non-aromatic cyclic radicals. Hetero-aromatic cyclic radicals also means heteroaryl. Preferred hetero-non-aromatic cyclic groups are those containing 3 to 7 ring atoms which includes at least one hetero atom, and includes cyclic amines such as morpholino, piperidino, pyrrolidino, and the like, and cyclic ethers, such as tetrahydrofuran, tetrahydropyran, and the like. Additionally, the heterocyclic group may be optionally substituted.

The term “aryl” or “aromatic group” as used herein contemplates single-ring groups and polycyclic ring systems. The polycyclic rings may have two or more rings in which two carbons are common to two adjoining rings (the rings are “fused”) wherein at least one of the rings is aromatic, e.g., the other rings can be cycloalkyls, cycloalkenyls, aryl, heterocycles, and/or heteroaryls. Preferred aryl groups are those containing six to thirty carbon atoms, preferably six to twenty carbon atoms, more preferably six to twelve carbon atoms. Especially preferred is an aryl group having six carbons, ten carbons or twelve carbons. Suitable aryl groups include phenyl, biphenyl, triphenyl, triphenylene, tetraphenylene, naphthalene, anthracene, phenalene, phenanthrene, fluorene, pyrene, chrysene, perylene, and azulene, preferably phenyl, biphenyl, triphenyl, triphenylene, fluorene, and naphthalene. Additionally, the aryl group may be optionally substituted.

The term “heteroaryl” as used herein contemplates single-ring hetero-aromatic groups that may include from one to five heteroatoms. The term heteroaryl also includes polycyclic hetero-aromatic systems having two or more rings in which two atoms are common to two adjoining rings (the rings are “fused”) wherein at least one of the rings is a heteroaryl, e.g., the other rings can be cycloalkyls, cycloalkenyls, aryl, heterocycles, and/or heteroaryls. Preferred heteroaryl groups are those containing three to thirty carbon atoms, preferably three to twenty carbon atoms, more preferably three to twelve carbon atoms. Suitable heteroaryl groups include dibenzothiophene, dibenzofuran, dibenzoselenophene, furan, thiophene, benzofuran, benzothiophene, benzoselenophene, carbazole, indolocarbazole, pyridylindole, pyrrolodipyridine, pyrazole, imidazole, triazole, oxazole, thiazole, oxadiazole, oxatriazole, dioxazole, thiadiazole, pyridine, pyridazine, pyrimidine, pyrazine, triazine, oxazine, oxathiazine, oxadiazine, indole, benzimidazole, indazole, indoxazine, benzoxazole, benzisoxazole, benzothiazole, quinoline, isoquinoline, cinnoline, quinazoline, quinoxaline, naphthyridine, phthalazine, pteridine, xanthene, acridine, phenazine, phenothiazine, phenoxazine, benzofuropyridine, furodipyridine, benzothienopyridine, thienodipyridine, benzoselenophenopyridine, and selenophenodipyridine, preferably dibenzothiophene, dibenzofuran, dibenzoselenophene, carbazole, indolocarbazole, imidazole, pyridine, triazine, benzimidazole, 1,2-azaborine, 1,3-azaborine, 1,4-azaborine, borazine, and aza-analogs thereof. Additionally, the heteroaryl group may be optionally substituted.

The alkyl, cycloalkyl, alkenyl, alkynyl, aralkyl, heterocyclic group, aryl, and heteroaryl may be unsubstituted or may be substituted with one or more substituents selected from the group consisting of deuterium, halogen, alkyl, cycloalkyl, heteroalkyl, arylalkyl, alkoxy, aryloxy, amino, cyclic amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carbonyl, carboxylic acid, ether, ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, and combinations thereof.

As used herein, “substituted” indicates that a substituent other than H is bonded to the relevant position, such as carbon. Thus, for example, where R¹ is mono-substituted, then one R¹ must be other than H. Similarly, where R¹ is di-substituted, then two of R¹ must be other than H. Similarly, where R¹ is unsubstituted, R¹ is hydrogen for all available positions.

The “aza” designation in the fragments described herein, i.e. aza-dibenzofuran, aza-dibenzothiophene, etc. means that one or more of the C—H groups in the respective fragment can be replaced by a nitrogen atom, for example, and without any limitation, azatriphenylene encompasses both dibenzo[f,h]quinoxaline and dibenzo[f,h]quinoline. One of ordinary skill in the art can readily envision other nitrogen analogs of the aza-derivatives described above, and all such analogs are intended to be encompassed by the terms as set forth herein.

It is to be understood that when a molecular fragment is described as being a substituent or otherwise attached to another moiety, its name may be written as if it were a fragment (e.g. phenyl, phenylene, naphthyl, dibenzofuryl) or as if it were the whole molecule (e.g. benzene, naphthalene, dibenzofuran). As used herein, these different ways of designating a substituent or attached fragment are considered to be equivalent.

Narrow emission spectrum is desirable for RGB display applications because better color purity can be obtained. Emission line shape of iridium containing complexes is determined by the ligand structures that surround the metal center. Rigidifying the ligands, as well as introducing certain substituents at certain positions, can help achieving narrow emission. A series of novel ligands are disclosed herein, containing benzofuroquinoline, benzothienoquinoline, benzoselenophenoquinoline, or benzosiloloquinoline structures. The iridium complexes containing these ligands show narrow emission and high EQE in devices.

Compounds of the Invention

The compounds of the present invention may be synthesized using techniques well-known in the art of organic synthesis. The starting materials and intermediates required for the synthesis may be obtained from commercial sources or synthesized according to methods known to those skilled in the art.

In one aspect, the invention relates to a compound of formula M(L_(A))_(x)(L_(B))_(y)(L_(C))_(z),

wherein ligand L_(A) is:

wherein ligand L_(B) is:

wherein ligand L_(C) is:

wherein M is a metal having an atomic number greater than 40;

wherein x is 1, 2, or 3;

wherein y is 0, 1, or 2;

wherein z is 0, 1, or 2;

wherein x+y+z is the oxidation state of the metal M;

wherein Y¹ to Y⁶ are carbon or nitrogen;

wherein Y is selected from the group consisting of S, Se, and SiRR′;

wherein rings C and D are each independently a 5 or 6-membered carbocyclic or heterocyclic ring;

wherein R^(A), R^(B), R^(C), and R^(D) each independently represent mono to the maximum possible number of substitution, or no substitution;

wherein each of R^(A), R^(B), R^(C), R^(D), R^(X), R^(Y), and R^(Z) is independently selected from the group consisting of hydrogen, deuterium, halide, alkyl, cycloalkyl, heteroalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carbonyl, carboxylic acids, ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, and combinations thereof; and

wherein any adjacent substituents are optionally joined or fused into a ring.

In one embodiment, M is selected from the group consisting of Ir, Rh, Re, Ru, Os, Pt, Au, and Cu. In another embodiment, M is Ir. In one embodiment, the compound has the formula M(L_(A))₂(L_(C)). In another embodiment, the compound has the formula M(L_(A))(L_(B))₂. In one embodiment, Y¹ to Y⁵ are carbon. In another embodiment, only one of Y¹ to Y⁵ is nitrogen.

In one embodiment, ligand L_(C) has the formula:

wherein R¹, R², R³, and R⁴ are independently selected from group consisting of alkyl, cycloalkyl, aryl, and heteroaryl; and wherein at least one of R¹, R², R³, and R⁴ has at least two carbon atoms.

In one embodiment, each of R^(A), R^(B), R^(C), R^(D), R^(X), R^(Y), and R^(Z) are independently selected from the group consisting of hydrogen, deuterium, alkyl, cycloalkyl, and combinations thereof. In another embodiment, R^(Y) is hydrogen. In another embodiment, ring C is benzene, and ring D is pyridine of which Y⁶ is N. In another embodiment, ligand L_(A) is selected from the group consisting of:

In one embodiment, ligand L_(A) of formula:

is selected from the group consisting of L_(A1) to L_(A1728):

Ligand number Y R^(A1) R^(A2) R^(A3) R^(A4) R^(B1) R^(B2) R^(B3) 1. S CH₃ H H H H H H 2. S CH(CH₃)₂ H H H H H H 3. S CH₂CH₃ H H H H H H 4. S CH₂CH(CH₃)₂ H H H H H H 5. S CH₂C(CH₃)₃ H H H H H H 6. S

H H H H H H 7. S CH₂CF₃ H H H H H H 8. S CH₂CH₂CF₃ H H H H H H 9. S CH₂C(CH₃)₂CF₃ H H H H H H 10. S CD₃ H H H H H H 11. S CD(CH₃)₂ H H H H H H 12. S CD₂CH(CH₃)₂ H H H H H H 13. S H CH₃ H H H H H 14. S H CH(CH₃)₂ H H H H H 15. S H CH₂CH₃ H H H H H 16. S H CH₂CH(CH₃)₂ H H H H H 17. S H CH₂C(CH₃)₃ H H H H H 18. S H

H H H H H 19. S H CH₂CF₃ H H H H H 20. S H CH₂CH₂CF₃ H H H H H 21. S H CH₂C(CH₃)₂CF₃ H H H H H 22. S H CD₃ H H H H H 23. S H CD(CH₃)₂ H H H H H 24. S H CD₂CH(CH₃)₂ H H H H H 25. S H H CH₃ H H H H 26. S H H CH(CH₃)₂ H H H H 27. S H H CH₂CH₃ H H H H 28. S H H CH₂CH(CH₃)₂ H H H H 29. S H H CH₂C(CH₃)₃ H H H H 30. S H H

H H H H 31. S H H CH₂CF₃ H H H H 32. S H H CH₂CH₂CF₃ H H H H 33. S H H CH₂C(CH₃)₂CF₃ H H H H 34. S H H CD₃ H H H H 35. S H H CD(CH₃)₂ H H H H 36. S H H CD₂CH(CH₃)₂ H H H H 37. S H H H CH₃ H H H 38. S H H H CH(CH₃)₂ H H H 39. S H H H CH₂CH₃ H H H 40. S H H H CH₂CH(CH₃)₂ H H H 41. S H H H CH₂C(CH₃)₃ H H H 42. S H H H

H H H 43. S H H H CH₂CF₃ H H H 44. S H H H CH₂CH₂CF₃ H H H 45. S H H H CH₂C(CH₃)₂CF₃ H H H 46. S H H H CD₃ H H H 47. S H H H CD(CH₃)₂ H H H 48. S H H H CD₂CH(CH₃)₂ H H H 49. S CH₃ CH₃ H H H H H 50. S CH(CH₃)₂ CH(CH₃)₂ H H H H H 51. S CH₂CH₃ CH₂CH₃ H H H H H 52. S CH₂CH(CH₃)₂ CH₂CH(CH₃)₂ H H H H H 53. S CH₂C(CH₃)₃ CH₂C(CH₃)₃ H H H H H 54. S

H H H H H 55. S CH₂CF₃ CH₂CF₃ H H H H H 56. S CH₂CH₂CF₃ CH₂CH₂CF₃ H H H H H 57. S CH₂C(CH₃)₂CF₃ CH₂C(CH₃)₂CF₃ H H H H H 58. S CD₃ CD₂ H H H H H 59. S CD(CH₃)₂ CD(CH₃)₂ H H H H H 60. S CD₂CH(CH₃)₂ CD₂CH(CH₃)₂ H H H H H 61. S CH₃ H CH₃ H H H H 62. S CH(CH₃)₂ H CH(CH₃)₂ H H H H 63. S CH₂CH₃ H CH₂CH₃ H H H H 64. S CH₂CH(CH₃)₂ H CH₂CH(CH₃)₂ H H H H 65. S CH₂C(CH₃)₃ H CH₂C(CH₃)₃ H H H H 66. S

H

H H H H 67. S CH₂CF₃ H CH₂CF₃ H H H H 68. S CH₂CH₂CF₃ H CH₂CH₂CF₃ H H H H 69. S CH₂C(CH₃)₂CF₃ H CH₂C(CH₃)₂CF₃ H H H H 70. S CD₃ H CD₃ H H H H 71. S CD(CH₃)₂ H CD(CH₃)₂ H H H H 72. S CD₂CH(CH₃)₂ H CD₂CH(CH₃)₂ H H H H 73. S CH₃ H H CH₃ H H H 74. S CH(CH₃)₂ H H CH(CH₃)₂ H H H 75. S CH₂CH₃ H H CH₂CH₃ H H H 76. S CH₂CH(CH₃)₂ H H CH₂CH(CH₃)₂ H H H 77. S CH₂C(CH₃)₃ H H CH₂C(CH₃)₃ H H H 78. S

H H

H H H 79. S CH₂CF₃ H H CH₂CF₃ H H H 80. S CH₂CH₂CF₃ H H CH₂CH₂CF₃ H H H 81. S CH₂C(CH₃)₂CF₃ H H CH₂C(CH₃)₂CF₃ H H H 82. S CD₃ H H CD₃ H H H 83. S CD(CH₃)₂ H H CD(CH₃)₂ H H H 84. S CD₂CH(CH₃)₂ H H CD₂CH(CH₃)₂ H H H 85. S H CH₃ H CH₃ H H H 86. S H CH(CH₃)₂ H CH(CH₃)₂ H H H 87. S H CH₂CH₃ H CH₂CH₃ H H H 88. S H CH₂CH(CH₃)₂ H CH₂CH(CH₃)₂ H H H 89. S H CH₂C(CH₃)₃ H CH₂C(CH₃)₃ H H H 90. S H

H

H H H 91. S H CH₂CF₃ H CH₂CF₃ H H H 92. S H CH₂CH₂CF₃ H CH₂CH₂CF₃ H H H 93. S H CH₂C(CH₃)₂CF₃ H CH₂C(CH₃)₂CF₃ H H H 94. S H CD₃ H CD₃ H H H 95. S H CD(CH₃)₂ H CD(CH₃)₂ H H H 96. S H CD₂CH(CH₃)₂ H CD₂CH(CH₃)₂ H H H 97. S CH₃ H H H CH₃ H H 98. S CH(CH₃)₂ H H H CH₃ H H 99. S CH₂CH₃ H H H CH₃ H H 100. S CH₂CH(CH₃)₂ H H H CH₃ H H 101. S CH₂C(CH₃)₃ H H H CH₃ H H 102. S

H H H CH₃ H H 103. S CH₂CF₃ H H H CH₃ H H 104. S CH₂CH₂CF₃ H H H CH₃ H H 105. S CH₂C(CH₃)₂CF₃ H H H CH₃ H H 106. S CD₃ H H H CH₃ H H 107. S CD(CH₃)₂ H H H CH₃ H H 108. S CD₂CH(CH₃)₂ H H H CH₃ H H 109. S H CH₃ H H CH₃ H H 110. S H CH(CH₃)₂ H H CH₃ H H 111. S H CH₂CH₃ H H CH₃ H H 112. S H CH₂CH(CH₃)₂ H H CH₃ H H 113. S H CH₂C(CH₃)₃ H H CH₃ H H 114. S H

H H CH₃ H H 115. S H CH₂CF₃ H H CH₃ H H 116. S H CH₂CH₂CF₃ H H CH₃ H H 117. S H CH₂C(CH₃)₂CF₃ H H CH₃ H H 118. S H CD₃ H H CH₃ H H 119. S H CD(CH₃)₂ H H CH₃ H H 120. S H CD₂CH(CH₃)₂ H H CH₃ H H 121. S H H CH₃ H CH₃ H H 122. S H H CH(CH₃)₂ H CH₃ H H 123. S H H CH₂CH₃ H CH₃ H H 124. S H H CH₂CH(CH₃)₂ H CH₃ H H 125. S H H CH₂C(CH₃)₃ H CH₃ H H 126. S H H

H CH₃ H H 127. S H H CH₂CF₃ H CH₃ H H 128. S H H CH₂CH₂CF₃ H CH₃ H H 129. S H H CH₂C(CH₃)₂CF₃ H CH₃ H H 130. S H H CD₃ H CH₃ H H 131. S H H CD(CH₃)₂ H CH₃ H H 132. S H H CD₂CH(CH₃)₂ H CH₃ H H 133. S H H H CH₃ CH₃ H H 134. S H H H CH(CH₃)₂ CH₃ H H 135. S H H H CH₂CH₃ CH₃ H H 136. S H H H CH₂CH(CH₃)₂ CH₃ H H 137. S H H H CH₂C(CH₃)₃ CH₃ H H 138. S H H H

CH₃ H H 139. S H H H CH₂CF₃ CH₃ H H 140. S H H H CH₂CH₂CF₃ CH₃ H H 141. S H H H CH₂C(CH₃)₂CF₃ CH₃ H H 142. S H H H CD₃ CH₃ H H 143. S H H H CD(CH₃)₂ CH₃ H H 144. S H H H CD₂CH(CH₃)₂ CH₃ H H 145. S CH₃ CH₃ H H CH₃ H H 146. S CH(CH₃)₂ CH(CH₃)₂ H H CH₃ H H 147. S CH₂CH₃ CH₂CH₃ H H CH₃ H H 148. S CH₂CH(CH₃)₂ CH₂CH(CH₃)₂ H H CH₃ H H 149. S CH₂C(CH₃)₃ CH₂C(CH₃)₃ H H CH₃ H H 150. S

H H CH₃ H H 151. S CH₂CF₃ CH₂CF₃ H H CH₃ H H 152. S CH₂CH₂CF₃ CH₂CH₂CF₃ H H CH₃ H H 153. S CH₂C(CH₃)₂CF₃ CH₂C(CH₃)₂CF₃ H H CH₃ H H 154. S CD₃ CD₃ H H CH₃ H H 155. S CD(CH₃)₂ CD(CH₃)₂ H H CH₃ H H 156. S CD₂CH(CH₃)₂ CD₂CH(CH₃)₂ H H CH₃ H H 157. S CH₃ H CH₃ H CH₃ H H 158. S CH(CH₃)₂ H CH(CH₃)₂ H CH₃ H H 159. S CH₂CH₃ H CH₂CH₃ H CH₃ H H 160. S CH₂CH(CH₃)₂ H CH₂CH(CH₃)₂ H CH₃ H H 161. S CH₂C(CH₃)₃ H CH₂C(CH₃)₃ H CH₃ H H 162. S

H

H CH₃ H H 163. S CH₂CF₃ H CH₂CF₃ H CH₃ H H 164. S CH₂CH₂CF₃ H CH₂CH₂CF₃ H CH₃ H H 165. S CH₂C(CH₃)₂CF₃ H CH₂C(CH₃)₂CF₃ H CH₃ H H 166. S CD₃ H CD₃ H CH₃ H H 167. S CD(CH₃)₂ H CD(CH₃)₂ H CH₃ H H 168. S CD₂CH(CH₃)₂ H CD₂CH(CH₃)₂ H CH₃ H H 169. S CH₃ H H CH₃ CH₃ H H 170. S CH(CH₃)₂ H H CH(CH₃)₂ CH₃ H H 171. S CH₂CH₃ H H CH₂CH₃ CH₃ H H 172. S CH₂CH(CH₃)₂ H H CH₂CH(CH₃)₂ CH₃ H H 173. S CH₂C(CH₃)₃ H H CH₂C(CH₃)₃ CH₃ H H 174. S

H H

CH₃ H H 175. S CH₂CF₃ H H CH₂CF₃ CH₃ H H 176. S CH₂CH₂CF₃ H H CH₂CH₂CF₃ CH₃ H H 177. S CH₂C(CH₃)₂CF₃ H H CH₂C(CH₃)₂CF₃ CH₃ H H 178. S CD₃ H H CD₃ CH₃ H H 179. S CD(CH₃)₂ H H CD(CH₃)₂ CH₃ H H 180. S CD₂CH(CH₃)₂ H H CD₂CH(CH₃)₂ CH₃ H H 181. S H CH₃ H CH₃ CH₃ H H 182. S H CH(CH₃)₂ H CH(CH₃)₂ CH₃ H H 183. S H CH₂CH₃ H CH₂CH₃ CH₃ H H 184. S H CH₂CH(CH₃)₂ H CH₂CH(CH₃)₂ CH₃ H H 185. S H CH₂C(CH₃)₃ H CH₂C(CH₃)₃ CH₃ H H 186. S H

H

CH₃ H H 187. S H CH₂CF₃ H CH₂CF₃ CH₃ H H 188. S H CH₂CH₂CF₃ H CH₂CH₂CF₃ CH₃ H H 189. S H CH₂C(CH₃)₂CF₃ H CH₂C(CH₃)₂CF₃ CH₃ H H 190. S H CD₃ H CD₃ CH₃ H H 191. S H CD(CH₃)₂ H CD(CH₃)₂ CH₃ H H 192. S H CD₂CH(CH₃)₂ H CD₂CH(CH₃)₂ CH₃ H H 193. S CH₃ H H H H H CH₃ 194. S CH(CH₃)₂ H H H H H CH₃ 195. S CH₂CH₃ H H H H H CH₃ 196. S CH₂CH(CH₃)₂ H H H H H CH₃ 197. S CH₂C(CH₃)₃ H H H H H CH₃ 198. S

H H H H H CH₃ 199. S CH₂CF₃ H H H H H CH₃ 200. S CH₂CH₂CF₃ H H H H H CH₃ 201. S CH₂C(CH₃)₂CF₃ H H H H H CH₃ 202. S CD₃ H H H H H CH₃ 203. S CD(CH₃)₂ H H H H H CH₃ 204. S CD₂CH(CH₃)₂ H H H H H CH₃ 205. S H CH₃ H H H H CH₃ 206. S H CH(CH₃)₂ H H H H CH₃ 207. S H CH₂CH₃ H H H H CH₃ 208. S H CH₂CH(CH₃)₂ H H H H CH₃ 209. S H CH₂C(CH₃)₃ H H H H CH₃ 210. S H

H H H H CH₃ 211. S H CH₂CF₃ H H H H CH₃ 212. S H CH₂CH₂CF₃ H H H H CH₃ 213. S H CH₂C(CH₃)₂CF₃ H H H H CH₃ 214. S H CD₃ H H H H CH₃ 215. S H CD(CH₃)₂ H H H H CH₃ 216. S H CD₂CH(CH₃)₂ H H H H CH₃ 217. S H H CH₃ H H H CH₃ 218. S H H CH(CH₃)₂ H H H CH₃ 219. S H H CH₂CH₃ H H H CH₃ 220. S H H CH₂CH(CH₃)₂ H H H CH₃ 221. S H H CH₂C(CH₃)₃ H H H CH₃ 222. S H H

H H H CH₃ 223. S H H CH₂CF₃ H H H CH₃ 224. S H H CH₂CH₂CF₃ H H H CH₃ 225. S H H CH₂C(CH₃)₂CF₃ H H H CH₃ 226. S H H CD₃ H H H CH₃ 227. S H H CD(CH₃)₂ H H H CH₃ 228. S H H CD₂CH(CH₃)₂ H H H CH₃ 229. S H H H CH₃ H H CH₃ 230. S H H H CH(CH₃)₂ H H CH₃ 231. S H H H CH₂CH₃ H H CH₃ 232. S H H H CH₂CH(CH₃)₂ H H CH₃ 233. S H H H CH₂C(CH₃)₃ H H CH₃ 234. S H H H

H H CH₃ 235. S H H H CH₂CF₃ H H CH₃ 236. S H H H CH₂CH₂CF₃ H H CH₃ 237. S H H H CH₂C(CH₃)₂CF₃ H H CH₃ 238. S H H H CD₃ H H CH₃ 239. S H H H CD(CH₃)₂ H H CH₃ 240. S H H H CD₂CH(CH₃)₂ H H CH₃ 241. S CH₃ CH₃ H H H H CH₃ 242. S CH(CH₃)₂ CH(CH₃)₂ H H H H CH₃ 243. S CH₂CH₃ CH₂CH₃ H H H H CH₃ 244. S CH₂CH(CH₃)₂ CH₂CH(CH₃)₂ H H H H CH₃ 245. S CH₂C(CH₃)₃ CH₂C(CH₃)₃ H H H H CH₃ 246. S

H H H H CH₃ 247. S CH₂CF₃ CH₂CF₃ H H H H CH₃ 248. S CH₂CH₂CF₃ CH₂CH₂CF₃ H H H H CH₃ 249. S CH₂C(CH₃)₂CF₃ CH₂C(CH₃)₂CF₃ H H H H CH₃ 250. S CD₃ CD₃ H H H H CH₃ 251. S CD(CH₃)₂ CD(CH₃)₂ H H H H CH₃ 252. S CD₂CH(CH₃)₂ CD₂CH(CH₃)₂ H H H H CH₃ 253. S CH₃ H CH₃ H H H CH₃ 254. S CH(CH₃)₂ H CH(CH₃)₂ H H H CH₃ 255. S CH₂CH₃ H CH₂CH₃ H H H CH₃ 256. S CH₂CH(CH₃)₂ H CH₂CH(CH₃)₂ H H H CH₃ 257. S CH₂C(CH₃)₃ H CH₂C(CH₃)₃ H H H CH₃ 258. S

H

H H H CH₃ 259. S CH₂CF₃ H CH₂CF₃ H H H CH₃ 260. S CH₂CH₂CF₃ H CH₂CH₂CF₃ H H H CH₃ 261. S CH₂C(CH₃)₂CF₃ H CH₂C(CH₃)₂CF₃ H H H CH₃ 262. S CD₃ H CD₃ H H H CH₃ 263. S CD(CH₃)₂ H CD(CH₃)₂ H H H CH₃ 264. S CD₂CH(CH₃)₂ H CD₂CH(CH₃)₂ H H H CH₃ 265. S CH₃ H H CH₃ H H CH₃ 266. S CH(CH₃)₂ H H CH(CH₃)₂ H H CH₃ 267. S CH₂CH₃ H H CH₂CH₃ H H CH₃ 268. S CH₂CH(CH₃)₂ H H CH₂CH(CH₃)₂ H H CH₃ 269. S CH₂C(CH₃)₃ H H CH₂C(CH₃)₃ H H CH₃ 270. S

H H

H H CH₃ 271. S CH₂CF₃ H H CH₂CF₃ H H CH₃ 272. S CH₂CH₂CF₃ H H CH₂CH₂CF₃ H H CH₃ 273. S CH₂C(CH₃)₂CF₃ H H CH₂C(CH₃)₂CF₃ H H CH₃ 274. S CD₃ H H CD₃ H H CH₃ 275. S CD(CH₃)₂ H H CD(CH₃)₂ H H CH₃ 276. S CD₂CH(CH₃)₂ H H CD₂CH(CH₃)₂ H H CH₃ 277. S H CH₃ H CH₃ H H CH₃ 278. S H CH(CH₃)₂ H CH(CH₃)₂ H H CH₃ 279. S H CH₂CH₃ H CH₂CH₃ H H CH₃ 280. S H CH₂CH(CH₃)₂ H CH₂CH(CH₃)₂ H H CH₃ 281. S H CH₂C(CH₃)₃ H CH₂C(CH₃)₃ H H CH₃ 282. S H

H

H H CH₃ 283. S H CH₂CF₃ H CH₂CF₃ H H CH₃ 284. S H CH₂CH₂CF₃ H CH₂CH₂CF₃ H H CH₃ 285. S H CH₂C(CH₃)₂CF₃ H CH₂C(CH₃)₂CF₃ H H CH₃ 286. S H CD₃ H CD₃ H H CH₃ 287. S H CD(CH₃)₂ H CD(CH₃)₂ H H CH₃ 288. S H CD₂CH(CH₃)₂ H CD₂CH(CH₃)₂ H H CH₃ 289. S CH₃ H H H CH₃ H CH₃ 290. S CH(CH₃)₂ H H H CH₃ H CH₃ 291. S CH₂CH₃ H H H CH₃ H CH₃ 292. S CH₂CH(CH₃)₂ H H H CH₃ H CH₃ 293. S CH₂C(CH₃)₃ H H H CH₃ H CH₃ 294. S

H H H CH₃ H CH₃ 295. S CH₂CF₃ H H H CH₃ H CH₃ 296. S CH₂CH₂CF₃ H H H CH₃ H CH₃ 297. S CH₂C(CH₃)₂CF₃ H H H CH₃ H CH₃ 298. S CD₃ H H H CH₃ H CH₃ 299. S CD(CH₃)₂ H H H CH₃ H CH₃ 300. S CD₂CH(CH₃)₂ H H H CH₃ H CH₃ 301. S H CH₃ H H CH₃ H CH₃ 302. S H CH(CH₃)₂ H H CH₃ H CH₃ 303. S H CH₂CH₃ H H CH₃ H CH₃ 304. S H CH₂CH(CH₃)₂ H H CH₃ H CH₃ 305. S H CH₂C(CH₃)₃ H H CH₃ H CH₃ 306. S H

H H CH₃ H CH₃ 307. S H CH₂CF₃ H H CH₃ H CH₃ 308. S H CH₂CH₂CF₃ H H CH₃ H CH₃ 309. S H CH₂C(CH₃)₂CF₃ H H CH₃ H CH₃ 310. S H CD₃ H H CH₃ H CH₃ 311. S H CD(CH₃)₂ H H CH₃ H CH₃ 312. S H CD₂CH(CH₃)₂ H H CH₃ H CH₃ 313. S H H CH₃ H CH₃ H CH₃ 314. S H H CH(CH₃)₂ H CH₃ H CH₃ 315. S H H CH₂CH₃ H CH₃ H CH₃ 316. S H H CH₂CH(CH₃)₂ H CH₃ H CH₃ 317. S H H CH₂C(CH₃)₃ H CH₃ H CH₃ 318. S H H

H CH₃ H CH₃ 319. S H H CH₂CF₃ H CH₃ H CH₃ 320. S H H CH₂CH₂CF₃ H CH₃ H CH₃ 321. S H H CH₂C(CH₃)₂CF₃ H CH₃ H CH₃ 322. S H H CD₃ H CH₃ H CH₃ 323. S H H CD(CH₃)₂ H CH₃ H CH₃ 324. S H H CD₂CH(CH₃)₂ H CH₃ H CH₃ 325. S H H H CH₃ CH₃ H CH₃ 326. S H H H CH(CH₃)₂ CH₃ H CH₃ 327. S H H H CH₂CH₃ CH₃ H CH₃ 328. S H H H CH₂CH(CH₃)₂ CH₃ H CH₃ 329. S H H H CH₂C(CH₃)₃ CH₃ H CH₃ 330. S H H H

CH₃ H CH₃ 331. S H H H CH₂CF₃ CH₃ H CH₃ 332. S H H H CH₂CH₂CF₃ CH₃ H CH₃ 333. S H H H CH₂C(CH₃)₂CF₃ CH₃ H CH₃ 334. S H H H CD₃ CH₃ H CH₃ 335. S H H H CD(CH₃)₂ CH₃ H CH₃ 336. S H H H CD₂CH(CH₃)₂ CH₃ H CH₃ 337. S CH₃ CH₃ H H CH₃ H CH₃ 338. S CH(CH₃)₂ CH(CH₃)₂ H H CH₃ H CH₃ 339. S CH₂CH₃ CH₂CH₃ H H CH₃ H CH₃ 340. S CH₂CH(CH₃)₂ CH₂CH(CH₃)₂ H H CH₃ H CH₃ 341. S CH₂C(CH₃)₃ CH₂C(CH₃)₃ H H CH₃ H CH₃ 342. S

H H CH₃ H CH₃ 343. S CH₂CF₃ CH₂CF₃ H H CH₃ H CH₃ 344. S CH₂CH₂CF₃ CH₂CH₂CF₃ H H CH₃ H CH₃ 345. S CH₂C(CH₃)₂CF₃ CH₂C(CH₃)₂CF₃ H H CH₃ H CH₃ 346. S CD₃ CD₃ H H CH₃ H CH₃ 347. S CD(CH₃)₂ CD(CH₃)₂ H H CH₃ H CH₃ 348. S CD₂CH(CH₃)₂ CD₂CH(CH₃)₂ H H CH₃ H CH₃ 349. S CH₃ H CH₃ H CH₃ H CH₃ 350. S CH(CH₃)₂ H CH(CH₃)₂ H CH₃ H CH₃ 351. S CH₂CH₃ H CH₂CH₃ H CH₃ H CH₃ 352. S CH₂CH(CH₃)₂ H CH₂CH(CH₃)₂ H CH₃ H CH₃ 353. S CH₂C(CH₃)₃ H CH₂C(CH₃)₃ H CH₃ H CH₃ 354. S

H

H CH₃ H CH₃ 355. S CH₂CF₃ H CH₂CF₃ H CH₃ H CH₃ 356. S CH₂CH₂CF₃ H CH₂CH₂CF₃ H CH₃ H CH₃ 357. S CH₂C(CH₃)₂CF₃ H CH₂C(CH₃)₂CF₃ H CH₃ H CH₃ 358. S CD₃ H CD₃ H CH₃ H CH₃ 359. S CD(CH₃)₂ H CD(CH₃)₂ H CH₃ H CH₃ 360. S CD₂CH(CH₃)₂ H CD₂CH(CH₃)₂ H CH₃ H CH₃ 361. S CH₃ H H CH₃ CH₃ H CH₃ 362. S CH(CH₃)₂ H H CH(CH₃)₂ CH₃ H CH₃ 363. S CH₂CH₃ H H CH₂CH₃ CH₃ H CH₃ 364. S CH₂CH(CH₃)₂ H H CH₂CH(CH₃)₂ CH₃ H CH₃ 365. S CH₂C(CH₃)₃ H H CH₂C(CH₃)₃ CH₃ H CH₃ 366. S

H H

CH₃ H CH₃ 367. S CH₂CF₃ H H CH₂CF₃ CH₃ H CH₃ 368. S CH₂CH₂CF₃ H H CH₂CH₂CF₃ CH₃ H CH₃ 369. S CH₂C(CH₃)₂CF₃ H H CH₂C(CH₃)₂CF₃ CH₃ H CH₃ 370. S CD₃ H H CD₃ CH₃ H CH₃ 371. S CD(CH₃)₂ H H CD(CH₃)₂ CH₃ H CH₃ 372. S CD₂CH(CH₃)₂ H H CD₂CH(CH₃)₂ CH₃ H CH₃ 373. S H CH₃ H CH₃ CH₃ H CH₃ 374. S H CH(CH₃)₂ H CH(CH₃)₂ CH₃ H CH₃ 375. S H CH₂CH₃ H CH₂CH₃ CH₃ H CH₃ 376. S H CH₂CH(CH₃)₂ H CH₂CH(CH₃)₂ CH₃ H CH₃ 377. S H CH₂C(CH₃)₃ H CH₂C(CH₃)₃ CH₃ H CH₃ 378. S H

H

CH₃ H CH₃ 379. S H CH₂CF₃ H CH₂CF₃ CH₃ H CH₃ 380. S H CH₂CH₂CF₃ H CH₂CH₂CF₃ CH₃ H CH₃ 381. S H CH₂C(CH₃)₂CF₃ H CH₂C(CH₃)₂CF₃ CH₃ H CH₃ 382. S H CD₃ H CD₃ CH₃ H CH₃ 383. S H CD(CH₃)₂ H CD(CH₃)₂ CH₃ H CH₃ 384. S H CD₂CH(CH₃)₂ H CD₂CH(CH₃)₂ CH₃ H CH₃ 385. S CH₃ H H H CH₃ F CH₃ 386. S CH(CH₃)₂ H H H CH₃ F CH₃ 387. S CH₂CH₃ H H H CH₃ F CH₃ 388. S CH₂CH(CH₃)₂ H H H CH₃ F CH₃ 389. S CH₂C(CH₃)₃ H H H CH₃ F CH₃ 390. S

H H H CH₃ F CH₃ 391. S CH₂CF₃ H H H CH₃ F CH₃ 392. S CH₂CH₂CF₃ H H H CH₃ F CH₃ 393. S CH₂C(CH₃)₂CF₃ H H H CH₃ F CH₃ 394. S CD₃ H H H CH₃ F CH₃ 395. S CD(CH₃)₂ H H H CH₃ F CH₃ 396. S CD₂CH(CH₃)₂ H H H CH₃ F CH₃ 397. S H CH₃ H H CH₃ F CH₃ 398. S H CH(CH₃)₂ H H CH₃ F CH₃ 399. S H CH₂CH₃ H H CH₃ F CH₃ 400. S H CH₂CH(CH₃)₂ H H CH₃ F CH₃ 401. S H CH₂C(CH₃)₃ H H CH₃ F CH₃ 402. S H

H H CH₃ F CH₃ 403. S H CH₂CF₃ H H CH₃ F CH₃ 404. S H CH₂CH₂CF₃ H H CH₃ F CH₃ 405. S H CH₂C(CH₃)₂CF₃ H H CH₃ F CH₃ 406. S H CD₃ H H CH₃ F CH₃ 407. S H CD(CH₃)₂ H H CH₃ F CH₃ 408. S H CD₂CH(CH₃)₂ H H CH₃ F CH₃ 409. S H H CH₃ H CH₃ F CH₃ 410. S H H CH(CH₃)₂ H CH₃ F CH₃ 411. S H H CH₂CH₃ H CH₃ F CH₃ 412. S H H CH₂CH(CH₃)₂ H CH₃ F CH₃ 413. S H H CH₂C(CH₃)₃ H CH₃ F CH₃ 414. S H H

H CH₃ F CH₃ 415. S H H CH₂CF₃ H CH₃ F CH₃ 416. S H H CH₂CH₂CF₃ H CH₃ F CH₃ 417. S H H CH₂C(CH₃)₂CF₃ H CH₃ F CH₃ 418. S H H CD₃ H CH₃ F CH₃ 419. S H H CD(CH₃)₂ H CH₃ F CH₃ 420. S H H CD₂CH(CH₃)₂ H CH₃ F CH₃ 421. S H H H CH₃ CH₃ F CH₃ 422. S H H H CH(CH₃)₂ CH₃ F CH₃ 423. S H H H CH₂CH₃ CH₃ F CH₃ 424. S H H H CH₂CH(CH₃)₂ CH₃ F CH₃ 425. S H H H CH₂C(CH₃)₃ CH₃ F CH₃ 426. S H H H

CH₃ F CH₃ 427. S H H H CH₂CF₃ CH₃ F CH₃ 428. S H H H CH₂CH₂CF₃ CH₃ F CH₃ 429. S H H H CH₂C(CH₃)₂CF₃ CH₃ F CH₃ 430. S H H H CD₃ CH₃ F CH₃ 431. S H H H CD(CH₃)₂ CH₃ F CH₃ 432. S H H H CD₂CH(CH₃)₂ CH₃ F CH₃ 433. S CH₃ CH₃ H H CH₃ F CH₃ 434. S CH(CH₃)₂ CH(CH₃)₂ H H CH₃ F CH₃ 435. S CH₂CH₃ CH₂CH₃ H H CH₃ F CH₃ 436. S CH₂CH(CH₃)₂ CH₂CH(CH₃)₂ H H CH₃ F CH₃ 437. S CH₂C(CH₃)₃ CH₂C(CH₃)₃ H H CH₃ F CH₃ 438. S

H H CH₃ F CH₃ 439. S CH₂CF₃ CH₂CF₃ H H CH₃ F CH₃ 440. S CH₂CH₂CF₃ CH₂CH₂CF₃ H H CH₃ F CH₃ 441. S CH₂C(CH₃)₂CF₃ CH₂C(CH₃)₂CF₃ H H CH₃ F CH₃ 442. S CD₃ CD₃ H H CH₃ F CH₃ 443. S CD(CH₃)₂ CD(CH₃)₂ H H CH₃ F CH₃ 444. S CD₂CH(CH₃)₂ CD₂CH(CH₃)₂ H H CH₃ F CH₃ 445. S CH₃ H CH₃ H CH₃ F CH₃ 446. S CH(CH₃)₂ H CH(CH₃)₂ H CH₃ F CH₃ 447. S CH₂CH₃ H CH₂CH₃ H CH₃ F CH₃ 448. S CH₂CH(CH₃)₂ H CH₂CH(CH₃)₂ H CH₃ F CH₃ 449. S CH₂C(CH₃)₃ H CH₂C(CH₃)₃ H CH₃ F CH₃ 450. S

H

H CH₃ F CH₃ 451. S CH₂CF₃ H CH₂CF₃ H CH₃ F CH₃ 452. S CH₂CH₂CF₃ H CH₂CH₂CF₃ H CH₃ F CH₃ 453. S CH₂C(CH₃)₂CF₃ H CH₂C(CH₃)₂CF₃ H CH₃ F CH₃ 454. S CD₃ H CD₃ H CH₃ F CH₃ 455. S CD(CH₃)₂ H CD(CH₃)₂ H CH₃ F CH₃ 456. S CD₂CH(CH₃)₂ H CD₂CH(CH₃)₂ H CH₃ F CH₃ 457. S CH₃ H H CH₃ CH₃ F CH₃ 458. S CH(CH₃)₂ H H CH(CH₃)₂ CH₃ F CH₃ 459. S CH₂CH₃ H H CH₂CH₃ CH₃ F CH₃ 460. S CH₂CH(CH₃)₂ H H CH₂CH(CH₃)₂ CH₃ F CH₃ 461. S CH₂C(CH₃)₃ H H CH₂C(CH₃)₃ CH₃ F CH₃ 462. S

H H

CH₃ F CH₃ 463. S CH₂CF₃ H H CH₂CF₃ CH₃ F CH₃ 464. S CH₂CH₂CF₃ H H CH₂CH₂CF₃ CH₃ F CH₃ 465. S CH₂C(CH₃)₂CF₃ H H CH₂C(CH₃)₂CF₃ CH₃ F CH₃ 466. S CD₃ H H CD₃ CH₃ F CH₃ 467. S CD(CH₃)₂ H H CD(CH₃)₂ CH₃ F CH₃ 468. S CD₂CH(CH₃)₂ H H CD₂CH(CH₃)₂ CH₃ F CH₃ 469. S H CH₃ H CH₃ CH₃ F CH₃ 470. S H CH(CH₃)₂ H CH(CH₃)₂ CH₃ F CH₃ 471. S H CH₂CH₃ H CH₂CH₃ CH₃ F CH₃ 472. S H CH₂CH(CH₃)₂ H CH₂CH(CH₃)₂ CH₃ F CH₃ 473. S H CH₂C(CH₃)₃ H CH₂C(CH₃)₃ CH₃ F CH₃ 474. S H

H

CH₃ F CH₃ 475. S H CH₂CF₃ H CH₂CF₃ CH₃ F CH₃ 476. S H CH₂CH₂CF₃ H CH₂CH₂CF₃ CH₃ F CH₃ 477. S H CH₂C(CH₃)₂CF₃ H CH₂C(CH₃)₂CF₃ CH₃ F CH₃ 478. S H CD₃ H CD₃ CH₃ F CH₃ 479. S H CD(CH₃)₂ H CD(CH₃)₂ CH₃ F CH₃ 480. S H CD₂CH(CH₃)₂ H CD₂CH(CH₃)₂ CH₃ F CH₃ 481. S CD₃ H H H CD₃ H H 482. S CD(CH₃)₂ H H H CD₃ H H 483. S CD₂CH(CH₃)₂ H H H CD₃ H H 484. S H CD₃ H H CD₃ H H 485. S H CD(CH₃)₂ H H CD₃ H H 486. S H CD₂CH(CH₃)₂ H H CD₃ H H 487. S H H CD₃ H CD₃ H H 488. S H H CD(CH₃)₂ H CD₃ H H 489. S H H CD₂CH(CH₃)₂ H CD₃ H H 490. S H H H CD₃ CD₃ H H 491. S H H H CD(CH₃)₂ CD₃ H H 492. S H H H CD₂CH(CH₃)₂ CD₃ H H 493. S CD₃ CD₃ H H CD₃ H H 494. S CD(CH₃)₂ CD(CH₃)₂ H H CD₃ H H 495. S CD₂CH(CH₃)₂ CD₂CH(CH₃)₂ H H CD₃ H H 496. S CD₃ H CD₃ H CD₃ H H 497. S CD(CH₃)₂ H CD(CH₃)₂ H CD₃ H H 498. S CD₂CH(CH₃)₂ H CD₂CH(CH₃)₂ H CD₃ H H 499. S CD₃ H H CD₃ CD₃ H H 500. S CD(CH₃)₂ H H CD(CH₃)₂ CD₃ H H 501. S CD₂CH(CH₃)₂ H H CD₂CH(CH₃)₂ CD₃ H H 502. S H CD₃ H CD₃ CD₃ H H 503. S H CD(CH₃)₂ H CD(CH₃)₂ CD₃ H H 504. S H CD₂CH(CH₃)₂ H CD₂CH(CH₃)₂ CD₃ H H 505. S CD₃ H H H H H CD₃ 506. S CD(CH₃)₂ H H H H H CD₃ 507. S CD₂CH(CH₃)₂ H H H H H CD₃ 508. S H CD₃ H H H H CD₃ 509. S H CD(CH₃)₂ H H H H CD₃ 510. S H CD₂CH(CH₃)₂ H H H H CD₃ 511. S H H CD₃ H H H CD₃ 512. S H H CD(CH₃)₂ H H H CD₃ 513. S H H CD₂CH(CH₃)₂ H H H CD₃ 514. S H H H CD₃ H H CD₃ 515. S H H H CD(CH₃)₂ H H CD₃ 516. S H H H CD₂CH(CH₃)₂ H H CD₃ 517. S CD₃ CD₃ H H H H CD₃ 518. S CD(CH₃)₂ CD(CH₃)₂ H H H H CD₃ 519. S CD₂CH(CH₃)₂ CD₂CH(CH₃)₂ H H H H CD₃ 520. S CD₃ H CD₃ H H H CD₃ 521. S CD(CH₃)₂ H CD(CH₃)₂ H H H CD₃ 522. S CD₂CH(CH₃)₂ H CD₂CH(CH₃)₂ H H H CD₃ 523. S CD₃ H H CD₃ H H CD₃ 524. S CD(CH₃)₂ H H CD(CH₃)₂ H H CD₃ 525. S CD₂CH(CH₃)₂ H H CD₂CH(CH₃)₂ H H CD₃ 526. S H CD₃ H CD₃ H H CD₃ 527. S H CD(CH₃)₂ H CD(CH₃)₂ H H CD₃ 528. S H CD₂CH(CH₃)₂ H CD₂CH(CH₃)₂ H H CD₃ 529. S CD₃ H H H CD₃ H CD₃ 530. S CD(CH₃)₂ H H H CD₃ H CD₃ 531. S CD₂CH(CH₃)₂ H H H CD₃ H CD₃ 532. S H CD₃ H H CD₃ H CD₃ 533. S H CD(CH₃)₂ H H CD₃ H CD₃ 534. S H CD₂CH(CH₃)₂ H H CD₃ H CD₃ 535. S H H CD₃ H CD₃ H CD₃ 536. S H H CD(CH₃)₂ H CD₃ H CD₃ 537. S H H CD₂CH(CH₃)₂ H CD₃ H CD₃ 538. S H H H CD₃ CD₃ H CD₃ 539. S H H H CD(CH₃)₂ CD₃ H CD₃ 540. S H H H CD₂CH(CH₃)₂ CD₃ H CD₃ 541. S CD₃ CD₃ H H CD₃ H CD₃ 542. S CD(CH₃)₂ CD(CH₃)₂ H H CD₃ H CD₃ 543. S CD₂CH(CH₃)₂ CD₂CH(CH₃)₂ H H CD₃ H CD₃ 544. S CD₃ H CD₃ H CD₃ H CD₃ 545. S CD(CH₃)₂ H CD(CH₃)₂ H CD₃ H CD₃ 546. S CD₂CH(CH₃)₂ H CD₂CH(CH₃)₂ H CD₃ H CD₃ 547. S CD₃ H H CD₃ CD₃ H CD₃ 548. S CD(CH₃)₂ H H CD(CH₃)₂ CD₃ H CD₃ 549. S CD₂CH(CH₃)₂ H H CD₂CH(CH₃)₂ CD₃ H CD₃ 550. S H CD₃ H CD₃ CD₃ H CD₃ 551. S H CD(CH₃)₂ H CD(CH₃)₂ CD₃ H CD₃ 552. S H CD₂CH(CH₃)₂ H CD₂CH(CH₃)₂ CD₃ H CD₃ 553. S CD₃ H H H CD₃ F CD₃ 554. S CD(CH₃)₂ H H H CD₃ F CD₃ 555. S CD₂CH(CH₃)₂ H H H CD₃ F CD₃ 556. S H CD₃ H H CD₃ F CD₃ 557. S H CD(CH₃)₂ H H CD₃ F CD₃ 558. S H CD₂CH(CH₃)₂ H H CD₃ F CD₃ 559. S H H CD₃ H CD₃ F CD₃ 560. S H H CD(CH₃)₂ H CD₃ F CD₃ 561. S H H CD₂CH(CH₃)₂ H CD₃ F CD₃ 562. S H H H CD₃ CD₃ F CD₃ 563. S H H H CD(CH₃)₂ CD₃ F CD₃ 564. S H H H CD₂CH(CH₃)₂ CD₃ F CD₃ 565. S CD₃ CD₃ H H CD₃ F CD₃ 566. S CD(CH₃)₂ CD(CH₃)₂ H H CD₃ F CD₃ 567. S CD₂CH(CH₃)₂ CD₂CH(CH₃)₂ H H CD₃ F CD₃ 568. S CD₃ H CD₃ H CD₃ F CD₃ 569. S CD(CH₃)₂ H CD(CH₃)₂ H CD₃ F CD₃ 570. S CD₂CH(CH₃)₂ H CD₂CH(CH₃)₂ H CD₃ F CD₃ 571. S CD₃ H H CD₃ CD₃ F CD₃ 572. S CD(CH₃)₂ H H CD(CH₃)₂ CD₃ F CD₃ 573. S CD₂CH(CH₃)₂ H H CD₂CH(CH₃)₂ CD₃ F CD₃ 574. S H CD₃ H CD₃ CD₃ F CD₃ 575. S H CD(CH₃)₂ H CD(CH₃)₂ CD₃ F CD₃ 576. S H CD₂CH(CH₃)₂ H CD₂CH(CH₃)₂ CD₃ F CD₃ 577. Se CH₃ H H H H H H 578. Se CH(CH₃)₂ H H H H H H 579. Se CH₂CH₃ H H H H H H 580. Se CH₂CH(CH₃)₂ H H H H H H 581. Se CH₂C(CH₃)₃ H H H H H H 582. Se

H H H H H H 583. Se CH₂CF₃ H H H H H H 584. Se CH₂CH₂CF₃ H H H H H H 585. Se CH₂C(CH₃)₂CF₃ H H H H H H 586. Se CD₃ H H H H H H 587. Se CD(CH₃)₂ H H H H H H 588. Se CD₂CH(CH₃)₂ H H H H H H 589. Se H CH₃ H H H H H 590. Se H CH(CH₃)₂ H H H H H 591. Se H CH₂CH₃ H H H H H 592. Se H CH₂CH(CH₃)₂ H H H H H 593. Se H CH₂C(CH₃)₃ H H H H H 594. Se H

H H H H H 595. Se H CH₂CF₃ H H H H H 596. Se H CH₂CH₂CF₃ H H H H H 597. Se H CH₂C(CH₃)₂CF₃ H H H H H 598. Se H CD₃ H H H H H 599. Se H CD(CH₃)₂ H H H H H 600. Se H CD₂CH(CH₃)₂ H H H H H 601. Se H H CH₃ H H H H 602. Se H H CH(CH₃)₂ H H H H 603. Se H H CH₂CH₃ H H H H 604. Se H H CH₂CH(CH₃)₂ H H H H 605. Se H H CH₂C(CH₃)₃ H H H H 606. Se H H

H H H H 607. Se H H CH₂CF₃ H H H H 608. Se H H CH₂CH₂CF₃ H H H H 609. Se H H CH₂C(CH₃)₂CF₃ H H H H 610. Se H H CD₃ H H H H 611. Se H H CD(CH₃)₂ H H H H 612. Se H H CD₂CH(CH₃)₂ H H H H 613. Se H H H CH₃ H H H 614. Se H H H CH(CH₃)₂ H H H 615. Se H H H CH₂CH₃ H H H 616. Se H H H CH₂CH(CH₃)₂ H H H 617. Se H H H CH₂C(CH₃)₃ H H H 618. Se H H H

H H H 619. Se H H H CH₂CF₃ H H H 620. Se H H H CH₂CH₂CF₃ H H H 621. Se H H H CH₂C(CH₃)₂CF₃ H H H 622. Se H H H CD₃ H H H 623. Se H H H CD(CH₃)₂ H H H 624. Se H H H CD₂CH(CH₃)₂ H H H 625. Se CH₃ CH₃ H H H H H 626. Se CH(CH₃)₂ CH(CH₃)₂ H H H H H 627. Se CH₂CH₃ CH₂CH₃ H H H H H 628. Se CH₂CH(CH₃)₂ CH₂CH(CH₃)₂ H H H H H 629. Se CH₂C(CH₃)₃ CH₂C(CH₃)₃ H H H H H 630. Se

H H H H H 631. Se CH₂CF₃ CH₂CF₃ H H H H H 632. Se CH₂CH₂CF₃ CH₂CH₂CF₃ H H H H H 633. Se CH₂C(CH₃)₂CF₃ CH₂C(CH₃)₂CF₃ H H H H H 634. Se CD₃ CD₃ H H H H H 635. Se CD(CH₃)₂ CD(CH₃)₂ H H H H H 636. Se CD₂CH(CH₃)₂ CD₂CH(CH₃)₂ H H H H H 637. Se CH₃ H CH₃ H H H H 638. Se CH(CH₃)₂ H CH(CH₃)₂ H H H H 639. Se CH₂CH₃ H CH₂CH₃ H H H H 640. Se CH₂CH(CH₃)₂ H CH₂CH(CH₃)₂ H H H H 641. Se CH₂C(CH₃)₃ H CH₂C(CH₃)₃ H H H H 642. Se

H

H H H H 643. Se CH₂CF₃ H CH₂CF₃ H H H H 644. Se CH₂CH₂CF₃ H CH₂CH₂CF₃ H H H H 645. Se CH₂C(CH₃)₂CF₃ H CH₂C(CH₃)₂CF₃ H H H H 646. Se CD₃ H CD₃ H H H H 647. Se CD(CH₃)₂ H CD(CH₃)₂ H H H H 648. Se CD₂CH(CH₃)₂ H CD₂CH(CH₃)₂ H H H H 649. Se CH₃ H H CH₃ H H H 650. Se CH(CH₃)₂ H H CH(CH₃)₂ H H H 651. Se CH₂CH₃ H H CH₂CH₃ H H H 652. Se CH₂CH(CH₃)₂ H H CH₂CH(CH₃)₂ H H H 653. Se CH₂C(CH₃)₃ H H CH₂C(CH₃)₃ H H H 654. Se

H H

H H H 655. Se CH₂CF₃ H H CH₂CF₃ H H H 656. Se CH₂CH₂CF₃ H H CH₂CH₂CF₃ H H H 657. Se CH₂C(CH₃)₂CF₃ H H CH₂C(CH₃)₂CF₃ H H H 658. Se CD₃ H H CD₃ H H H 659. Se CD(CH₃)₂ H H CD(CH₃)₂ H H H 660. Se CD₂CH(CH₃)₂ H H CD₂CH(CH₃)₂ H H H 661. Se H CH₃ H CH₃ H H H 662. Se H CH(CH₃)₂ H CH(CH₃)₂ H H H 663. Se H CH₂CH₃ H CH₂CH₃ H H H 664. Se H CH₂CH(CH₃)₂ H CH₂CH(CH₃)₂ H H H 665. Se H CH₂C(CH₃)₃ H CH₂C(CH₃)₃ H H H 666. Se H

H

H H H 667. Se H CH₂CF₃ H CH₂CF₃ H H H 668. Se H CH₂CH₂CF₃ H CH₂CH₂CF₃ H H H 669. Se H CH₂C(CH₃)₂CF₃ H CH₂C(CH₃)₂CF₃ H H H 670. Se H CD₃ H CD₃ H H H 671. Se H CD(CH₃)₂ H CD(CH₃)₂ H H H 672. Se H CD₂CH(CH₃)₂ H CD₂CH(CH₃)₂ H H H 673. Se CH₃ H H H CH₃ H H 674. Se CH(CH₃)₂ H H H CH₃ H H 675. Se CH₂CH₃ H H H CH₃ H H 676. Se CH₂CH(CH₃)₂ H H H CH₃ H H 677. Se CH₂C(CH₃)₃ H H H CH₃ H H 678. Se

H H H CH₃ H H 679. Se CH₂CF₃ H H H CH₃ H H 680. Se CH₂CH₂CF₃ H H H CH₃ H H 681. Se CH₂C(CH₃)₂CF₃ H H H CH₃ H H 682. Se CD₃ H H H CH₃ H H 683. Se CD(CH₃)₂ H H H CH₃ H H 684. Se CD₂CH(CH₃)₂ H H H CH₃ H H 685. Se H CH₃ H H CH₃ H H 686. Se H CH(CH₃)₂ H H CH₃ H H 687. Se H CH₂CH₃ H H CH₃ H H 688. Se H CH₂CH(CH₃)₂ H H CH₃ H H 689. Se H CH₂C(CH₃)₃ H H CH₃ H H 690. Se H

H H CH₃ H H 691. Se H CH₂CF₃ H H CH₃ H H 692. Se H CH₂CH₂CF₃ H H CH₃ H H 693. Se H CH₂C(CH₃)₂CF₃ H H CH₃ H H 694. Se H CD₃ H H CH₃ H H 695. Se H CD(CH₃)₂ H H CH₃ H H 696. Se H CD₂CH(CH₃)₂ H H CH₃ H H 697. Se H H CH₃ H CH₃ H H 698. Se H H CH(CH₃)₂ H CH₃ H H 699. Se H H CH₂CH₃ H CH₃ H H 700. Se H H CH₂CH(CH₃)₂ H CH₃ H H 701. Se H H CH₂C(CH₃)₃ H CH₃ H H 702. Se H H

H CH₃ H H 703. Se H H CH₂CF₃ H CH₃ H H 704. Se H H CH₂CH₂CF₃ H CH₃ H H 705. Se H H CH₂C(CH₃)₂CF₃ H CH₃ H H 706. Se H H CD₃ H CH₃ H H 707. Se H H CD(CH₃)₂ H CH₃ H H 708. Se H H CD₂CH(CH₃)₂ H CH₃ H H 709. Se H H H CH₃ CH₃ H H 710. Se H H H CH(CH₃)₂ CH₃ H H 711. Se H H H CH₂CH₃ CH₃ H H 712. Se H H H CH₂CH(CH₃)₂ CH₃ H H 713. Se H H H CH₂C(CH₃)₃ CH₃ H H 714. Se H H H

CH₃ H H 715. Se H H H CH₂CF₃ CH₃ H H 716. Se H H H CH₂CH₂CF₃ CH₃ H H 717. Se H H H CH₂C(CH₃)₂CF₃ CH₃ H H 718. Se H H H CD₃ CH₃ H H 719. Se H H H CD(CH₃)₂ CH₃ H H 720. Se H H H CD₂CH(CH₃)₂ CH₃ H H 721. Se CH₃ CH₃ H H CH₃ H H 722. Se CH(CH₃)₂ CH(CH₃)₂ H H CH₃ H H 723. Se CH₂CH₃ CH₂CH₃ H H CH₃ H H 724. Se CH₂CH(CH₃)₂ CH₂CH(CH₃)₂ H H CH₃ H H 725. Se CH₂C(CH₃)₃ CH₂C(CH₃)₃ H H CH₃ H H 726. Se

H H CH₃ H H 727. Se CH₂CF₃ CH₂CF₃ H H CH₃ H H 728. Se CH₂CH₂CF₃ CH₂CH₂CF₃ H H CH₃ H H 729. Se CH₂C(CH₃)₂CF₃ CH₂C(CH₃)₂CF₃ H H CH₃ H H 730. Se CD₃ CD₃ H H CH₃ H H 731. Se CD(CH₃)₂ CD(CH₃)₂ H H CH₃ H H 732. Se CD₂CH(CH₃)₂ CD₂CH(CH₃)₂ H H CH₃ H H 733. Se CH₃ H CH₃ H CH₃ H H 734. Se CH(CH₃)₂ H CH(CH₃)₂ H CH₃ H H 735. Se CH₂CH₃ H CH₂CH₃ H CH₃ H H 736. Se CH₂CH(CH₃)₂ H CH₂CH(CH₃)₂ H CH₃ H H 737. Se CH₂C(CH₃)₃ H CH₂C(CH₃)₃ H CH₃ H H 738. Se

H

H CH₃ H H 739. Se CH₂CF₃ H CH₂CF₃ H CH₃ H H 740. Se CH₂CH₂CF₃ H CH₂CH₂CF₃ H CH₃ H H 741. Se CH₂C(CH₃)₂CF₃ H CH₂C(CH₃)₂CF₃ H CH₃ H H 742. Se CD₃ H CD₃ H CH₃ H H 743. Se CD(CH₃)₂ H CD(CH₃)₂ H CH₃ H H 744. Se CD₂CH(CH₃)₂ H CD₂CH(CH₃)₂ H CH₃ H H 745. Se CH₃ H H CH₃ CH₃ H H 746. Se CH(CH₃)₂ H H CH(CH₃)₂ CH₃ H H 747. Se CH₂CH₃ H H CH₂CH₃ CH₃ H H 748. Se CH₂CH(CH₃)₂ H H CH₂CH(CH₃)₂ CH₃ H H 749. Se CH₂C(CH₃)₃ H H CH₂C(CH₃)₃ CH₃ H H 750. Se

H H

CH₃ H H 751. Se CH₂CF₃ H H CH₂CF₃ CH₃ H H 752. Se CH₂CH₂CF₃ H H CH₂CH₂CF₃ CH₃ H H 753. Se CH₂C(CH₃)₂CF₃ H H CH₂C(CH₃)₂CF₃ CH₃ H H 754. Se CD₃ H H CD₃ CH₃ H H 755. Se CD(CH₃)₂ H H CD(CH₃)₂ CH₃ H H 756. Se CD₂CH(CH₃)₂ H H CD₂CH(CH₃)₂ CH₃ H H 757. Se H CH₃ H CH₃ CH₃ H H 758. Se H CH(CH₃)₂ H CH(CH₃)₂ CH₃ H H 759. Se H CH₂CH₃ H CH₂CH₃ CH₃ H H 760. Se H CH₂CH(CH₃)₂ H CH₂CH(CH₃)₂ CH₃ H H 761. Se H CH₂C(CH₃)₃ H CH₂C(CH₃)₃ CH₃ H H 762. Se H

H

CH₃ H H 763. Se H CH₂CF₃ H CH₂CF₃ CH₃ H H 764. Se H CH₂CH₂CF₃ H CH₂CH₂CF₃ CH₃ H H 765. Se H CH₂C(CH₃)₂CF₃ H CH₂C(CH₃)₂CF₃ CH₃ H H 766. Se H CD₃ H CD₃ CH₃ H H 767. Se H CD(CH₃)₂ H CD(CH₃)₂ CH₃ H H 768. Se H CD₂CH(CH₃)₂ H CD₂CH(CH₃)₂ CH₃ H H 769. Se CH₃ H H H H H CH₃ 770. Se CH(CH₃)₂ H H H H H CH₃ 771. Se CH₂CH₃ H H H H H CH₃ 772. Se CH₂CH(CH₃)₂ H H H H H CH₃ 773. Se CH₂C(CH₃)₃ H H H H H CH₃ 774. Se

H H H H H CH₃ 775. Se CH₂CF₃ H H H H H CH₃ 776. Se CH₂CH₂CF₃ H H H H H CH₃ 777. Se CH₂C(CH₃)₂CF₃ H H H H H CH₃ 778. Se CD₃ H H H H H CH₃ 779. Se CD(CH₃)₂ H H H H H CH₃ 780. Se CD₂CH(CH₃)₂ H H H H H CH₃ 781. Se H CH₃ H H H H CH₃ 782. Se H CH(CH₃)₂ H H H H CH₃ 783. Se H CH₂CH₃ H H H H CH₃ 784. Se H CH₂CH(CH₃)₂ H H H H CH₃ 785. Se H CH₂C(CH₃)₃ H H H H CH₃ 786. Se H

H H H H CH₃ 787. Se H CH₂CF₃ H H H H CH₃ 788. Se H CH₂CH₂CF₃ H H H H CH₃ 789. Se H CH₂C(CH₃)₂CF₃ H H H H CH₃ 790. Se H CD₃ H H H H CH₃ 791. Se H CD(CH₃)₂ H H H H CH₃ 792. Se H CD₂CH(CH₃)₂ H H H H CH₃ 793. Se H H CH₃ H H H CH₃ 794. Se H H CH(CH₃)₂ H H H CH₃ 795. Se H H CH₂CH₃ H H H CH₃ 796. Se H H CH₂CH(CH₃)₂ H H H CH₃ 797. Se H H CH₂C(CH₃)₃ H H H CH₃ 798. Se H H

H H H CH₃ 799. Se H H CH₂CF₃ H H H CH₃ 800. Se H H CH₂CH₂CF₃ H H H CH₃ 801. Se H H CH₂C(CH₃)₂CF₃ H H H CH₃ 802. Se H H CD₃ H H H CH₃ 803. Se H H CD(CH₃)₂ H H H CH₃ 804. Se H H CD₂CH(CH₃)₂ H H H CH₃ 805. Se H H H CH₃ H H CH₃ 806. Se H H H CH(CH₃)₂ H H CH₃ 807. Se H H H CH₂CH₃ H H CH₃ 808. Se H H H CH₂CH(CH₃)₂ H H CH₃ 809. Se H H H CH₂C(CH₃)₃ H H CH₃ 810. Se H H H

H H CH₃ 811. Se H H H CH₂CF₃ H H CH₃ 812. Se H H H CH₂CH₂CF₃ H H CH₃ 813. Se H H H CH₂C(CH₃)₂CF₃ H H CH₃ 814. Se H H H CD₃ H H CH₃ 815. Se H H H CD(CH₃)₂ H H CH₃ 816. Se H H H CD₂CH(CH₃)₂ H H CH₃ 817. Se CH₃ CH₃ H H H H CH₃ 818. Se CH(CH₃)₂ CH(CH₃)₂ H H H H CH₃ 819. Se CH₂CH₃ CH₂CH₃ H H H H CH₃ 820. Se CH₂CH(CH₃)₂ CH₂CH(CH₃)₂ H H H H CH₃ 821. Se CH₂C(CH₃)₃ CH₂C(CH₃)₃ H H H H CH₃ 822. Se

H H H H CH₃ 823. Se CH₂CF₃ CH₂CF₃ H H H H CH₃ 824. Se CH₂CH₂CF₃ CH₂CH₂CF₃ H H H H CH₃ 825. Se CH₂C(CH₃)₂CF₃ CH₂C(CH₃)₂CF₃ H H H H CH₃ 826. Se CD₃ CD₃ H H H H CH₃ 827. Se CD(CH₃)₂ CD(CH₃)₂ H H H H CH₃ 828. Se CD₂CH(CH₃)₂ CD₂CH(CH₃)₂ H H H H CH₃ 829. Se CH₃ H CH₃ H H H CH₃ 830. Se CH(CH₃)₂ H CH(CH₃)₂ H H H CH₃ 831. Se CH₂CH₃ H CH₂CH₃ H H H CH₃ 832. Se CH₂CH(CH₃)₂ H CH₂CH(CH₃)₂ H H H CH₃ 833. Se CH₂C(CH₃)₃ H CH₂C(CH₃)₃ H H H CH₃ 834. Se

H

H H H CH₃ 835. Se CH₂CF₃ H CH₂CF₃ H H H CH₃ 836. Se CH₂CH₂CF₃ H CH₂CH₂CF₃ H H H CH₃ 837. Se CH₂C(CH₃)₂CF₃ H CH₂C(CH₃)₂CF₃ H H H CH₃ 838. Se CD₃ H CD₃ H H H CH₃ 839. Se CD(CH₃)₂ H CD(CH₃)₂ H H H CH₃ 840. Se CD₂CH(CH₃)₂ H CD₂CH(CH₃)₂ H H H CH₃ 841. Se CH₃ H H CH₃ H H CH₃ 842. Se CH(CH₃)₂ H H CH(CH₃)₂ H H CH₃ 843. Se CH₂CH₃ H H CH₂CH₃ H H CH₃ 844. Se CH₂CH(CH₃)₂ H H CH₂CH(CH₃)₂ H H CH₃ 845. Se CH₂C(CH₃)₃ H H CH₂C(CH₃)₃ H H CH₃ 846. Se

H H

H H CH₃ 847. Se CH₂CF₃ H H CH₂CF₃ H H CH₃ 848. Se CH₂CH₂CF₃ H H CH₂CH₂CF₃ H H CH₃ 849. Se CH₂C(CH₃)₂CF₃ H H CH₂C(CH₃)₂CF₃ H H CH₃ 850. Se CD₃ H H CD₃ H H CH₃ 851. Se CD(CH₃)₂ H H CD(CH₃)₂ H H CH₃ 852. Se CD₂CH(CH₃)₂ H H CD₂CH(CH₃)₂ H H CH₃ 853. Se H CH₃ H CH₃ H H CH₃ 854. Se H CH(CH₃)₂ H CH(CH₃)₂ H H CH₃ 855. Se H CH₂CH₃ H CH₂CH₃ H H CH₃ 856. Se H CH₂CH(CH₃)₂ H CH₂CH(CH₃)₂ H H CH₃ 857. Se H CH₂C(CH₃)₃ H CH₂C(CH₃)₃ H H CH₃ 858. Se H

H

H H CH₃ 859. Se H CH₂CF₃ H CH₂CF₃ H H CH₃ 860. Se H CH₂CH₂CF₃ H CH₂CH₂CF₃ H H CH₃ 861. Se H CH₂C(CH₃)₂CF₃ H CH₂C(CH₃)₂CF₃ H H CH₃ 862. Se H CD₃ H CD₃ H H CH₃ 863. Se H CD(CH₃)₂ H CD(CH₃)₂ H H CH₃ 864. Se H CD₂CH(CH₃)₂ H CD₂CH(CH₃)₂ H H CH₃ 865. Se CH₃ H H H CH₃ H CH₃ 866. Se CH(CH₃)₂ H H H CH₃ H CH₃ 867. Se CH₂CH₃ H H H CH₃ H CH₃ 868. Se CH₂CH(CH₃)₂ H H H CH₃ H CH₃ 869. Se CH₂C(CH₃)₃ H H H CH₃ H CH₃ 870. Se

H H H CH₃ H CH₃ 871. Se CH₂CF₃ H H H CH₃ H CH₃ 872. Se CH₂CH₂CF₃ H H H CH₃ H CH₃ 873. Se CH₂C(CH₃)₂CF₃ H H H CH₃ H CH₃ 874. Se CD₃ H H H CH₃ H CH₃ 875. Se CD(CH₃)₂ H H H CH₃ H CH₃ 876. Se CD₂CH(CH₃)₂ H H H CH₃ H CH₃ 877. Se H CH₃ H H CH₃ H CH₃ 878. Se H CH(CH₃)₂ H H CH₃ H CH₃ 879. Se H CH₂CH₃ H H CH₃ H CH₃ 880. Se H CH₂CH(CH₃)₂ H H CH₃ H CH₃ 881. Se H CH₂C(CH₃)₃ H H CH₃ H CH₃ 882. Se H

H H CH₃ H CH₃ 883. Se H CH₂CF₃ H H CH₃ H CH₃ 884. Se H CH₂CH₂CF₃ H H CH₃ H CH₃ 885. Se H CH₂C(CH₃)₂CF₃ H H CH₃ H CH₃ 886. Se H CD₃ H H CH₃ H CH₃ 887. Se H CD(CH₃)₂ H H CH₃ H CH₃ 888. Se H CD₂CH(CH₃)₂ H H CH₃ H CH₃ 889. Se H H CH₃ H CH₃ H CH₃ 890. Se H H CH(CH₃)₂ H CH₃ H CH₃ 891. Se H H CH₂CH₃ H CH₃ H CH₃ 892. Se H H CH₂CH(CH₃)₂ H CH₃ H CH₃ 893. Se H H CH₂C(CH₃)₃ H CH₃ H CH₃ 894. Se H H

H CH₃ H CH₃ 895. Se H H CH₂CF₃ H CH₃ H CH₃ 896. Se H H CH₂CH₂CF₃ H CH₃ H CH₃ 897. Se H H CH₂C(CH₃)₂CF₃ H CH₃ H CH₃ 898. Se H H CD₃ H CH₃ H CH₃ 899. Se H H CD(CH₃)₂ H CH₃ H CH₃ 900. Se H H CD₂CH(CH₃)₂ H CH₃ H CH₃ 901. Se H H H CH₃ CH₃ H CH₃ 902. Se H H H CH(CH₃)₂ CH₃ H CH₃ 903. Se H H H CH₂CH₃ CH₃ H CH₃ 904. Se H H H CH₂CH(CH₃)₂ CH₃ H CH₃ 905. Se H H H CH₂C(CH₃)₃ CH₃ H CH₃ 906. Se H H H

CH₃ H CH₃ 907. Se H H H CH₂CF₃ CH₃ H CH₃ 908. Se H H H CH₂CH₂CF₃ CH₃ H CH₃ 909. Se H H H CH₂C(CH₃)₂CF₃ CH₃ H CH₃ 910. Se H H H CD₃ CH₃ H CH₃ 911. Se H H H CD(CH₃)₂ CH₃ H CH₃ 912. Se H H H CD₂CH(CH₃)₂ CH₃ H CH₃ 913. Se CH₃ CH₃ H H CH₃ H CH₃ 914. Se CH(CH₃)₂ CH(CH₃)₂ H H CH₃ H CH₃ 915. Se CH₂CH₃ CH₂CH₃ H H CH₃ H CH₃ 916. Se CH₂CH(CH₃)₂ CH₂CH(CH₃)₂ H H CH₃ H CH₃ 917. Se CH₂C(CH₃)₃ CH₂C(CH₃)₃ H H CH₃ H CH₃ 918. Se

H H CH₃ H CH₃ 919. Se CH₂CF₃ CH₂CF₃ H H CH₃ H CH₃ 920. Se CH₂CH₂CF₃ CH₂CH₂CF₃ H H CH₃ H CH₃ 921. Se CH₂C(CH₃)₂CF₃ CH₂C(CH₃)₂CF₃ H H CH₃ H CH₃ 922. Se CD₃ CD₃ H H CH₃ H CH₃ 923. Se CD(CH₃)₂ CD(CH₃)₂ H H CH₃ H CH₃ 924. Se CD₂CH(CH₃)₂ CD₂CH(CH₃)₂ H H CH₃ H CH₃ 925. Se CH₃ H CH₃ H CH₃ H CH₃ 926. Se CH(CH₃)₂ H CH(CH₃)₂ H CH₃ H CH₃ 927. Se CH₂CH₃ H CH₂CH₃ H CH₃ H CH₃ 928. Se CH₂CH(CH₃)₂ H CH₂CH(CH₃)₂ H CH₃ H CH₃ 929. Se CH₂C(CH₃)₃ H CH₂C(CH₃)₃ H CH₃ H CH₃ 930. Se

H

H CH₃ H CH₃ 931. Se CH₂CF₃ H CH₂CF₃ H CH₃ H CH₃ 932. Se CH₂CH₂CF₃ H CH₂CH₂CF₃ H CH₃ H CH₃ 933. Se CH₂C(CH₃)₂CF₃ H CH₂C(CH₃)₂CF₃ H CH₃ H CH₃ 934. Se CD₃ H CD₃ H CH₃ H CH₃ 935. Se CD(CH₃)₂ H CD(CH₃)₂ H CH₃ H CH₃ 936. Se CD₂CH(CH₃)₂ H CD₂CH(CH₃)₂ H CH₃ H CH₃ 937. Se CH₃ H H CH₃ CH₃ H CH₃ 938. Se CH(CH₃)₂ H H CH(CH₃)₂ CH₃ H CH₃ 939. Se CH₂CH₃ H H CH₂CH₃ CH₃ H CH₃ 940. Se CH₂CH(CH₃)₂ H H CH₂CH(CH₃)₂ CH₃ H CH₃ 941. Se CH₂C(CH₃)₃ H H CH₂C(CH₃)₃ CH₃ H CH₃ 942. Se

H H

CH₃ H CH₃ 943. Se CH₂CF₃ H H CH₂CF₃ CH₃ H CH₃ 944. Se CH₂CH₂CF₃ H H CH₂CH₂CF₃ CH₃ H CH₃ 945. Se CH₂C(CH₃)₂CF₃ H H CH₂C(CH₃)₂CF₃ CH₃ H CH₃ 946. Se CD₃ H H CD₃ CH₃ H CH₃ 947. Se CD(CH₃)₂ H H CD(CH₃)₂ CH₃ H CH₃ 948. Se CD₂CH(CH₃)₂ H H CD₂CH(CH₃)₂ CH₃ H CH₃ 949. Se H CH₃ H CH₃ CH₃ H CH₃ 950. Se H CH(CH₃)₂ H CH(CH₃)₂ CH₃ H CH₃ 951. Se H CH₂CH₃ H CH₂CH₃ CH₃ H CH₃ 952. Se H CH₂CH(CH₃)₂ H CH₂CH(CH₃)₂ CH₃ H CH₃ 953. Se H CH₂C(CH₃)₃ H CH₂C(CH₃)₃ CH₃ H CH₃ 954. Se H

H

CH₃ H CH₃ 955. Se H CH₂CF₃ H CH₂CF₃ CH₃ H CH₃ 956. Se H CH₂CH₂CF₃ H CH₂CH₂CF₃ CH₃ H CH₃ 957. Se H CH₂C(CH₃)₂CF₃ H CH₂C(CH₃)₂CF₃ CH₃ H CH₃ 958. Se H CD₃ H CD₃ CH₃ H CH₃ 959. Se H CD(CH₃)₂ H CD(CH₃)₂ CH₃ H CH₃ 960. Se H CD₂CH(CH₃)₂ H CD₂CH(CH₃)₂ CH₃ H CH₃ 961. Se CH₃ H H H CH₃ F CH₃ 962. Se CH(CH₃)₂ H H H CH₃ F CH₃ 963. Se CH₂CH₃ H H H CH₃ F CH₃ 964. Se CH₂CH(CH₃)₂ H H H CH₃ F CH₃ 965. Se CH₂C(CH₃)₃ H H H CH₃ F CH₃ 966. Se

H H H CH₃ F CH₃ 967. Se CH₂CF₃ H H H CH₃ F CH₃ 968. Se CH₂CH₂CF₃ H H H CH₃ F CH₃ 969. Se CH₂C(CH₃)₂CF₃ H H H CH₃ F CH₃ 970. Se CD₃ H H H CH₃ F CH₃ 971. Se CD(CH₃)₂ H H H CH₃ F CH₃ 972. Se CD₂CH(CH₃)₂ H H H CH₃ F CH₃ 973. Se H CH₃ H H CH₃ F CH₃ 974. Se H CH(CH₃)₂ H H CH₃ F CH₃ 975. Se H CH₂CH₃ H H CH₃ F CH₃ 976. Se H CH₂CH(CH₃)₂ H H CH₃ F CH₃ 977. Se H CH₂C(CH₃)₃ H H CH₃ F CH₃ 978. Se H

H H CH₃ F CH₃ 979. Se H CH₂CF₃ H H CH₃ F CH₃ 980. Se H CH₂CH₂CF₃ H H CH₃ F CH₃ 981. Se H CH₂C(CH₃)₂CF₃ H H CH₃ F CH₃ 982. Se H CD₃ H H CH₃ F CH₃ 983. Se H CD(CH₃)₂ H H CH₃ F CH₃ 984. Se H CD₂CH(CH₃)₂ H H CH₃ F CH₃ 985. Se H H CH₃ H CH₃ F CH₃ 986. Se H H CH(CH₃)₂ H CH₃ F CH₃ 987. Se H H CH₂CH₃ H CH₃ F CH₃ 988. Se H H CH₂CH(CH₃)₂ H CH₃ F CH₃ 989. Se H H CH₂C(CH₃)₃ H CH₃ F CH₃ 990. Se H H

H CH₃ F CH₃ 991. Se H H CH₂CF₃ H CH₃ F CH₃ 992. Se H H CH₂CH₂CF₃ H CH₃ F CH₃ 993. Se H H CH₂C(CH₃)₂CF₃ H CH₃ F CH₃ 994. Se H H CD₃ H CH₃ F CH₃ 995. Se H H CD(CH₃)₂ H CH₃ F CH₃ 996. Se H H CD₂CH(CH₃)₂ H CH₃ F CH₃ 997. Se H H H CH₃ CH₃ F CH₃ 998. Se H H H CH(CH₃)₂ CH₃ F CH₃ 999. Se H H H CH₂CH₃ CH₃ F CH₃ 1000. Se H H H CH₂CH(CH₃)₂ CH₃ F CH₃ 1001. Se H H H CH₂C(CH₃)₃ CH₃ F CH₃ 1002. Se H H H

CH₃ F CH₃ 1003. Se H H H CH₂CF₃ CH₃ F CH₃ 1004. Se H H H CH₂CH₂CF₃ CH₃ F CH₃ 1005. Se H H H CH₂C(CH₃)₂CF₃ CH₃ F CH₃ 1006. Se H H H CD₃ CH₃ F CH₃ 1007. Se H H H CD(CH₃)₂ CH₃ F CH₃ 1008. Se H H H CD₂CH(CH₃)₂ CH₃ F CH₃ 1009. Se CH₃ CH₃ H H CH₃ F CH₃ 1010. Se CH(CH₃)₂ CH(CH₃)₂ H H CH₃ F CH₃ 1011. Se CH₂CH₃ CH₂CH₃ H H CH₃ F CH₃ 1012. Se CH₂CH(CH₃)₂ CH₂CH(CH₃)₂ H H CH₃ F CH₃ 1013. Se CH₂C(CH₃)₃ CH₂C(CH₃)₃ H H CH₃ F CH₃ 1014. Se

H H CH₃ F CH₃ 1015. Se CH₂CF₃ CH₂CF₃ H H CH₃ F CH₃ 1016. Se CH₂CH₂CF₃ CH₂CH₂CF₃ H H CH₃ F CH₃ 1017. Se CH₂C(CH₃)₂CF₃ CH₂C(CH₃)₂CF₃ H H CH₃ F CH₃ 1018. Se CD₃ CD₃ H H CH₃ F CH₃ 1019. Se CD(CH₃)₂ CD(CH₃)₂ H H CH₃ F CH₃ 1020. Se CD₂CH(CH₃)₂ CD₂CH(CH₃)₂ H H CH₃ F CH₃ 1021. Se CH₃ H CH₃ H CH₃ F CH₃ 1022. Se CH(CH₃)₂ H CH(CH₃)₂ H CH₃ F CH₃ 1023. Se CH₂CH₃ H CH₂CH₃ H CH₃ F CH₃ 1024. Se CH₂CH(CH₃)₂ H CH₂CH(CH₃)₂ H CH₃ F CH₃ 1025. Se CH₂C(CH₃)₃ H CH₂C(CH₃)₃ H CH₃ F CH₃ 1026. Se

H

H CH₃ F CH₃ 1027. Se CH₂CF₃ H CH₂CF₃ H CH₃ F CH₃ 1028. Se CH₂CH₂CF₃ H CH₂CH₂CF₃ H CH₃ F CH₃ 1029. Se CH₂C(CH₃)₂CF₃ H CH₂C(CH₃)₂CF₃ H CH₃ F CH₃ 1030. Se CD₃ H CD₃ H CH₃ F CH₃ 1031. Se CD(CH₃)₂ H CD(CH₃)₂ H CH₃ F CH₃ 1032. Se CD₂CH(CH₃)₂ H CD₂CH(CH₃)₂ H CH₃ F CH₃ 1033. Se CH₃ H H CH₃ CH₃ F CH₃ 1034. Se CH(CH₃)₂ H H CH(CH₃)₂ CH₃ F CH₃ 1035. Se CH₂CH₃ H H CH₂CH₃ CH₃ F CH₃ 1036. Se CH₂CH(CH₃)₂ H H CH₂CH(CH₃)₂ CH₃ F CH₃ 1037. Se CH₂C(CH₃)₃ H H CH₂C(CH₃)₃ CH₃ F CH₃ 1038. Se

H H

CH₃ F CH₃ 1039. Se CH₂CF₃ H H CH₂CF₃ CH₃ F CH₃ 1040. Se CH₂CH₂CF₃ H H CH₂CH₂CF₃ CH₃ F CH₃ 1041. Se CH₂C(CH₃)₂CF₃ H H CH₂C(CH₃)₂CF₃ CH₃ F CH₃ 1042. Se CD₃ H H CD₃ CH₃ F CH₃ 1043. Se CD(CH₃)₂ H H CD(CH₃)₂ CH₃ F CH₃ 1044. Se CD₂CH(CH₃)₂ H H CD₂CH(CH₃)₂ CH₃ F CH₃ 1045. Se H CH₃ H CH₃ CH₃ F CH₃ 1046. Se H CH(CH₃)₂ H CH(CH₃)₂ CH₃ F CH₃ 1047. Se H CH₂CH₃ H CH₂CH₃ CH₃ F CH₃ 1048. Se H CH₂CH(CH₃)₂ H CH₂CH(CH₃)₂ CH₃ F CH₃ 1049. Se H CH₂C(CH₃)₃ H CH₂C(CH₃)₃ CH₃ F CH₃ 1050. Se H

H

CH₃ F CH₃ 1051. Se H CH₂CF₃ H CH₂CF₃ CH₃ F CH₃ 1052. Se H CH₂CH₂CF₃ H CH₂CH₂CF₃ CH₃ F CH₃ 1053. Se H CH₂C(CH₃)₂CF₃ H CH₂C(CH₃)₂CF₃ CH₃ F CH₃ 1054. Se H CD₃ H CD₃ CH₃ F CH₃ 1055. Se H CD(CH₃)₂ H CD(CH₃)₂ CH₃ F CH₃ 1056. Se H CD₂CH(CH₃)₂ H CD₂CH(CH₃)₂ CH₃ F CH₃ 1057. Se CD₃ H H H CD₃ H H 1058. Se CD(CH₃)₂ H H H CD₃ H H 1059. Se CD₂CH(CH₃)₂ H H H CD₃ H H 1060. Se H CD₃ H H CD₃ H H 1061. Se H CD(CH₃)₂ H H CD₃ H H 1062. Se H CD₂CH(CH₃)₂ H H CD₃ H H 1063. Se H H CD₃ H CD₃ H H 1064. Se H H CD(CH₃)₂ H CD₃ H H 1065. Se H H CD₂CH(CH₃)₂ H CD₃ H H 1066. Se H H H CD₃ CD₃ H H 1067. Se H H H CD(CH₃)₂ CD₃ H H 1068. Se H H H CD₂CH(CH₃)₂ CD₃ H H 1069. Se CD₃ CD₃ H H CD₃ H H 1070. Se CD(CH₃)₂ CD(CH₃)₂ H H CD₃ H H 1071. Se CD₂CH(CH₃)₂ CD₂CH(CH₃)₂ H H CD₃ H H 1072. Se CD₃ H CD₃ H CD₃ H H 1073. Se CD(CH₃)₂ H CD(CH₃)₂ H CD₃ H H 1074. Se CD₂CH(CH₃)₂ H CD₂CH(CH₃)₂ H CD₃ H H 1075. Se CD₃ H H CD₃ CD₃ H H 1076. Se CD(CH₃)₂ H H CD(CH₃)₂ CD₃ H H 1077. Se CD₂CH(CH₃)₂ H H CD₂CH(CH₃)₂ CD₃ H H 1078. Se H CD₃ H CD₃ CD₃ H H 1079. Se H CD(CH₃)₂ H CD(CH₃)₂ CD₃ H H 1080. Se H CD₂CH(CH₃)₂ H CD₂CH(CH₃)₂ CD₃ H H 1081. Se CD₃ H H H H H CD₃ 1082. Se CD(CH₃)₂ H H H H H CD₃ 1083. Se CD₂CH(CH₃)₂ H H H H H CD₃ 1084. Se H CD₃ H H H H CD₃ 1085. Se H CD(CH₃)₂ H H H H CD₃ 1086. Se H CD₂CH(CH₃)₂ H H H H CD₃ 1087. Se H H CD₃ H H H CD₃ 1088. Se H H CD(CH₃)₂ H H H CD₃ 1089. Se H H CD₂CH(CH₃)₂ H H H CD₃ 1090. Se H H H CD₃ H H CD₃ 1091. Se H H H CD(CH₃)₂ H H CD₃ 1092. Se H H H CD₂CH(CH₃)₂ H H CD₃ 1093. Se CD₃ CD₃ H H H H CD₃ 1094. Se CD(CH₃)₂ CD(CH₃)₂ H H H H CD₃ 1095. Se CD₂CH(CH₃)₂ CD₂CH(CH₃)₂ H H H H CD₃ 1096. Se CD₃ H CD₃ H H H CD₃ 1097. Se CD(CH₃)₂ H CD(CH₃)₂ H H H CD₃ 1098. Se CD₂CH(CH₃)₂ H CD₂CH(CH₃)₂ H H H CD₃ 1099. Se CD₃ H H CD₃ H H CD₃ 1100. Se CD(CH₃)₂ H H CD(CH₃)₂ H H CD₃ 1101. Se CD₂CH(CH₃)₂ H H CD₂CH(CH₃)₂ H H CD₃ 1102. Se H CD₃ H CD₃ H H CD₃ 1103. Se H CD(CH₃)₂ H CD(CH₃)₂ H H CD₃ 1104. Se H CD₂CH(CH₃)₂ H CD₂CH(CH₃)₂ H H CD₃ 1105. Se CD₃ H H H CD₃ H CD₃ 1106. Se CD(CH₃)₂ H H H CD₃ H CD₃ 1107. Se CD₂CH(CH₃)₂ H H H CD₃ H CD₃ 1108. Se H CD₃ H H CD₃ H CD₃ 1109. Se H CD(CH₃)₂ H H CD₃ H CD₃ 1110. Se H CD₂CH(CH₃)₂ H H CD₃ H CD₃ 1111. Se H H CD₃ H CD₃ H CD₃ 1112. Se H H CD(CH₃)₂ H CD₃ H CD₃ 1113. Se H H CD₂CH(CH₃)₂ H CD₃ H CD₃ 1114. Se H H H CD₃ CD₃ H CD₃ 1115. Se H H H CD(CH₃)₂ CD₃ H CD₃ 1116. Se H H H CD₂CH(CH₃)₂ CD₃ H CD₃ 1117. Se CD₃ CD₃ H H CD₃ H CD₃ 1118. Se CD(CH₃)₂ CD(CH₃)₂ H H CD₃ H CD₃ 1119. Se CD₂CH(CH₃)₂ CD₂CH(CH₃)₂ H H CD₃ H CD₃ 1120. Se CD₃ H CD₃ H CD₃ H CD₃ 1121. Se CD(CH₃)₂ H CD(CH₃)₂ H CD₃ H CD₃ 1122. Se CD₂CH(CH₃)₂ H CD₂CH(CH₃)₂ H CD₃ H CD₃ 1123. Se CD₃ H H CD₃ CD₃ H CD₃ 1124. Se CD(CH₃)₂ H H CD(CH₃)₂ CD₃ H CD₃ 1125. Se CD₂CH(CH₃)₂ H H CD₂CH(CH₃)₂ CD₃ H CD₃ 1126. Se H CD₃ H CD₃ CD₃ H CD₃ 1127. Se H CD(CH₃)₂ H CD(CH₃)₂ CD₃ H CD₃ 1128. Se H CD₂CH(CH₃)₂ H CD₂CH(CH₃)₂ CD₃ H CD₃ 1129. Se CD₃ H H H CD₃ F CD₃ 1130. Se CD(CH₃)₂ H H H CD₃ F CD₃ 1131. Se CD₂CH(CH₃)₂ H H H CD₃ F CD₃ 1132. Se H CD₃ H H CD₃ F CD₃ 1133. Se H CD(CH₃)₂ H H CD₃ F CD₃ 1134. Se H CD₂CH(CH₃)₂ H H CD₃ F CD₃ 1135. Se H H CD₃ H CD₃ F CD₃ 1136. Se H H CD(CH₃)₂ H CD₃ F CD₃ 1137. Se H H CD₂CH(CH₃)₂ H CD₃ F CD₃ 1138. Se H H H CD₃ CD₃ F CD₃ 1139. Se H H H CD(CH₃)₂ CD₃ F CD₃ 1140. Se H H H CD₂CH(CH₃)₂ CD₃ F CD₃ 1141. Se CD₃ CD₃ H H CD₃ F CD₃ 1142. Se CD(CH₃)₂ CD(CH₃)₂ H H CD₃ F CD₃ 1143. Se CD₂CH(CH₃)₂ CD₂CH(CH₃)₂ H H CD₃ F CD₃ 1144. Se CD₃ H CD₃ H CD₃ F CD₃ 1145. Se CD(CH₃)₂ H CD(CH₃)₂ H CD₃ F CD₃ 1146. Se CD₂CH(CH₃)₂ H CD₂CH(CH₃)₂ H CD₃ F CD₃ 1147. Se CD₃ H H CD₃ CD₃ F CD₃ 1148. Se CD(CH₃)₂ H H CD(CH₃)₂ CD₃ F CD₃ 1149. Se CD₂CH(CH₃)₂ H H CD₂CH(CH₃)₂ CD₃ F CD₃ 1150. Se H CD₃ H CD₃ CD₃ F CD₃ 1151. Se H CD(CH₃)₂ H CD(CH₃)₂ CD₃ F CD₃ 1152. Se H CD₂CH(CH₃)₂ H CD₂CH(CH₃)₂ CD₃ F CD₃ 1153. (CH₃)₂Si CH₃ H H H H H H 1154. (CH₃)₂Si CH(CH₃)₂ H H H H H H 1155. (CH₃)₂Si CH₂CH₃ H H H H H H 1156. (CH₃)₂Si CH₂CH(CH₃)₂ H H H H H H 1157. (CH₃)₂Si CH₂C(CH₃)₃ H H H H H H 1158. (CH₃)₂Si

H H H H H H 1159. (CH₃)₂Si CH₂CF₃ H H H H H H 1160. (CH₃)₂Si CH₂CH₂CF₃ H H H H H H 1161. (CH₃)₂Si CH₂C(CH₃)₂CF₃ H H H H H H 1162. (CH₃)₂Si CD₃ H H H H H H 1163. (CH₃)₂Si CD(CH₃)₂ H H H H H H 1164. (CH₃)₂Si CD₂CH(CH₃)₂ H H H H H H 1165. (CH₃)₂Si H CH₃ H H H H H 1166. (CH₃)₂Si H CH(CH₃)₂ H H H H H 1167. (CH₃)₂Si H CH₂CH₃ H H H H H 1168. (CH₃)₂Si H CH₂CH(CH₃)₂ H H H H H 1169. (CH₃)₂Si H CH₂C(CH₃)₃ H H H H H 1170. (CH₃)₂Si H

H H H H H 1171. (CH₃)₂Si H CH₂CF₃ H H H H H 1172. (CH₃)₂Si H CH₂CH₂CF₃ H H H H H 1173. (CH₃)₂Si H CH₂C(CH₃)₂CF₃ H H H H H 1174. (CH₃)₂Si H CD₃ H H H H H 1175. (CH₃)₂Si H CD(CH₃)₂ H H H H H 1176. (CH₃)₂Si H CD₂CH(CH₃)₂ H H H H H 1177. (CH₃)₂Si H H CH₃ H H H H 1178. (CH₃)₂Si H H CH(CH₃)₂ H H H H 1179. (CH₃)₂Si H H CH₂CH₃ H H H H 1180. (CH₃)₂Si H H CH₂CH(CH₃)₂ H H H H 1181. (CH₃)₂Si H H CH₂C(CH₃)₃ H H H H 1182. (CH₃)₂Si H H

H H H H 1183. (CH₃)₂Si H H CH₂CF₃ H H H H 1184. (CH₃)₂Si H H CH₂CH₂CF₃ H H H H 1185. (CH₃)₂Si H H CH₂C(CH₃)₂CF₃ H H H H 1186. (CH₃)₂Si H H CD₃ H H H H 1187. (CH₃)₂Si H H CD(CH₃)₂ H H H H 1188. (CH₃)₂Si H H CD₂CH(CH₃)₂ H H H H 1189. (CH₃)₂Si H H H CH₃ H H H 1190. (CH₃)₂Si H H H CH(CH₃)₂ H H H 1191. (CH₃)₂Si H H H CH₂CH₃ H H H 1192. (CH₃)₂Si H H H CH₂CH(CH₃)₂ H H H 1193. (CH₃)₂Si H H H CH₂C(CH₃)₃ H H H 1194. (CH₃)₂Si H H H

H H H 1195. (CH₃)₂Si H H H CH₂CF₃ H H H 1196. (CH₃)₂Si H H H CH₂CH₂CF₃ H H H 1197. (CH₃)₂Si H H H CH₂C(CH₃)₂CF₃ H H H 1198. (CH₃)₂Si H H H CD₃ H H H 1199. (CH₃)₂Si H H H CD(CH₃)₂ H H H 1200. (CH₃)₂Si H H H CD₂CH(CH₃)₂ H H H 1201. (CH₃)₂Si CH₃ CH₃ H H H H H 1202. (CH₃)₂Si CH(CH₃)₂ CH(CH₃)₂ H H H H H 1203. (CH₃)₂Si CH₂CH₃ CH₂CH₃ H H H H H 1204. (CH₃)₂Si CH₂CH(CH₃)₂ CH₂CH(CH₃)₂ H H H H H 1205. (CH₃)₂Si CH₂C(CH₃)₃ CH₂C(CH₃)₃ H H H H H 1206. (CH₃)₂Si

H H H H H 1207. (CH₃)₂Si CH₂CF₃ CH₂CF₃ H H H H H 1208. (CH₃)₂Si CH₂CH₂CF₃ CH₂CH₂CF₃ H H H H H 1209. (CH₃)₂Si CH₂C(CH₃)₂CF₃ CH₂C(CH₃)₂CF₃ H H H H H 1210. (CH₃)₂Si CD₃ CD₃ H H H H H 1211. (CH₃)₂Si CD(CH₃)₂ CD(CH₃)₂ H H H H H 1212. (CH₃)₂Si CD₂CH(CH₃)₂ CD₂CH(CH₃)₂ H H H H H 1213. (CH₃)₂Si CH₃ H CH₃ H H H H 1214. (CH₃)₂Si CH(CH₃)₂ H CH(CH₃)₂ H H H H 1215. (CH₃)₂Si CH₂CH₃ H CH₂CH₃ H H H H 1216. (CH₃)₂Si CH₂CH(CH₃)₂ H CH₂CH(CH₃)₂ H H H H 1217. (CH₃)₂Si CH₂C(CH₃)₃ H CH₂C(CH₃)₃ H H H H 1218. (CH₃)₂Si

H

H H H H 1219. (CH₃)₂Si CH₂CF₃ H CH₂CF₃ H H H H 1220. (CH₃)₂Si CH₂CH₂CF₃ H CH₂CH₂CF₃ H H H H 1221. (CH₃)₂Si CH₂C(CH₃)₂CF₃ H CH₂C(CH₃)₂CF₃ H H H H 1222. (CH₃)₂Si CD₃ H CD₃ H H H H 1223. (CH₃)₂Si CD(CH₃)₂ H CD(CH₃)₂ H H H H 1224. (CH₃)₂Si CD₂CH(CH₃)₂ H CD₂CH(CH₃)₂ H H H H 1225. (CH₃)₂Si CH₃ H H CH₃ H H H 1226. (CH₃)₂Si CH(CH₃)₂ H H CH(CH₃)₂ H H H 1227. (CH₃)₂Si CH₂CH₃ H H CH₂CH₃ H H H 1228. (CH₃)₂Si CH₂CH(CH₃)₂ H H CH₂CH(CH₃)₂ H H H 1229. (CH₃)₂Si CH₂C(CH₃)₃ H H CH₂C(CH₃)₃ H H H 1230. (CH₃)₂Si

H H

H H H 1231. (CH₃)₂Si CH₂CF₃ H H CH₂CF₃ H H H 1232. (CH₃)₂Si CH₂CH₂CF₃ H H CH₂CH₂CF₃ H H H 1233. (CH₃)₂Si CH₂C(CH₃)₂CF₃ H H CH₂C(CH₃)₂CF₃ H H H 1234. (CH₃)₂Si CD₃ H H CD₃ H H H 1235. (CH₃)₂Si CD(CH₃)₂ H H CD(CH₃)₂ H H H 1236. (CH₃)₂Si CD₂CH(CH₃)₂ H H CD₂CH(CH₃)₂ H H H 1237. (CH₃)₂Si H CH₃ H CH₃ H H H 1238. (CH₃)₂Si H CH(CH₃)₂ H CH(CH₃)₂ H H H 1239. (CH₃)₂Si H CH₂CH₃ H CH₂CH₃ H H H 1240. (CH₃)₂Si H CH₂CH(CH₃)₂ H CH₂CH(CH₃)₂ H H H 1241. (CH₃)₂Si H CH₂C(CH₃)₃ H CH₂C(CH₃)₃ H H H 1242. (CH₃)₂Si H

H

H H H 1243. (CH₃)₂Si H CH₂CF₃ H CH₂CF₃ H H H 1244. (CH₃)₂Si H CH₂CH₂CF₃ H CH₂CH₂CF₃ H H H 1245. (CH₃)₂Si H CH₂C(CH₃)₂CF₃ H CH₂C(CH₃)₂CF₃ H H H 1246. (CH₃)₂Si H CD₃ H CD₃ H H H 1247. (CH₃)₂Si H CD(CH₃)₂ H CD(CH₃)₂ H H H 1248. (CH₃)₂Si H CD₂CH(CH₃)₂ H CD₂CH(CH₃)₂ H H H 1249. (CH₃)₂Si CH₃ H H H CH₃ H H 1250. (CH₃)₂Si CH(CH₃)₂ H H H CH₃ H H 1251. (CH₃)₂Si CH₂CH₃ H H H CH₃ H H 1252. (CH₃)₂Si CH₂CH(CH₃)₂ H H H CH₃ H H 1253. (CH₃)₂Si CH₂C(CH₃)₃ H H H CH₃ H H 1254. (CH₃)₂Si

H H H CH₃ H H 1255. (CH₃)₂Si CH₂CF₃ H H H CH₃ H H 1256. (CH₃)₂Si CH₂CH₂CF₃ H H H CH₃ H H 1257. (CH₃)₂Si CH₂C(CH₃)₂CF₃ H H H CH₃ H H 1258. (CH₃)₂Si CD₃ H H H CH₃ H H 1259. (CH₃)₂Si CD(CH₃)₂ H H H CH₃ H H 1260. (CH₃)₂Si CD₂CH(CH₃)₂ H H H CH₃ H H 1261. (CH₃)₂Si H CH₃ H H CH₃ H H 1262. (CH₃)₂Si H CH(CH₃)₂ H H CH₃ H H 1263. (CH₃)₂Si H CH₂CH₃ H H CH₃ H H 1264. (CH₃)₂Si H CH₂CH(CH₃)₂ H H CH₃ H H 1265. (CH₃)₂Si H CH₂C(CH₃)₃ H H CH₃ H H 1266. (CH₃)₂Si H

H H CH₃ H H 1267. (CH₃)₂Si H CH₂CF₃ H H CH₃ H H 1268. (CH₃)₂Si H CH₂CH₂CF₃ H H CH₃ H H 1269. (CH₃)₂Si H CH₂C(CH₃)₂CF₃ H H CH₃ H H 1270. (CH₃)₂Si H CD₃ H H CH₃ H H 1271. (CH₃)₂Si H CD(CH₃)₂ H H CH₃ H H 1272. (CH₃)₂Si H CD₂CH(CH₃)₂ H H CH₃ H H 1273. (CH₃)₂Si H H CH₃ H CH₃ H H 1274. (CH₃)₂Si H H CH(CH₃)₂ H CH₃ H H 1275. (CH₃)₂Si H H CH₂CH₃ H CH₃ H H 1276. (CH₃)₂Si H H CH₂CH(CH₃)₂ H CH₃ H H 1277. (CH₃)₂Si H H CH₂C(CH₃)₃ H CH₃ H H 1278. (CH₃)₂Si H H

H CH₃ H H 1279. (CH₃)₂Si H H CH₂CF₃ H CH₃ H H 1280. (CH₃)₂Si H H CH₂CH₂CF₃ H CH₃ H H 1281. (CH₃)₂Si H H CH₂C(CH₃)₂CF₃ H CH₃ H H 1282. (CH₃)₂Si H H CD₃ H CH₃ H H 1283. (CH₃)₂Si H H CD(CH₃)₂ H CH₃ H H 1284. (CH₃)₂Si H H CD₂CH(CH₃)₂ H CH₃ H H 1285. (CH₃)₂Si H H H CH₃ CH₃ H H 1286. (CH₃)₂Si H H H CH(CH₃)₂ CH₃ H H 1287. (CH₃)₂Si H H H CH₂CH₃ CH₃ H H 1288. (CH₃)₂Si H H H CH₂CH(CH₃)₂ CH₃ H H 1289. (CH₃)₂Si H H H CH₂C(CH₃)₃ CH₃ H H 1290. (CH₃)₂Si H H H

CH₃ H H 1291. (CH₃)₂Si H H H CH₂CF₃ CH₃ H H 1292. (CH₃)₂Si H H H CH₂CH₂CF₃ CH₃ H H 1293. (CH₃)₂Si H H H CH₂C(CH₃)₂CF₃ CH₃ H H 1294. (CH₃)₂Si H H H CD₃ CH₃ H H 1295. (CH₃)₂Si H H H CD(CH₃)₂ CH₃ H H 1296. (CH₃)₂Si H H H CD₂CH(CH₃)₂ CH₃ H H 1297. (CH₃)₂Si CH₃ CH₃ H H CH₃ H H 1298. (CH₃)₂Si CH(CH₃)₂ CH(CH₃)₂ H H CH₃ H H 1299. (CH₃)₂Si CH₂CH₃ CH₂CH₃ H H CH₃ H H 1300. (CH₃)₂Si CH₂CH(CH₃)₂ CH₂CH(CH₃)₂ H H CH₃ H H 1301. (CH₃)₂Si CH₂C(CH₃)₃ CH₂C(CH₃)₃ H H CH₃ H H 1302. (CH₃)₂Si

H H CH₃ H H 1303. (CH₃)₂Si CH₂CF₃ CH₂CF₃ H H CH₃ H H 1304. (CH₃)₂Si CH₂CH₂CF₃ CH₂CH₂CF₃ H H CH₃ H H 1305. (CH₃)₂Si CH₂C(CH₃)₂CF₃ CH₂C(CH₃)₂CF₃ H H CH₃ H H 1306. (CH₃)₂Si CD₃ CD₃ H H CH₃ H H 1307. (CH₃)₂Si CD(CH₃)₂ CD(CH₃)₂ H H CH₃ H H 1308. (CH₃)₂Si CD₂CH(CH₃)₂ CD₂CH(CH₃)₂ H H CH₃ H H 1309. (CH₃)₂Si CH₃ H CH₃ H CH₃ H H 1310. (CH₃)₂Si CH(CH₃)₂ H CH(CH₃)₂ H CH₃ H H 1311. (CH₃)₂Si CH₂CH₃ H CH₂CH₃ H CH₃ H H 1312. (CH₃)₂Si CH₂CH(CH₃)₂ H CH₂CH(CH₃)₂ H CH₃ H H 1313. (CH₃)₂Si CH₂C(CH₃)₃ H CH₂C(CH₃)₃ H CH₃ H H 1314. (CH₃)₂Si

H

H CH₃ H H 1315. (CH₃)₂Si CH₂CF₃ H CH₂CF₃ H CH₃ H H 1316. (CH₃)₂Si CH₂CH₂CF₃ H CH₂CH₂CF₃ H CH₃ H H 1317. (CH₃)₂Si CH₂C(CH₃)₂CF₃ H CH₂C(CH₃)₂CF₃ H CH₃ H H 1318. (CH₃)₂Si CD₃ H CD₃ H CH₃ H H 1319. (CH₃)₂Si CD(CH₃)₂ H CD(CH₃)₂ H CH₃ H H 1320. (CH₃)₂Si CD₂CH(CH₃)₂ H CD₂CH(CH₃)₂ H CH₃ H H 1321. (CH₃)₂Si CH₃ H H CH₃ CH₃ H H 1322. (CH₃)₂Si CH(CH₃)₂ H H CH(CH₃)₂ CH₃ H H 1323. (CH₃)₂Si CH₂CH₃ H H CH₂CH₃ CH₃ H H 1324. (CH₃)₂Si CH₂CH(CH₃)₂ H H CH₂CH(CH₃)₂ CH₃ H H 1325. (CH₃)₂Si CH₂C(CH₃)₃ H H CH₂C(CH₃)₃ CH₃ H H 1326. (CH₃)₂Si

H H

CH₃ H H 1327. (CH₃)₂Si CH₂CF₃ H H CH₂CF₃ CH₃ H H 1328. (CH₃)₂Si CH₂CH₂CF₃ H H CH₂CH₂CF₃ CH₃ H H 1329. (CH₃)₂Si CH₂C(CH₃)₂CF₃ H H CH₂C(CH₃)₂CF₃ CH₃ H H 1330. (CH₃)₂Si CD₃ H H CD₃ CH₃ H H 1331. (CH₃)₂Si CD(CH₃)₂ H H CD(CH₃)₂ CH₃ H H 1332. (CH₃)₂Si CD₂CH(CH₃)₂ H H CD₂CH(CH₃)₂ CH₃ H H 1333. (CH₃)₂Si H CH₃ H CH₃ CH₃ H H 1334. (CH₃)₂Si H CH(CH₃)₂ H CH(CH₃)₂ CH₃ H H 1335. (CH₃)₂Si H CH₂CH₃ H CH₂CH₃ CH₃ H H 1336. (CH₃)₂Si H CH₂CH(CH₃)₂ H CH₂CH(CH₃)₂ CH₃ H H 1337. (CH₃)₂Si H CH₂C(CH₃)₃ H CH₂C(CH₃)₃ CH₃ H H 1338. (CH₃)₂Si H

H

CH₃ H H 1339. (CH₃)₂Si H CH₂CF₃ H CH₂CF₃ CH₃ H H 1340. (CH₃)₂Si H CH₂CH₂CF₃ H CH₂CH₂CF₃ CH₃ H H 1341. (CH₃)₂Si H CH₂C(CH₃)₂CF₃ H CH₂C(CH₃)₂CF₃ CH₃ H H 1342. (CH₃)₂Si H CD₃ H CD₃ CH₃ H H 1343. (CH₃)₂Si H CD(CH₃)₂ H CD(CH₃)₂ CH₃ H H 1344. (CH₃)₂Si H CD₂CH(CH₃)₂ H CD₂CH(CH₃)₂ CH₃ H H 1345. (CH₃)₂Si CH₃ H H H H H CH₃ 1346. (CH₃)₂Si CH(CH₃)₂ H H H H H CH₃ 1347. (CH₃)₂Si CH₂CH₃ H H H H H CH₃ 1348. (CH₃)₂Si CH₂CH(CH₃)₂ H H H H H CH₃ 1349. (CH₃)₂Si CH₂C(CH₃)₃ H H H H H CH₃ 1350. (CH₃)₂Si

H H H H H CH₃ 1351. (CH₃)₂Si CH₂CF₃ H H H H H CH₃ 1352. (CH₃)₂Si CH₂CH₂CF₃ H H H H H CH₃ 1353. (CH₃)₂Si CH₂C(CH₃)₂CF₃ H H H H H CH₃ 1354. (CH₃)₂Si CD₃ H H H H H CH₃ 1355. (CH₃)₂Si CD(CH₃)₂ H H H H H CH₃ 1356. (CH₃)₂Si CD₂CH(CH₃)₂ H H H H H CH₃ 1357. (CH₃)₂Si H CH₃ H H H H CH₃ 1358. (CH₃)₂Si H CH(CH₃)₂ H H H H CH₃ 1359. (CH₃)₂Si H CH₂CH₃ H H H H CH₃ 1360. (CH₃)₂Si H CH₂CH(CH₃)₂ H H H H CH₃ 1361. (CH₃)₂Si H CH₂C(CH₃)₃ H H H H CH₃ 1362. (CH₃)₂Si H

H H H H CH₃ 1363. (CH₃)₂Si H CH₂CF₃ H H H H CH₃ 1364. (CH₃)₂Si H CH₂CH₂CF₃ H H H H CH₃ 1365. (CH₃)₂Si H CH₂C(CH₃)₂CF₃ H H H H CH₃ 1366. (CH₃)₂Si H CD₃ H H H H CH₃ 1367. (CH₃)₂Si H CD(CH₃)₂ H H H H CH₃ 1368. (CH₃)₂Si H CD₂CH(CH₃)₂ H H H H CH₃ 1369. (CH₃)₂Si H H CH₃ H H H CH₃ 1370. (CH₃)₂Si H H CH(CH₃)₂ H H H CH₃ 1371. (CH₃)₂Si H H CH₂CH₃ H H H CH₃ 1372. (CH₃)₂Si H H CH₂CH(CH₃)₂ H H H CH₃ 1373. (CH₃)₂Si H H CH₂C(CH₃)₃ H H H CH₃ 1374. (CH₃)₂Si H H

H H H CH₃ 1375. (CH₃)₂Si H H CH₂CF₃ H H H CH₃ 1376. (CH₃)₂Si H H CH₂CH₂CF₃ H H H CH₃ 1377. (CH₃)₂Si H H CH₂C(CH₃)₂CF₃ H H H CH₃ 1378. (CH₃)₂Si H H CD₃ H H H CH₃ 1379. (CH₃)₂Si H H CD(CH₃)₂ H H H CH₃ 1380. (CH₃)₂Si H H CD₂CH(CH₃)₂ H H H CH₃ 1381. (CH₃)₂Si H H H CH₃ H H CH₃ 1382. (CH₃)₂Si H H H CH(CH₃)₂ H H CH₃ 1383. (CH₃)₂Si H H H CH₂CH₃ H H CH₃ 1384. (CH₃)₂Si H H H CH₂CH(CH₃)₂ H H CH₃ 1385. (CH₃)₂Si H H H CH₂C(CH₃)₃ H H CH₃ 1386. (CH₃)₂Si H H H

H H CH₃ 1387. (CH₃)₂Si H H H CH₂CF₃ H H CH₃ 1388. (CH₃)₂Si H H H CH₂CH₂CF₃ H H CH₃ 1389. (CH₃)₂Si H H H CH₂C(CH₃)₂CF₃ H H CH₃ 1390. (CH₃)₂Si H H H CD₃ H H CH₃ 1391. (CH₃)₂Si H H H CD(CH₃)₂ H H CH₃ 1392. (CH₃)₂Si H H H CD₂CH(CH₃)₂ H H CH₃ 1393. (CH₃)₂Si CH₃ CH₃ H H H H CH₃ 1394. (CH₃)₂Si CH(CH₃)₂ CH(CH₃)₂ H H H H CH₃ 1395. (CH₃)₂Si CH₂CH₃ CH₂CH₃ H H H H CH₃ 1396. (CH₃)₂Si CH₂CH(CH₃)₂ CH₂CH(CH₃)₂ H H H H CH₃ 1397. (CH₃)₂Si CH₂C(CH₃)₃ CH₂C(CH₃)₃ H H H H CH₃ 1398. (CH₃)₂Si

H H H H CH₃ 1399. (CH₃)₂Si CH₂CF₃ CH₂CF₃ H H H H CH₃ 1400. (CH₃)₂Si CH₂CH₂CF₃ CH₂CH₂CF₃ H H H H CH₃ 1401. (CH₃)₂Si CH₂C(CH₃)₂CF₃ CH₂C(CH₃)₂CF₃ H H H H CH₃ 1402. (CH₃)₂Si CD₃ CD₃ H H H H CH₃ 1403. (CH₃)₂Si CD(CH₃)₂ CD(CH₃)₂ H H H H CH₃ 1404. (CH₃)₂Si CD₂CH(CH₃)₂ CD₂CH(CH₃)₂ H H H H CH₃ 1405. (CH₃)₂Si CH₃ H CH₃ H H H CH₃ 1406. (CH₃)₂Si CH(CH₃)₂ H CH(CH₃)₂ H H H CH₃ 1407. (CH₃)₂Si CH₂CH₃ H CH₂CH₃ H H H CH₃ 1408. (CH₃)₂Si CH₂CH(CH₃)₂ H CH₂CH(CH₃)₂ H H H CH₃ 1409. (CH₃)₂Si CH₂C(CH₃)₃ H CH₂C(CH₃)₃ H H H CH₃ 1410. (CH₃)₂Si

H

H H H CH₃ 1411. (CH₃)₂Si CH₂CF₃ H CH₂CF₃ H H H CH₃ 1412. (CH₃)₂Si CH₂CH₂CF₃ H CH₂CH₂CF₃ H H H CH₃ 1413. (CH₃)₂Si CH₂C(CH₃)₂CF₃ H CH₂C(CH₃)₂CF₃ H H H CH₃ 1414. (CH₃)₂Si CD₃ H CD₃ H H H CH₃ 1415. (CH₃)₂Si CD(CH₃)₂ H CD(CH₃)₂ H H H CH₃ 1416. (CH₃)₂Si CD₂CH(CH₃)₂ H CD₂CH(CH₃)₂ H H H CH₃ 1417. (CH₃)₂Si CH₃ H H CH₃ H H CH₃ 1418. (CH₃)₂Si CH(CH₃)₂ H H CH(CH₃)₂ H H CH₃ 1419. (CH₃)₂Si CH₂CH₃ H H CH₂CH₃ H H CH₃ 1420. (CH₃)₂Si CH₂CH(CH₃)₂ H H CH₂CH(CH₃)₂ H H CH₃ 1421. (CH₃)₂Si CH₂C(CH₃)₃ H H CH₂C(CH₃)₃ H H CH₃ 1422. (CH₃)₂Si

H H

H H CH₃ 1423. (CH₃)₂Si CH₂CF₃ H H CH₂CF₃ H H CH₃ 1424. (CH₃)₂Si CH₂CH₂CF₃ H H CH₂CH₂CF₃ H H CH₃ 1425. (CH₃)₂Si CH₂C(CH₃)₂CF₃ H H CH₂C(CH₃)₂CF₃ H H CH₃ 1426. (CH₃)₂Si CD₃ H H CD₃ H H CH₃ 1427. (CH₃)₂Si CD(CH₃)₂ H H CD(CH₃)₂ H H CH₃ 1428. (CH₃)₂Si CD₂CH(CH₃)₂ H H CD₂CH(CH₃)₂ H H CH₃ 1429. (CH₃)₂Si H CH₃ H CH₃ H H CH₃ 1430. (CH₃)₂Si H CH(CH₃)₂ H CH(CH₃)₂ H H CH₃ 1431. (CH₃)₂Si H CH₂CH₃ H CH₂CH₃ H H CH₃ 1432. (CH₃)₂Si H CH₂CH(CH₃)₂ H CH₂CH(CH₃)₂ H H CH₃ 1433. (CH₃)₂Si H CH₂C(CH₃)₃ H CH₂C(CH₃)₃ H H CH₃ 1434. (CH₃)₂Si H

H

H H CH₃ 1435. (CH₃)₂Si H CH₂CF₃ H CH₂CF₃ H H CH₃ 1436. (CH₃)₂Si H CH₂CH₂CF₃ H CH₂CH₂CF₃ H H CH₃ 1437. (CH₃)₂Si H CH₂C(CH₃)₂CF₃ H CH₂C(CH₃)₂CF₃ H H CH₃ 1438. (CH₃)₂Si H CD₃ H CD₃ H H CH₃ 1439. (CH₃)₂Si H CD(CH₃)₂ H CD(CH₃)₂ H H CH₃ 1440. (CH₃)₂Si H CD₂CH(CH₃)₂ H CD₂CH(CH₃)₂ H H CH₃ 1441. (CH₃)₂Si CH₃ H H H CH₃ H CH₃ 1442. (CH₃)₂Si CH(CH₃)₂ H H H CH₃ H CH₃ 1443. (CH₃)₂Si CH₂CH₃ H H H CH₃ H CH₃ 1444. (CH₃)₂Si CH₂CH(CH₃)₂ H H H CH₃ H CH₃ 1445. (CH₃)₂Si CH₂C(CH₃)₃ H H H CH₃ H CH₃ 1446. (CH₃)₂Si

H H H CH₃ H CH₃ 1447. (CH₃)₂Si CH₂CF₃ H H H CH₃ H CH₃ 1448. (CH₃)₂Si CH₂CH₂CF₃ H H H CH₃ H CH₃ 1449. (CH₃)₂Si CH₂C(CH₃)₂CF₃ H H H CH₃ H CH₃ 1450. (CH₃)₂Si CD₃ H H H CH₃ H CH₃ 1451. (CH₃)₂Si CD(CH₃)₂ H H H CH₃ H CH₃ 1452. (CH₃)₂Si CD₂CH(CH₃)₂ H H H CH₃ H CH₃ 1453. (CH₃)₂Si H CH₃ H H CH₃ H CH₃ 1454. (CH₃)₂Si H CH(CH₃)₂ H H CH₃ H CH₃ 1455. (CH₃)₂Si H CH₂CH₃ H H CH₃ H CH₃ 1456. (CH₃)₂Si H CH₂CH(CH₃)₂ H H CH₃ H CH₃ 1457. (CH₃)₂Si H CH₂C(CH₃)₃ H H CH₃ H CH₃ 1458. (CH₃)₂Si H

H H CH₃ H CH₃ 1459. (CH₃)₂Si H CH₂CF₃ H H CH₃ H CH₃ 1460. (CH₃)₂Si H CH₂CH₂CF₃ H H CH₃ H CH₃ 1461. (CH₃)₂Si H CH₂C(CH₃)₂CF₃ H H CH₃ H CH₃ 1462. (CH₃)₂Si H CD₃ H H CH₃ H CH₃ 1463. (CH₃)₂Si H CD(CH₃)₂ H H CH₃ H CH₃ 1464. (CH₃)₂Si H CD₂CH(CH₃)₂ H H CH₃ H CH₃ 1465. (CH₃)₂Si H H CH₃ H CH₃ H CH₃ 1466. (CH₃)₂Si H H CH(CH₃)₂ H CH₃ H CH₃ 1467. (CH₃)₂Si H H CH₂CH₃ H CH₃ H CH₃ 1468. (CH₃)₂Si H H CH₂CH(CH₃)₂ H CH₃ H CH₃ 1469. (CH₃)₂Si H H CH₂C(CH₃)₃ H CH₃ H CH₃ 1470. (CH₃)₂Si H H

H CH₃ H CH₃ 1471. (CH₃)₂Si H H CH₂CF₃ H CH₃ H CH₃ 1472. (CH₃)₂Si H H CH₂CH₂CF₃ H CH₃ H CH₃ 1473. (CH₃)₂Si H H CH₂C(CH₃)₂CF₃ H CH₃ H CH₃ 1474. (CH₃)₂Si H H CD₃ H CH₃ H CH₃ 1475. (CH₃)₂Si H H CD(CH₃)₂ H CH₃ H CH₃ 1476. (CH₃)₂Si H H CD₂CH(CH₃)₂ H CH₃ H CH₃ 1477. (CH₃)₂Si H H H CH₃ CH₃ H CH₃ 1478. (CH₃)₂Si H H H CH(CH₃)₂ CH₃ H CH₃ 1479. (CH₃)₂Si H H H CH₂CH₃ CH₃ H CH₃ 1480. (CH₃)₂Si H H H CH₂CH(CH₃)₂ CH₃ H CH₃ 1481. (CH₃)₂Si H H H CH₂C(CH₃)₃ CH₃ H CH₃ 1482. (CH₃)₂Si H H H

CH₃ H CH₃ 1483. (CH₃)₂Si H H H CH₂CF₃ CH₃ H CH₃ 1484. (CH₃)₂Si H H H CH₂CH₂CF₃ CH₃ H CH₃ 1485. (CH₃)₂Si H H H CH₂C(CH₃)₂CF₃ CH₃ H CH₃ 1486. (CH₃)₂Si H H H CD₃ CH₃ H CH₃ 1487. (CH₃)₂Si H H H CD(CH₃)₂ CH₃ H CH₃ 1488. (CH₃)₂Si H H H CD₂CH(CH₃)₂ CH₃ H CH₃ 1489. (CH₃)₂Si CH₃ CH₃ H H CH₃ H CH₃ 1490. (CH₃)₂Si CH(CH₃)₂ CH(CH₃)₂ H H CH₃ H CH₃ 1491. (CH₃)₂Si CH₂CH₃ CH₂CH₃ H H CH₃ H CH₃ 1492. (CH₃)₂Si CH₂CH(CH₃)₂ CH₂CH(CH₃)₂ H H CH₃ H CH₃ 1493. (CH₃)₂Si CH₂C(CH₃)₃ CH₂C(CH₃)₃ H H CH₃ H CH₃ 1494. (CH₃)₂Si

H H CH₃ H CH₃ 1495. (CH₃)₂Si CH₂CF₃ CH₂CF₃ H H CH₃ H CH₃ 1496. (CH₃)₂Si CH₂CH₂CF₃ CH₂CH₂CF₃ H H CH₃ H CH₃ 1497. (CH₃)₂Si CH₂C(CH₃)₂CF₃ CH₂C(CH₃)₂CF₃ H H CH₃ H CH₃ 1498. (CH₃)₂Si CD₃ CD₃ H H CH₃ H CH₃ 1499. (CH₃)₂Si CD(CH₃)₂ CD(CH₃)₂ H H CH₃ H CH₃ 1500. (CH₃)₂Si CD₂CH(CH₃)₂ CD₂CH(CH₃)₂ H H CH₃ H CH₃ 1501. (CH₃)₂Si CH₃ H CH₃ H CH₃ H CH₃ 1502. (CH₃)₂Si CH(CH₃)₂ H CH(CH₃)₂ H CH₃ H CH₃ 1503. (CH₃)₂Si CH₂CH₃ H CH₂CH₃ H CH₃ H CH₃ 1504. (CH₃)₂Si CH₂CH(CH₃)₂ H CH₂CH(CH₃)₂ H CH₃ H CH₃ 1505. (CH₃)₂Si CH₂C(CH₃)₃ H CH₂C(CH₃)₃ H CH₃ H CH₃ 1506. (CH₃)₂Si

H

H CH₃ H CH₃ 1507. (CH₃)₂Si CH₂CF₃ H CH₂CF₃ H CH₃ H CH₃ 1508. (CH₃)₂Si CH₂CH₂CF₃ H CH₂CH₂CF₃ H CH₃ H CH₃ 1509. (CH₃)₂Si CH₂C(CH₃)₂CF₃ H CH₂C(CH₃)₂CF₃ H CH₃ H CH₃ 1510. (CH₃)₂Si CD₃ H CD₃ H CH₃ H CH₃ 1511. (CH₃)₂Si CD(CH₃)₂ H CD(CH₃)₂ H CH₃ H CH₃ 1512. (CH₃)₂Si CD₂CH(CH₃)₂ H CD₂CH(CH₃)₂ H CH₃ H CH₃ 1513. (CH₃)₂Si CH₃ H H CH₃ CH₃ H CH₃ 1514. (CH₃)₂Si CH(CH₃)₂ H H CH(CH₃)₂ CH₃ H CH₃ 1515. (CH₃)₂Si CH₂CH₃ H H CH₂CH₃ CH₃ H CH₃ 1516. (CH₃)₂Si CH₂CH(CH₃)₂ H H CH₂CH(CH₃)₂ CH₃ H CH₃ 1517. (CH₃)₂Si CH₂C(CH₃)₃ H H CH₂C(CH₃)₃ CH₃ H CH₃ 1518. (CH₃)₂Si

H H

CH₃ H CH₃ 1519. (CH₃)₂Si CH₂CF₃ H H CH₂CF₃ CH₃ H CH₃ 1520. (CH₃)₂Si CH₂CH₂CF₃ H H CH₂CH₂CF₃ CH₃ H CH₃ 1521. (CH₃)₂Si CH₂C(CH₃)₂CF₃ H H CH₂C(CH₃)₂CF₃ CH₃ H CH₃ 1522. (CH₃)₂Si CD₃ H H CD₃ CH₃ H CH₃ 1523. (CH₃)₂Si CD(CH₃)₂ H H CD(CH₃)₂ CH₃ H CH₃ 1524. (CH₃)₂Si CD₂CH(CH₃)₂ H H CD₂CH(CH₃)₂ CH₃ H CH₃ 1525. (CH₃)₂Si H CH₃ H CH₃ CH₃ H CH₃ 1526. (CH₃)₂Si H CH(CH₃)₂ H CH(CH₃)₂ CH₃ H CH₃ 1527. (CH₃)₂Si H CH₂CH₃ H CH₂CH₃ CH₃ H CH₃ 1528. (CH₃)₂Si H CH₂CH(CH₃)₂ H CH₂CH(CH₃)₂ CH₃ H CH₃ 1529. (CH₃)₂Si H CH₂C(CH₃)₃ H CH₂C(CH₃)₃ CH₃ H CH₃ 1530. (CH₃)₂Si H

H

CH₃ H CH₃ 1531. (CH₃)₂Si H CH₂CF₃ H CH₂CF₃ CH₃ H CH₃ 1532. (CH₃)₂Si H CH₂CH₂CF₃ H CH₂CH₂CF₃ CH₃ H CH₃ 1533. (CH₃)₂Si H CH₂C(CH₃)₂CF₃ H CH₂C(CH₃)₂CF₃ CH₃ H CH₃ 1534. (CH₃)₂Si H CD₃ H CD₃ CH₃ H CH₃ 1535. (CH₃)₂Si H CD(CH₃)₂ H CD(CH₃)₂ CH₃ H CH₃ 1536. (CH₃)₂Si H CD₂CH(CH₃)₂ H CD₂CH(CH₃)₂ CH₃ H CH₃ 1537. (CH₃)₂Si CH₃ H H H CH₃ F CH₃ 1538. (CH₃)₂Si CH(CH₃)₂ H H H CH₃ F CH₃ 1539. (CH₃)₂Si CH₂CH₃ H H H CH₃ F CH₃ 1540. (CH₃)₂Si CH₂CH(CH₃)₂ H H H CH₃ F CH₃ 1541. (CH₃)₂Si CH₂C(CH₃)₃ H H H CH₃ F CH₃ 1542. (CH₃)₂Si

H H H CH₃ F CH₃ 1543. (CH₃)₂Si CH₂CF₃ H H H CH₃ F CH₃ 1544. (CH₃)₂Si CH₂CH₂CF₃ H H H CH₃ F CH₃ 1545. (CH₃)₂Si CH₂C(CH₃)₂CF₃ H H H CH₃ F CH₃ 1546. (CH₃)₂Si CD₃ H H H CH₃ F CH₃ 1547. (CH₃)₂Si CD(CH₃)₂ H H H CH₃ F CH₃ 1548. (CH₃)₂Si CD₂CH(CH₃)₂ H H H CH₃ F CH₃ 1549. (CH₃)₂Si H CH₃ H H CH₃ F CH₃ 1550. (CH₃)₂Si H CH(CH₃)₂ H H CH₃ F CH₃ 1551. (CH₃)₂Si H CH₂CH₃ H H CH₃ F CH₃ 1552. (CH₃)₂Si H CH₂CH(CH₃)₂ H H CH₃ F CH₃ 1553. (CH₃)₂Si H CH₂C(CH₃)₃ H H CH₃ F CH₃ 1554. (CH₃)₂Si H

H H CH₃ F CH₃ 1555. (CH₃)₂Si H CH₂CF₃ H H CH₃ F CH₃ 1556. (CH₃)₂Si H CH₂CH₂CF₃ H H CH₃ F CH₃ 1557. (CH₃)₂Si H CH₂C(CH₃)₂CF₃ H H CH₃ F CH₃ 1558. (CH₃)₂Si H CD₃ H H CH₃ F CH₃ 1559. (CH₃)₂Si H CD(CH₃)₂ H H CH₃ F CH₃ 1560. (CH₃)₂Si H CD₂CH(CH₃)₂ H H CH₃ F CH₃ 1561. (CH₃)₂Si H H CH₃ H CH₃ F CH₃ 1562. (CH₃)₂Si H H CH(CH₃)₂ H CH₃ F CH₃ 1563. (CH₃)₂Si H H CH₂CH₃ H CH₃ F CH₃ 1564. (CH₃)₂Si H H CH₂CH(CH₃)₂ H CH₃ F CH₃ 1565. (CH₃)₂Si H H CH₂C(CH₃)₃ H CH₃ F CH₃ 1566. (CH₃)₂Si H H

H CH₃ F CH₃ 1567. (CH₃)₂Si H H CH₂CF₃ H CH₃ F CH₃ 1568. (CH₃)₂Si H H CH₂CH₂CF₃ H CH₃ F CH₃ 1569. (CH₃)₂Si H H CH₂C(CH₃)₂CF₃ H CH₃ F CH₃ 1570. (CH₃)₂Si H H CD₃ H CH₃ F CH₃ 1571. (CH₃)₂Si H H CD(CH₃)₂ H CH₃ F CH₃ 1572. (CH₃)₂Si H H CD₂CH(CH₃)₂ H CH₃ F CH₃ 1573. (CH₃)₂Si H H H CH₃ CH₃ F CH₃ 1574. (CH₃)₂Si H H H CH(CH₃)₂ CH₃ F CH₃ 1575. (CH₃)₂Si H H H CH₂CH₃ CH₃ F CH₃ 1576. (CH₃)₂Si H H H CH₂CH(CH₃)₂ CH₃ F CH₃ 1577. (CH₃)₂Si H H H CH₂C(CH₃)₃ CH₃ F CH₃ 1578. (CH₃)₂Si H H H

CH₃ F CH₃ 1579. (CH₃)₂Si H H H CH₂CF₃ CH₃ F CH₃ 1580. (CH₃)₂Si H H H CH₂CH₂CF₃ CH₃ F CH₃ 1581. (CH₃)₂Si H H H CH₂C(CH₃)₂CF₃ CH₃ F CH₃ 1582. (CH₃)₂Si H H H CD₃ CH₃ F CH₃ 1583. (CH₃)₂Si H H H CD(CH₃)₂ CH₃ F CH₃ 1584. (CH₃)₂Si H H H CD₂CH(CH₃)₂ CH₃ F CH₃ 1585. (CH₃)₂Si CH₃ CH₃ H H CH₃ F CH₃ 1586. (CH₃)₂Si CH(CH₃)₂ CH(CH₃)₂ H H CH₃ F CH₃ 1587. (CH₃)₂Si CH₂CH₃ CH₂CH₃ H H CH₃ F CH₃ 1588. (CH₃)₂Si CH₂CH(CH₃)₂ CH₂CH(CH₃)₂ H H CH₃ F CH₃ 1589. (CH₃)₂Si CH₂C(CH₃)₃ CH₂C(CH₃)₃ H H CH₃ F CH₃ 1590. (CH₃)₂Si

H H CH₃ F CH₃ 1591. (CH₃)₂Si CH₂CF₃ CH₂CF₃ H H CH₃ F CH₃ 1592. (CH₃)₂Si CH₂CH₂CF₃ CH₂CH₂CF₃ H H CH₃ F CH₃ 1593. (CH₃)₂Si CH₂C(CH₃)₂CF₃ CH₂C(CH₃)₂CF₃ H H CH₃ F CH₃ 1594. (CH₃)₂Si CD₃ CD₃ H H CH₃ F CH₃ 1595. (CH₃)₂Si CD(CH₃)₂ CD(CH₃)₂ H H CH₃ F CH₃ 1596. (CH₃)₂Si CD₂CH(CH₃)₂ CD₂CH(CH₃)₂ H H CH₃ F CH₃ 1597. (CH₃)₂Si CH₃ H CH₃ H CH₃ F CH₃ 1598. (CH₃)₂Si CH(CH₃)₂ H CH(CH₃)₂ H CH₃ F CH₃ 1599. (CH₃)₂Si CH₂CH₃ H CH₂CH₃ H CH₃ F CH₃ 1600. (CH₃)₂Si CH₂CH(CH₃)₂ H CH₂CH(CH₃)₂ H CH₃ F CH₃ 1601. (CH₃)₂Si CH₂C(CH₃)₃ H CH₂C(CH₃)₃ H CH₃ F CH₃ 1602. (CH₃)₂Si

H

H CH₃ F CH₃ 1603. (CH₃)₂Si CH₂CF₃ H CH₂CF₃ H CH₃ F CH₃ 1604. (CH₃)₂Si CH₂CH₂CF₃ H CH₂CH₂CF₃ H CH₃ F CH₃ 1605. (CH₃)₂Si CH₂C(CH₃)₂CF₃ H CH₂C(CH₃)₂CF₃ H CH₃ F CH₃ 1606. (CH₃)₂Si CD₃ H CD₃ H CH₃ F CH₃ 1607. (CH₃)₂Si CD(CH₃)₂ H CD(CH₃)₂ H CH₃ F CH₃ 1608. (CH₃)₂Si CD₂CH(CH₃)₂ H CD₂CH(CH₃)₂ H CH₃ F CH₃ 1609. (CH₃)₂Si CH₃ H H CH₃ CH₃ F CH₃ 1610. (CH₃)₂Si CH(CH₃)₂ H H CH(CH₃)₂ CH₃ F CH₃ 1611. (CH₃)₂Si CH₂CH₃ H H CH₂CH₃ CH₃ F CH₃ 1612. (CH₃)₂Si CH₂CH(CH₃)₂ H H CH₂CH(CH₃)₂ CH₃ F CH₃ 1613. (CH₃)₂Si CH₂C(CH₃)₃ H H CH₂C(CH₃)₃ CH₃ F CH₃ 1614. (CH₃)₂Si

H H

CH₃ F CH₃ 1615. (CH₃)₂Si CH₂CF₃ H H CH₂CF₃ CH₃ F CH₃ 1616. (CH₃)₂Si CH₂CH₂CF₃ H H CH₂CH₂CF₃ CH₃ F CH₃ 1617. (CH₃)₂Si CH₂C(CH₃)₂CF₃ H H CH₂C(CH₃)₂CF₃ CH₃ F CH₃ 1618. (CH₃)₂Si CD₃ H H CD₃ CH₃ F CH₃ 1619. (CH₃)₂Si CD(CH₃)₂ H H CD(CH₃)₂ CH₃ F CH₃ 1620. (CH₃)₂Si CD₂CH(CH₃)₂ H H CD₂CH(CH₃)₂ CH₃ F CH₃ 1621. (CH₃)₂Si H CH₃ H CH₃ CH₃ F CH₃ 1622. (CH₃)₂Si H CH(CH₃)₂ H CH(CH₃)₂ CH₃ F CH₃ 1623. (CH₃)₂Si H CH₂CH₃ H CH₂CH₃ CH₃ F CH₃ 1624. (CH₃)₂Si H CH₂CH(CH₃)₂ H CH₂CH(CH₃)₂ CH₃ F CH₃ 1625. (CH₃)₂Si H CH₂C(CH₃)₃ H CH₂C(CH₃)₃ CH₃ F CH₃ 1626. (CH₃)₂Si H

H

CH₃ F CH₃ 1627. (CH₃)₂Si H CH₂CF₃ H CH₂CF₃ CH₃ F CH₃ 1628. (CH₃)₂Si H CH₂CH₂CF₃ H CH₂CH₂CF₃ CH₃ F CH₃ 1629. (CH₃)₂Si H CH₂C(CH₃)₂CF₃ H CH₂C(CH₃)₂CF₃ CH₃ F CH₃ 1630. (CH₃)₂Si H CD₃ H CD₃ CH₃ F CH₃ 1631. (CH₃)₂Si H CD(CH₃)₂ H CD(CH₃)₂ CH₃ F CH₃ 1632. (CH₃)₂Si H CD₂CH(CH₃)₂ H CD₂CH(CH₃)₂ CH₃ F CH₃ 1633. (CH₃)₂Si CD₃ H H H CD₃ H H 1634. (CH₃)₂Si CD(CH₃)₂ H H H CD₃ H H 1635. (CH₃)₂Si CD₂CH(CH₃)₂ H H H CD₃ H H 1636. (CH₃)₂Si H CD₃ H H CD₃ H H 1637. (CH₃)₂Si H CD(CH₃)₂ H H CD₃ H H 1638. (CH₃)₂Si H CD₂CH(CH₃)₂ H H CD₃ H H 1639. (CH₃)₂Si H H CD₃ H CD₃ H H 1640. (CH₃)₂Si H H CD(CH₃)₂ H CD₃ H H 1641. (CH₃)₂Si H H CD₂CH(CH₃)₂ H CD₃ H H 1642. (CH₃)₂Si H H H CD₃ CD₃ H H 1643. (CH₃)₂Si H H H CD(CH₃)₂ CD₃ H H 1644. (CH₃)₂Si H H H CD₂CH(CH₃)₂ CD₃ H H 1645. (CH₃)₂Si CD₃ CD₃ H H CD₃ H H 1646. (CH₃)₂Si CD(CH₃)₂ CD(CH₃)₂ H H CD₃ H H 1647. (CH₃)₂Si CD₂CH(CH₃)₂ CD₂CH(CH₃)₂ H H CD₃ H H 1648. (CH₃)₂Si CD₃ H CD₃ H CD₃ H H 1649. (CH₃)₂Si CD(CH₃)₂ H CD(CH₃)₂ H CD₃ H H 1650. (CH₃)₂Si CD₂CH(CH₃)₂ H CD₂CH(CH₃)₂ H CD₃ H H 1651. (CH₃)₂Si CD₃ H H CD₃ CD₃ H H 1652. (CH₃)₂Si CD(CH₃)₂ H H CD(CH₃)₂ CD₃ H H 1653. (CH₃)₂Si CD₂CH(CH₃)₂ H H CD₂CH(CH₃)₂ CD₃ H H 1654. (CH₃)₂Si H CD₃ H CD₃ CD₃ H H 1655. (CH₃)₂Si H CD(CH₃)₂ H CD(CH₃)₂ CD₃ H H 1656. (CH₃)₂Si H CD₂CH(CH₃)₂ H CD₂CH(CH₃)₂ CD₃ H H 1657. (CH₃)₂Si CD₃ H H H H H CD₃ 1658. (CH₃)₂Si CD(CH₃)₂ H H H H H CD₃ 1659. (CH₃)₂Si CD₂CH(CH₃)₂ H H H H H CD₃ 1660. (CH₃)₂Si H CD₃ H H H H CD₃ 1661. (CH₃)₂Si H CD(CH₃)₂ H H H H CD₃ 1662. (CH₃)₂Si H CD₂CH(CH₃)₂ H H H H CD₃ 1663. (CH₃)₂Si H H CD₃ H H H CD₃ 1664. (CH₃)₂Si H H CD(CH₃)₂ H H H CD₃ 1665. (CH₃)₂Si H H CD₂CH(CH₃)₂ H H H CD₃ 1666. (CH₃)₂Si H H H CD₃ H H CD₃ 1667. (CH₃)₂Si H H H CD(CH₃)₂ H H CD₃ 1668. (CH₃)₂Si H H H CD₂CH(CH₃)₂ H H CD₃ 1669. (CH₃)₂Si CD₃ CD₃ H H H H CD₃ 1670. (CH₃)₂Si CD(CH₃)₂ CD(CH₃)₂ H H H H CD₃ 1671. (CH₃)₂Si CD₂CH(CH₃)₂ CD₂CH(CH₃)₂ H H H H CD₃ 1672. (CH₃)₂Si CD₃ H CD₃ H H H CD₃ 1673. (CH₃)₂Si CD(CH₃)₂ H CD(CH₃)₂ H H H CD₃ 1674. (CH₃)₂Si CD₂CH(CH₃)₂ H CD₂CH(CH₃)₂ H H H CD₃ 1675. (CH₃)₂Si CD₃ H H CD₃ H H CD₃ 1676. (CH₃)₂Si CD(CH₃)₂ H H CD(CH₃)₂ H H CD₃ 1677. (CH₃)₂Si CD₂CH(CH₃)₂ H H CD₂CH(CH₃)₂ H H CD₃ 1678. (CH₃)₂Si H CD₃ H CD₃ H H CD₃ 1679. (CH₃)₂Si H CD(CH₃)₂ H CD(CH₃)₂ H H CD₃ 1680. (CH₃)₂Si H CD₂CH(CH₃)₂ H CD₂CH(CH₃)₂ H H CD₃ 1681. (CH₃)₂Si CD₃ H H H CD₃ H CD₃ 1682. (CH₃)₂Si CD(CH₃)₂ H H H CD₃ H CD₃ 1683. (CH₃)₂Si CD₂CH(CH₃)₂ H H H CD₃ H CD₃ 1684. (CH₃)₂Si H CD₃ H H CD₃ H CD₃ 1685. (CH₃)₂Si H CD(CH₃)₂ H H CD₃ H CD₃ 1686. (CH₃)₂Si H CD₂CH(CH₃)₂ H H CD₃ H CD₃ 1687. (CH₃)₂Si H H CD₃ H CD₃ H CD₃ 1688. (CH₃)₂Si H H CD(CH₃)₂ H CD₃ H CD₃ 1689. (CH₃)₂Si H H CD₂CH(CH₃)₂ H CD₃ H CD₃ 1690. (CH₃)₂Si H H H CD₃ CD₃ H CD₃ 1691. (CH₃)₂Si H H H CD(CH₃)₂ CD₃ H CD₃ 1692. (CH₃)₂Si H H H CD₂CH(CH₃)₂ CD₃ H CD₃ 1693. (CH₃)₂Si CD₃ CD₃ H H CD₃ H CD₃ 1694. (CH₃)₂Si CD(CH₃)₂ CD(CH₃)₂ H H CD₃ H CD₃ 1695. (CH₃)₂Si CD₂CH(CH₃)₂ CD₂CH(CH₃)₂ H H CD₃ H CD₃ 1696. (CH₃)₂Si CD₃ H CD₃ H CD₃ H CD₃ 1697. (CH₃)₂Si CD(CH₃)₂ H CD(CH₃)₂ H CD₃ H CD₃ 1698. (CH₃)₂Si CD₂CH(CH₃)₂ H CD₂CH(CH₃)₂ H CD₃ H CD₃ 1699. (CH₃)₂Si CD₃ H H CD₃ CD₃ H CD₃ 1700. (CH₃)₂Si CD(CH₃)₂ H H CD(CH₃)₂ CD₃ H CD₃ 1701. (CH₃)₂Si CD₂CH(CH₃)₂ H H CD₂CH(CH₃)₂ CD₃ H CD₃ 1702. (CH₃)₂Si H CD₃ H CD₃ CD₃ H CD₃ 1703. (CH₃)₂Si H CD(CH₃)₂ H CD(CH₃)₂ CD₃ H CD₃ 1704. (CH₃)₂Si H CD₂CH(CH₃)₂ H CD₂CH(CH₃)₂ CD₃ H CD₃ 1705. (CH₃)₂Si CD₃ H H H CD₃ F CD₃ 1706. (CH₃)₂Si CD(CH₃)₂ H H H CD₃ F CD₃ 1707. (CH₃)₂Si CD₂CH(CH₃)₂ H H H CD₃ F CD₃ 1708. (CH₃)₂Si H CD₃ H H CD₃ F CD₃ 1709. (CH₃)₂Si H CD(CH₃)₂ H H CD₃ F CD₃ 1710. (CH₃)₂Si H CD₂CH(CH₃)₂ H H CD₃ F CD₃ 1711. (CH₃)₂Si H H CD₃ H CD₃ F CD₃ 1712. (CH₃)₂Si H H CD(CH₃)₂ H CD₃ F CD₃ 1713. (CH₃)₂Si H H CD₂CH(CH₃)₂ H CD₃ F CD₃ 1714. (CH₃)₂Si H H H CD₃ CD₃ F CD₃ 1715. (CH₃)₂Si H H H CD(CH₃)₂ CD₃ F CD₃ 1716. (CH₃)₂Si H H H CD₂CH(CH₃)₂ CD₃ F CD₃ 1717. (CH₃)₂Si CD₃ CD₃ H H CD₃ F CD₃ 1718. (CH₃)₂Si CD(CH₃)₂ CD(CH₃)₂ H H CD₃ F CD₃ 1719. (CH₃)₂Si CD₂CH(CH₃)₂ CD₂CH(CH₃)₂ H H CD₃ F CD₃ 1720. (CH₃)₂Si CD₃ H CD₃ H CD₃ F CD₃ 1721. (CH₃)₂Si CD(CH₃)₂ H CD(CH₃)₂ H CD₃ F CD₃ 1722. (CH₃)₂Si CD₂CH(CH₃)₂ H CD₂CH(CH₃)₂ H CD₃ F CD₃ 1723. (CH₃)₂Si CD₃ H H CD₃ CD₃ F CD₃ 1724. (CH₃)₂Si CD(CH₃)₂ H H CD(CH₃)₂ CD₃ F CD₃ 1725. (CH₃)₂Si CD₂CH(CH₃)₂ H H CD₂CH(CH₃)₂ CD₃ F CD₃ 1726. (CH₃)₂Si H CD₃ H CD₃ CD₃ F CD₃ 1727. (CH₃)₂Si H CD(CH₃)₂ H CD(CH₃)₂ CD₃ F CD₃ 1728. (CH₃)₂Si H CD₂CH(CH₃)₂ H CD₂CH(CH₃)₂ CD₃ F CD₃

In one embodiment, ligand L_(B) is selected from the group consisting of:

wherein each X¹ to X¹³ are independently selected from the group consisting of carbon and nitrogen;

wherein X is selected from the group consisting of BR′, NR′, PR′, O, S, Se, C═O, S═O, SO₂, CR′R″, SiR′R″, and GeR′R″;

wherein R′ and R″ are optionally fused or joined to form a ring;

wherein each R_(a), R_(b), R_(c), and R_(d) may represent from mono substitution to the possible maximum number of substitution, or no substitution;

wherein R′, R″, R_(a), R_(b), R_(c), and R_(d) are each independently selected from the group consisting of hydrogen, deuterium, halide, alkyl, cycloalkyl, heteroalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carbonyl, carboxylic acids, ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, and combinations thereof; and

wherein any two adjacent substituents of R_(a), R_(b), R_(c), and R_(d) are optionally fused or joined to form a ring or form a multidentate ligand.

In one embodiment, ligand L_(B) is selected from the group consisting of:

In another embodiment, ligand L_(B) is selected from the group consisting of:

In another embodiment, ligand L_(B) is selected from the group consisting of:

In another embodiment, ligand L_(B) is selected from the group consisting of:

In one embodiment, ligand L_(C) is selected from the group consisting of:

In one embodiment, the compound is Compound x having the formula M(L_(Ai))₂(L_(Cj)); wherein x=13(i−1)+j, i is an integer from 1 to 1728, and j is an integer from 1 to 13; and wherein L_(Cj) is selected from the group consisting of:

In some embodiments, the compound can be an emissive dopant. In some embodiments, the compound can produce emissions via phosphorescence, fluorescence, thermally activated delayed fluorescence, i.e., TADF (also referred to as E-type delayed fluorescence), triplet-triplet annihilation, or combinations of these processes.

Devices of the Invention

According to another aspect of the present disclosure, an OLED is also provided. The OLED includes an anode, a cathode, and an organic layer disposed between the anode and the cathode. The organic layer may include a host and a phosphorescent dopant. The organic layer can include a compound according to Formula I, and its variations as described herein.

The OLED can be incorporated into one or more of a consumer product, an electronic component module, and a lighting panel. The organic layer can be an emissive layer and the compound can be an emissive dopant in some embodiments, while the compound can be a non-emissive dopant in other embodiments.

The organic layer can also include a host. In some embodiments, two or more hosts are preferred. In some embodiments, the hosts used maybe a) bipolar, b) electron transporting, c) hole transporting or d) wide band gap materials that play little role in charge transport. In some embodiments, the host can include a metal complex. The host can be a triphenylene containing benzo-fused thiophene or benzo-fused furan. Any substituent in the host can be an unfused substituent independently selected from the group consisting of C_(n)H_(2n+1), OC_(n)H_(2n+1), OAr₁, N(C_(n)H_(2n+1))₂, N(Ar₁)(Ar₂), CH═CH—C_(n)H_(2n+1), C≡C—C_(n)H_(2n+1), Ar₁, Ar₁—Ar₂, and C_(n)H_(2n)—Ar₁, or the host has no substitution. In the preceding substituents n can range from 1 to 10; and Ar₁ and Ar₂ can be independently selected from the group consisting of benzene, biphenyl, naphthalene, triphenylene, carbazole, and heteroaromatic analogs thereof. The host can be an inorganic compound. For example a Zn containing inorganic material e.g. ZnS.

The host can be a compound comprising at least one chemical group selected from the group consisting of triphenylene, carbazole, dibenzothiophene, dibenzofuran, dibenzoselenophene, azatriphenylene, azacarbazole, aza-dibenzothiophene, aza-dibenzofuran, and aza-dibenzoselenophene. The host can include a metal complex. The host can be, but is not limited to, a specific compound selected from the group consisting of:

and combinations thereof.

Additional information on possible hosts is provided below.

In yet another aspect of the present disclosure, a formulation that comprises a compound according to Formula I is described. The formulation can include one or more components selected from the group consisting of a solvent, a host, a hole injection material, hole transport material, and an electron transport layer material, disclosed herein.

Combination with Other Materials

The materials described herein as useful for a particular layer in an organic light emitting device may be used in combination with a wide variety of other materials present in the device. For example, emissive dopants disclosed herein may be used in conjunction with a wide variety of hosts, transport layers, blocking layers, injection layers, electrodes and other layers that may be present. The materials described or referred to below are non-limiting examples of materials that may be useful in combination with the compounds disclosed herein, and one of skill in the art can readily consult the literature to identify other materials that may be useful in combination.

Conductivity Dopants:

A charge transport layer can be doped with conductivity dopants to substantially alter its density of charge carriers, which will in turn alter its conductivity. The conductivity is increased by generating charge carriers in the matrix material, and depending on the type of dopant, a change in the Fermi level of the semiconductor may also be achieved. Hole-transporting layer can be doped by p-type conductivity dopants and n-type conductivity dopants are used in the electron-transporting layer.

Non-limiting examples of the conductivity dopants that may be used in an OLED in combination with materials disclosed herein are exemplified below together with references that disclose those materials: EP01617493, EP01968131, EP2020694, EP2684932, US20050139810, US20070160905, US20090167167, US2010288362, WO006081780, WO2009003455, WO2009008277, WO2009011327, WO2014009310, US2007252140, US2015060804 and US2012146012.

HIL/HTL:

A hole injecting/transporting material to be used in the present invention is not particularly limited, and any compound may be used as long as the compound is typically used as a hole injecting/transporting material. Examples of the material include, but are not limited to: a phthalocyanine or porphyrin derivative; an aromatic amine derivative; an indolocarbazole derivative; a polymer containing fluorohydrocarbon; a polymer with conductivity dopants; a conducting polymer, such as PEDOT/PSS; a self-assembly monomer derived from compounds such as phosphonic acid and silane derivatives; a metal oxide derivative, such as MoO_(x); a p-type semiconducting organic compound, such as 1,4,5,8,9,12-Hexaazatriphenylenehexacarbonitrile; a metal complex, and a cross-linkable compounds.

Examples of aromatic amine derivatives used in HIL or HTL include, but not limit to the following general structures:

Each of Ar¹ to Ar⁹ is selected from the group consisting of aromatic hydrocarbon cyclic compounds such as benzene, biphenyl, triphenyl, triphenylene, naphthalene, anthracene, phenalene, phenanthrene, fluorene, pyrene, chrysene, perylene, and azulene; the group consisting of aromatic heterocyclic compounds such as dibenzothiophene, dibenzofuran, dibenzoselenophene, furan, thiophene, benzofuran, benzothiophene, benzoselenophene, carbazole, indolocarbazole, pyridylindole, pyrrolodipyridine, pyrazole, imidazole, triazole, oxazole, thiazole, oxadiazole, oxatriazole, dioxazole, thiadiazole, pyridine, pyridazine, pyrimidine, pyrazine, triazine, oxazine, oxathiazine, oxadiazine, indole, benzimidazole, indazole, indoxazine, benzoxazole, benzisoxazole, benzothiazole, quinoline, isoquinoline, cinnoline, quinazoline, quinoxaline, naphthyridine, phthalazine, pteridine, xanthene, acridine, phenazine, phenothiazine, phenoxazine, benzofuropyridine, furodipyridine, benzothienopyridine, thienodipyridine, benzoselenophenopyridine, and selenophenodipyridine; and the group consisting of 2 to 10 cyclic structural units which are groups of the same type or different types selected from the aromatic hydrocarbon cyclic group and the aromatic heterocyclic group and are bonded to each other directly or via at least one of oxygen atom, nitrogen atom, sulfur atom, silicon atom, phosphorus atom, boron atom, chain structural unit and the aliphatic cyclic group. Each Ar may be unsubstituted or may be substituted by a substituent selected from the group consisting of deuterium, halide, alkyl, cycloalkyl, heteroalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carbonyl, carboxylic acids, ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, and combinations thereof.

In one aspect, Ar¹ to Ar⁹ is independently selected from the group consisting of:

wherein k is an integer from 1 to 20; X¹⁰¹ to X¹⁰⁸ is C (including CH) or N; Z¹⁰¹ is NAr¹, O, or S; Ar¹ has the same group defined above.

Examples of metal complexes used in HIL or HTL include, but are not limited to the following general formula:

wherein Met is a metal, which can have an atomic weight greater than 40; (Y¹⁰¹-Y¹⁰²) is a bidentate ligand, Y¹⁰¹ and Y¹⁰² are independently selected from C, N, O, P, and S; L¹⁰¹ is an ancillary ligand; k′ is an integer value from 1 to the maximum number of ligands that may be attached to the metal; and k′+k″ is the maximum number of ligands that may be attached to the metal.

In one aspect, (Y¹⁰¹-Y¹⁰²) is a 2-phenylpyridine derivative. In another aspect, (Y¹⁰¹-Y¹⁰²) is a carbene ligand. In another aspect, Met is selected from Ir, Pt, Os, and Zn. In a further aspect, the metal complex has a smallest oxidation potential in solution vs. Fc⁺/Fc couple less than about 0.6 V.

Non-limiting examples of the HIL and HTL materials that may be used in an OLED in combination with materials disclosed herein are exemplified below together with references that disclose those materials: CN102702075, DE102012005215, EP01624500, EP01698613, EP01806334, EP01930964, EP01972613, EP01997799, EP02011790, EP02055700, EP02055701, EP1725079, EP2085382, EP2660300, EP650955, JP07-073529, JP2005112765, JP2007091719, JP2008021687, JP2014-009196, KR20110088898, KR20130077473, TW201139402, U.S. Ser. No. 06/517,957, US20020158242, US20030162053, US20050123751, US20060182993, US20060240279, US20070145888, US20070181874, US20070278938, US20080014464, US20080091025, US20080106190, US20080124572, US20080145707, US20080220265, US20080233434, US20080303417, US2008107919, US20090115320, US20090167161, US2009066235, US2011007385, US20110163302, US2011240968, US2011278551, US2012205642, US2013241401, US20140117329, US2014183517, U.S. Pat. Nos. 5,061,569, 5,639,914, WO05075451, WO07125714, WO08023550, WO08023759, WO2009145016, WO2010061824, WO2011075644, WO2012177006, WO2013018530, WO2013039073, WO2013087142, WO2013118812, WO2013120577, WO2013157367, WO2013175747, WO2014002873, WO2014015935, WO2014015937, WO2014030872, WO2014030921, WO2014034791, WO2014104514, WO2014157018.

EBL:

An electron blocking layer (EBL) may be used to reduce the number of electrons and/or excitons that leave the emissive layer. The presence of such a blocking layer in a device may result in substantially higher efficiencies, and or longer lifetime, as compared to a similar device lacking a blocking layer. Also, a blocking layer may be used to confine emission to a desired region of an OLED. In some embodiments, the EBL material has a higher LUMO (closer to the vacuum level) and/or higher triplet energy than the emitter closest to the EBL interface. In some embodiments, the EBL material has a higher LUMO (closer to the vacuum level) and or higher triplet energy than one or more of the hosts closest to the EBL interface. In one aspect, the compound used in EBL contains the same molecule or the same functional groups used as one of the hosts described below.

Host:

The light emitting layer of the organic EL device of the present invention preferably contains at least a metal complex as light emitting material, and may contain a host material using the metal complex as a dopant material. Examples of the host material are not particularly limited, and any metal complexes or organic compounds may be used as long as the triplet energy of the host is larger than that of the dopant. Any host material may be used with any dopant so long as the triplet criteria is satisfied.

Examples of metal complexes used as host are preferred to have the following general formula:

wherein Met is a metal; (Y¹⁰³-Y¹⁰⁴) is a bidentate ligand, Y¹⁰³ and Y¹⁰⁴ are independently selected from C, N, O, P, and S; L¹⁰¹ is an another ligand; k′ is an integer value from 1 to the maximum number of ligands that may be attached to the metal; and k′+k″ is the maximum number of ligands that may be attached to the metal.

In one aspect, the metal complexes are:

wherein (O—N) is a bidentate ligand, having metal coordinated to atoms O and N.

In another aspect, Met is selected from Ir and Pt. In a further aspect, (Y¹⁰³-Y¹⁰⁴) is a carbene ligand.

Examples of other organic compounds used as host are selected from the group consisting of aromatic hydrocarbon cyclic compounds such as benzene, biphenyl, triphenyl, triphenylene, tetraphenylene, naphthalene, anthracene, phenalene, phenanthrene, fluorene, pyrene, chrysene, perylene, and azulene; the group consisting of aromatic heterocyclic compounds such as dibenzothiophene, dibenzofuran, dibenzoselenophene, furan, thiophene, benzofuran, benzothiophene, benzoselenophene, carbazole, indolocarbazole, pyridylindole, pyrrolodipyridine, pyrazole, imidazole, triazole, oxazole, thiazole, oxadiazole, oxatriazole, dioxazole, thiadiazole, pyridine, pyridazine, pyrimidine, pyrazine, triazine, oxazine, oxathiazine, oxadiazine, indole, benzimidazole, indazole, indoxazine, benzoxazole, benzisoxazole, benzothiazole, quinoline, isoquinoline, cinnoline, quinazoline, quinoxaline, naphthyridine, phthalazine, pteridine, xanthene, acridine, phenazine, phenothiazine, phenoxazine, benzofuropyridine, furodipyridine, benzothienopyridine, thienodipyridine, benzoselenophenopyridine, and selenophenodipyridine; and the group consisting of 2 to 10 cyclic structural units which are groups of the same type or different types selected from the aromatic hydrocarbon cyclic group and the aromatic heterocyclic group and are bonded to each other directly or via at least one of oxygen atom, nitrogen atom, sulfur atom, silicon atom, phosphorus atom, boron atom, chain structural unit and the aliphatic cyclic group. Each option within each group may be unsubstituted or may be substituted by a substituent selected from the group consisting of deuterium, halide, alkyl, cycloalkyl, heteroalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carbonyl, carboxylic acids, ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, and combinations thereof.

In one aspect, the host compound contains at least one of the following groups in the molecule:

wherein each of R¹⁰¹ to R¹⁰⁷ is independently selected from the group consisting of hydrogen, deuterium, halide, alkyl, cycloalkyl, heteroalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carbonyl, carboxylic acids, ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, and combinations thereof, and when it is aryl or heteroaryl, it has the similar definition as Ar's mentioned above. k is an integer from 0 to 20 or 1 to 20; k′″ is an integer from 0 to 20. X¹⁰¹ to X¹⁰⁸ is selected from C (including CH) or N, and

Z¹⁰¹ and Z¹⁰² is selected from NR¹⁰¹, O, or S.

Non-limiting examples of the host materials that may be used in an OLED in combination with materials disclosed herein are exemplified below together with references that disclose those materials: EP2034538, EP2034538A, EP2757608, JP2007254297, KR20100079458, KR20120088644, KR20120129733, KR20130115564, TW201329200, US20030175553, US20050238919, US20060280965, US20090017330, US20090030202, US20090167162, US20090302743, US20090309488, US20100012931, US20100084966, US20100187984, US2010187984, US2012075273, US2012126221, US2013009543, US2013105787, US2013175519, US2014001446, US20140183503, US20140225088, US2014034914, U.S. Pat. No. 7,154,114, WO2001039234, WO2004093207, WO2005014551, WO2005089025, WO2006072002, WO2006114966, WO2007063754, WO2008056746, WO2009003898, WO2009021126, WO2009063833, WO2009066778, WO2009066779, WO2009086028, WO2010056066, WO2010107244, WO2011081423, WO2011081431, WO2011086863, WO2012128298, WO2012133644, WO2012133649, WO2013024872, WO2013035275, WO2013081315, WO2013191404, WO2014142472,

Additional Emitters:

One or more additional emitter dopants may be used in conjunction with the compound of the present disclosure. Examples of the additional emitter dopants are not particularly limited, and any compounds may be used as long as the compounds are typically used as emitter materials. Examples of suitable emitter materials include, but are not limited to, compounds which can produce emissions via phosphorescence, fluorescence, thermally activated delayed fluorescence, i.e., TADF (also referred to as E-type delayed fluorescence), triplet-triplet annihilation, or combinations of these processes.

Non-limiting examples of the emitter materials that may be used in an OLED in combination with materials disclosed herein are exemplified below together with references that disclose those materials: CN103694277, CN1696137, EB01238981, EP01239526, EP01961743, EP1239526, EP1244155, EP1642951, EP1647554, EP1841834, EP1841834B, EP2062907, EP2730583, JP2012074444, JP2013110263, JP4478555, KR1020090133652, KR20120032054, KR20130043460, TW201332980, U.S. Ser. No. 06/699,599, U.S. Ser. No. 06/916,554, US20010019782, US20020034656, US20030068526, US20030072964, US20030138657, US20050123788, US20050244673, US2005123791, US2005260449, US20060008670, US20060065890, US20060127696, US20060134459, US20060134462, US20060202194, US20060251923, US20070034863, US20070087321, US20070103060, US20070111026, US20070190359, US20070231600, US2007034863, US2007104979, US2007104980, US2007138437, US2007224450, US2007278936, US20080020237, US20080233410, US20080261076, US20080297033, US200805851, US2008161567, US2008210930, US20090039776, US20090108737, US20090115322, US20090179555, US2009085476, US2009104472, US20100090591, US20100148663, US20100244004, US20100295032, US2010102716, US2010105902, US2010244004, US2010270916, US20110057559, US20110108822, US20110204333, US2011215710, US2011227049, US2011285275, US2012292601, US20130146848, US2013033172, US2013165653, US2013181190, US2013334521, US20140246656, US2014103305, U.S. Pat. Nos. 6,303,238, 6,413,656, 6,653,654, 6,670,645, 6,687,266, 6,835,469, 6,921,915, 7,279,704, 7,332,232, 7,378,162, 7,534,505, 7,675,228, 7,728,137, 7,740,957, 7,759,489, 7,951,947, 8,067,099, 8,592,586, 8,871,361, WO06081973, WO06121811, WO07018067, WO07108362, WO07115970, WO7115981, WO8035571, WO2002015645, WO2003040257, WO2005019373, WO2006056418, WO2008054584, WO2008078800, WO2008096609, WO2008101842, WO2009000673, WO2009050281, WO2009100991, WO2010028151, WO2010054731, WO2010086089, WO2010118029, WO2011044988, WO2011051404, WO2011107491, WO2012020327, WO2012163471, WO2013094620, WO2013107487, WO2013174471, WO2014007565, WO2014008982, WO2014023377, WO2014024131, WO2014031977, WO2014038456, WO2014112450.

HBL:

A hole blocking layer (HBL) may be used to reduce the number of holes and/or excitons that leave the emissive layer. The presence of such a blocking layer in a device may result in substantially higher efficiencies and/or longer lifetime as compared to a similar device lacking a blocking layer. Also, a blocking layer may be used to confine emission to a desired region of an OLED. In some embodiments, the HBL material has a lower HOMO (further from the vacuum level) and or higher triplet energy than the emitter closest to the HBL interface. In some embodiments, the HBL material has a lower HOMO (further from the vacuum level) and or higher triplet energy than one or more of the hosts closest to the HBL interface.

In one aspect, compound used in HBL contains the same molecule or the same functional groups used as host described above.

In another aspect, compound used in HBL contains at least one of the following groups in the molecule:

wherein k is an integer from 1 to 20; L¹⁰¹ is an another ligand, k′ is an integer from 1 to 3.

ETL:

Electron transport layer (ETL) may include a material capable of transporting electrons. Electron transport layer may be intrinsic (undoped), or doped. Doping may be used to enhance conductivity. Examples of the ETL material are not particularly limited, and any metal complexes or organic compounds may be used as long as they are typically used to transport electrons.

In one aspect, compound used in ETL contains at least one of the following groups in the molecule:

wherein R¹⁰¹ is selected from the group consisting of hydrogen, deuterium, halide, alkyl, cycloalkyl, heteroalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carbonyl, carboxylic acids, ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, and combinations thereof, when it is aryl or heteroaryl, it has the similar definition as Ar's mentioned above. Ar¹ to Ar³ has the similar definition as Ar's mentioned above. k is an integer from 1 to 20. X¹⁰¹ to X¹⁰⁸ is selected from C (including CH) or N.

In another aspect, the metal complexes used in ETL contain, but are not limited to, the following general formulae:

wherein (O—N) or (N—N) is a bidentate ligand, having metal coordinated to atoms O, N or N, N; L¹⁰¹ is another ligand; k′ is an integer value from 1 to the maximum number of ligands that may be attached to the metal.

Non-limiting examples of the ETL materials that may be used in an OLED in combination with materials disclosed herein are exemplified below together with references that disclose those materials: CN103508940, EP01602648, EP01734038, EP01956007, JP2004-022334, JP2005149918, JP2005-268199, KR0117693, KR20130108183, US20040036077, US20070104977, US2007018155, US20090101870, US20090115316, US20090140637, US20090179554, US2009218940, US2010108990, US2011156017, US2011210320, US2012193612, US2012214993, US2014014925, US2014014927, US20140284580, U.S. Pat. Nos. 6,656,612, 8,415,031, WO2003060956, WO2007111263, WO2009148269, WO2010067894, WO2010072300, WO2011074770, WO2011105373, WO2013079217, WO2013145667, WO2013180376, WO2014104499, WO2014104535,

Charge Generation Layer (CGL)

In tandem or stacked OLEDs, the CGL plays an essential role in the performance, which is composed of an n-doped layer and a p-doped layer for injection of electrons and holes, respectively. Electrons and holes are supplied from the CGL and electrodes. The consumed electrons and holes in the CGL are refilled by the electrons and holes injected from the cathode and anode, respectively; then, the bipolar currents reach a steady state gradually. Typical CGL materials include n and p conductivity dopants used in the transport layers.

In any above-mentioned compounds used in each layer of the OLED device, the hydrogen atoms can be partially or fully deuterated. Thus, any specifically listed substituent, such as, without limitation, methyl, phenyl, pyridyl, etc. may be undeuterated, partially deuterated, and fully deuterated versions thereof. Similarly, classes of substituents such as, without limitation, alkyl, aryl, cycloalkyl, heteroaryl, etc. also may be undeuterated, partially deuterated, and fully deuterated versions thereof.

It is understood that the various embodiments described herein are by way of example only, and are not intended to limit the scope of the invention. For example, many of the materials and structures described herein may be substituted with other materials and structures without deviating from the spirit of the invention. The present invention as claimed may therefore include variations from the particular examples and preferred embodiments described herein, as will be apparent to one of skill in the art. It is understood that various theories as to why the invention works are not intended to be limiting. 

We claim:
 1. A compound of formula M(L_(A))_(x)(L_(B))_(y)(L_(C))_(z), wherein ligand L_(A) is:

wherein ligand L_(B) is:

wherein ligand L_(C) is:

wherein M is a metal having an atomic number greater than 40; wherein x is 1, 2, or 3; wherein y is 0, 1, or 2; wherein z is 0, 1, or 2; wherein x+y+z is the oxidation state of the metal M; wherein Y¹ to Y⁶ are carbon or nitrogen; wherein Y is selected from the group consisting of S and Se; wherein rings C and D are each independently a 5 or 6-membered carbocyclic or heterocyclic ring; wherein R^(A), R^(B), R^(C), and R^(D) each independently represent mono to the maximum possible number of substitution, or no substitution; wherein each of R^(A), R^(B), R^(C), R^(D), R^(X), R^(Y), and R^(Z) is independently selected from the group consisting of hydrogen, deuterium, halide, alkyl, cycloalkyl, heteroalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carbonyl, carboxylic acids, ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, and combinations thereof; and wherein any adjacent substituents are optionally joined or fused into a ring.
 2. The compound of claim 1, wherein M is selected from the group consisting of Ir, Rh, Re, Ru, Os, Pt, Au, and Cu.
 3. The compound of claim 1, wherein the compound has the formula selected from the group consisting of M(L_(A))₂(L_(C)) and M(L_(A))(L_(B))₂.
 4. The compound of claim 1, wherein ligand L_(C) has the formula:

wherein R¹, R², R³, and R⁴ are independently selected from group consisting of alkyl, cycloalkyl, aryl, and heteroaryl; and wherein at least one of R¹, R², R³, and R⁴ has at least two carbon atoms.
 5. The compound of claim 1, wherein ring C is benzene, and ring D is pyridine of which Y⁶ is N.
 6. The compound of claim 1, wherein ligand L_(A) is selected from the group consisting of:


7. The compound of claim 1, wherein ligand L_(B) is selected from the group consisting of:

wherein each X¹ to X¹³ are independently selected from the group consisting of carbon and nitrogen; wherein X is selected from the group consisting of BR′, NR′, PR′, O, S, Se, C═O, S═O, SO₂, CR′R″, SiR′R″, and GeR′R″; wherein R′ and R″ are optionally fused or joined to form a ring; wherein each R_(a), R_(b), R_(c), and R_(d) may represent from mono substitution to the possible maximum number of substitution, or no substitution; wherein R′, R″, R_(a), R_(b), R_(c), and R_(d) are each independently selected from the group consisting of hydrogen, deuterium, halide, alkyl, cycloalkyl, heteroalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carbonyl, carboxylic acids, ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, and combinations thereof; and wherein any two adjacent substituents of R_(a), R_(b), R_(c), and R_(d) are optionally fused or joined to form a ring or form a multidentate ligand.
 8. The compound of claim 1, wherein ligand L_(B) is selected from the group consisting of:


9. The compound of claim 1, wherein ligand L_(C) is selected from the group consisting of:


10. An organic light emitting device (OLED) comprising: an anode; a cathode; and an organic layer, disposed between the anode and the cathode, comprising a compound having formula M(L_(A))_(x)(L_(B))_(y)(L_(C))_(z), wherein ligand L_(A) is:

wherein ligand L_(B) is:

wherein ligand L_(C) is:

wherein M is a metal having an atomic number greater than 40; wherein x is 1, 2, or 3; wherein y is 0, 1, or 2; wherein z is 0, 1, or 2; wherein x+y+z is the oxidation state of the metal M; wherein Y¹ to Y⁶ are carbon or nitrogen; wherein Y is selected from the group consisting of S and Se; wherein rings C and D are each independently a 5 or 6-membered carbocyclic or heterocyclic ring; wherein R^(A), R^(B), R^(C), and R^(D) each independently represent mono to the maximum possible number of substitution, or no substitution; wherein each of R^(A), R^(B), R^(C), R^(D), R^(X), R^(Y), and R^(Z) is independently selected from the group consisting of hydrogen, deuterium, halide, alkyl, cycloalkyl, heteroalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carbonyl, carboxylic acids, ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, and combinations thereof; and wherein any adjacent substituents are optionally joined or fused into a ring.
 11. The OLED of claim 10, wherein the OLED is incorporated into a device selected from the group consisting of a consumer product, an electronic component module, and a lighting panel.
 12. The OLED of claim 10, wherein the organic layer is an emissive layer and the compound is an emissive dopant or a non-emissive dopant.
 13. The OLED of claim 10, wherein the organic layer further comprises a host, wherein the host comprises at least one chemical group selected from the group consisting of triphenylene, carbazole, dibenzothiophene, dibenzofuran, dibenzoselenophene, azatriphenylene, azacarbazole, aza-dibenzothiophene, aza-dibenzofuran, and aza-dibenzoselenophene.
 14. The OLED of claim 10, wherein the organic layer further comprises a host, wherein the host is selected from the group consisting of:

and combinations thereof.
 15. The OLED of claim 10, wherein the organic layer further comprises a host, wherein the host comprises a metal complex.
 16. A formulation comprising a compound of formula M(L_(A))_(x)(L_(B))_(y)(L_(C))_(z), wherein ligand L_(A) is:

wherein ligand L_(B) is:

wherein ligand L_(C) is:

wherein M is a metal having an atomic number greater than 40; wherein x is 1, 2, or 3; wherein y is 0, 1, or 2; wherein z is 0, 1, or 2; wherein x+y+z is the oxidation state of the metal M; wherein Y¹ to Y⁶ are carbon or nitrogen; wherein Y is selected from the group consisting of S and Se; wherein rings C and D are each independently a 5 or 6-membered carbocyclic or heterocyclic ring; wherein R^(A), R^(B), R^(C), and R^(D) each independently represent mono to the maximum possible number of substitution, or no substitution; wherein each of R^(A), R^(B), R^(C), R^(D), R^(X), R^(Y), and R^(Z) is independently selected from the group consisting of hydrogen, deuterium, halide, alkyl, cycloalkyl, heteroalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carbonyl, carboxylic acids, ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, and combinations thereof; and wherein any adjacent substituents are optionally joined or fused into a ring.
 17. The compound of claim 1, wherein Y¹ to Y⁵ are carbon.
 18. The compound of claim 1, wherein only one of Y¹ to Y⁵ is nitrogen.
 19. The compound of claim 1, wherein ligand L_(A) of formula:

is selected from the group consisting of L_(A1) to L_(A1152): Ligand number Y R^(A1) R^(A2) R^(A3) R^(A4) R^(B1) R^(B2) R^(B3)
 1. S CH₃ H H H H H H
 2. S CH(CH₃)₂ H H H H H H
 3. S CH₂CH₃ H H H H H H
 4. S CH₂CH(CH₃)₂ H H H H H H
 5. S CH₂C(CH₃)₃ H H H H H H
 6. S

H H H H H H
 7. S CH₂CF₃ H H H H H H
 8. S CH₂CH₂CF₃ H H H H H H
 9. S CH₂C(CH₃)₂CF₃ H H H H H H
 10. S CD₃ H H H H H H
 11. S CD(CH₃)₂ H H H H H H
 12. S CD₂CH(CH₃)₂ H H H H H H
 13. S H CH₃ H H H H H
 14. S H CH(CH₃)₂ H H H H H
 15. S H CH₂CH₃ H H H H H
 16. S H CH₂CH(CH₃)₂ H H H H H
 17. S H CH₂C(CH₃)₃ H H H H H
 18. S H

H H H H H
 19. S H CH₂CF₃ H H H H H
 20. S H CH₂CH₂CF₃ H H H H H
 21. S H CH₂C(CH₃)₂CF₃ H H H H H
 22. S H CD₃ H H H H H
 23. S H CD(CH₃)₂ H H H H H
 24. S H CD₂CH(CH₃)₂ H H H H H
 25. S H H CH₃ H H H H
 26. S H H CH(CH₃)₂ H H H H
 27. S H H CH₂CH₃ H H H H
 28. S H H CH₂CH(CH₃)₂ H H H H
 29. S H H CH₂C(CH₃)₃ H H H H
 30. S H H

H H H H
 31. S H H CH₂CF₃ H H H H
 32. S H H CH₂CH₂CF₃ H H H H
 33. S H H CH₂C(CH₃)₂CF₃ H H H H
 34. S H H CD₃ H H H H
 35. S H H CD(CH₃)₂ H H H H
 36. S H H CD₂CH(CH₃)₂ H H H H
 37. S H H H CH₃ H H H
 38. S H H H CH(CH₃)₂ H H H
 39. S H H H CH₂CH₃ H H H
 40. S H H H CH₂CH(CH₃)₂ H H H
 41. S H H H CH₂C(CH₃)₃ H H H
 42. S H H H

H H H
 43. S H H H CH₂CF₃ H H H
 44. S H H H CH₂CH₂CF₃ H H H
 45. S H H H CH₂C(CH₃)₂CF₃ H H H
 46. S H H H CD₃ H H H
 47. S H H H CD(CH₃)₂ H H H
 48. S H H H CD₂CH(CH₃)₂ H H H
 49. S CH₃ CH₃ H H H H H
 50. S CH(CH₃)₂ CH(CH₃)₂ H H H H H
 51. S CH₂CH₃ CH₂CH₃ H H H H H
 52. S CH₂CH(CH₃)₂ CH₂CH(CH₃)₂ H H H H H
 53. S CH₂C(CH₃)₃ CH₂C(CH₃)₃ H H H H H
 54. S

H H H H H
 55. S CH₂CF₃ CH₂CF₃ H H H H H
 56. S CH₂CH₂CF₃ CH₂CH₂CF₃ H H H H H
 57. S CH₂C(CH₃)₂CF₃ CH₂C(CH₃)₂CF₃ H H H H H
 58. S CD₃ CD₂ H H H H H
 59. S CD(CH₃)₂ CD(CH₃)₂ H H H H H
 60. S CD₂CH(CH₃)₂ CD₂CH(CH₃)₂ H H H H H
 61. S CH₃ H CH₃ H H H H
 62. S CH(CH₃)₂ H CH(CH₃)₂ H H H H
 63. S CH₂CH₃ H CH₂CH₃ H H H H
 64. S CH₂CH(CH₃)₂ H CH₂CH(CH₃)₂ H H H H
 65. S CH₂C(CH₃)₃ H CH₂C(CH₃)₃ H H H H
 66. S

H

H H H H
 67. S CH₂CF₃ H CH₂CF₃ H H H H
 68. S CH₂CH₂CF₃ H CH₂CH₂CF₃ H H H H
 69. S CH₂C(CH₃)₂CF₃ H CH₂C(CH₃)₂CF₃ H H H H
 70. S CD₃ H CD₃ H H H H
 71. S CD(CH₃)₂ H CD(CH₃)₂ H H H H
 72. S CD₂CH(CH₃)₂ H CD₂CH(CH₃)₂ H H H H
 73. S CH₃ H H CH₃ H H H
 74. S CH(CH₃)₂ H H CH(CH₃)₂ H H H
 75. S CH₂CH₃ H H CH₂CH₃ H H H
 76. S CH₂CH(CH₃)₂ H H CH₂CH(CH₃)₂ H H H
 77. S CH₂C(CH₃)₃ H H CH₂C(CH₃)₃ H H H
 78. S

H H

H H H
 79. S CH₂CF₃ H H CH₂CF₃ H H H
 80. S CH₂CH₂CF₃ H H CH₂CH₂CF₃ H H H
 81. S CH₂C(CH₃)₂CF₃ H H CH₂C(CH₃)₂CF₃ H H H
 82. S CD₃ H H CD₃ H H H
 83. S CD(CH₃)₂ H H CD(CH₃)₂ H H H
 84. S CD₂CH(CH₃)₂ H H CD₂CH(CH₃)₂ H H H
 85. S H CH₃ H CH₃ H H H
 86. S H CH(CH₃)₂ H CH(CH₃)₂ H H H
 87. S H CH₂CH₃ H CH₂CH₃ H H H
 88. S H CH₂CH(CH₃)₂ H CH₂CH(CH₃)₂ H H H
 89. S H CH₂C(CH₃)₃ H CH₂C(CH₃)₃ H H H
 90. S H

H

H H H
 91. S H CH₂CF₃ H CH₂CF₃ H H H
 92. S H CH₂CH₂CF₃ H CH₂CH₂CF₃ H H H
 93. S H CH₂C(CH₃)₂CF₃ H CH₂C(CH₃)₂CF₃ H H H
 94. S H CD₃ H CD₃ H H H
 95. S H CD(CH₃)₂ H CD(CH₃)₂ H H H
 96. S H CD₂CH(CH₃)₂ H CD₂CH(CH₃)₂ H H H
 97. S CH₃ H H H CH₃ H H
 98. S CH(CH₃)₂ H H H CH₃ H H
 99. S CH₂CH₃ H H H CH₃ H H
 100. S CH₂CH(CH₃)₂ H H H CH₃ H H
 101. S CH₂C(CH₃)₃ H H H CH₃ H H
 102. S

H H H CH₃ H H
 103. S CH₂CF₃ H H H CH₃ H H
 104. S CH₂CH₂CF₃ H H H CH₃ H H
 105. S CH₂C(CH₃)₂CF₃ H H H CH₃ H H
 106. S CD₃ H H H CH₃ H H
 107. S CD(CH₃)₂ H H H CH₃ H H
 108. S CD₂CH(CH₃)₂ H H H CH₃ H H
 109. S H CH₃ H H CH₃ H H
 110. S H CH(CH₃)₂ H H CH₃ H H
 111. S H CH₂CH₃ H H CH₃ H H
 112. S H CH₂CH(CH₃)₂ H H CH₃ H H
 113. S H CH₂C(CH₃)₃ H H CH₃ H H
 114. S H

H H CH₃ H H
 115. S H CH₂CF₃ H H CH₃ H H
 116. S H CH₂CH₂CF₃ H H CH₃ H H
 117. S H CH₂C(CH₃)₂CF₃ H H CH₃ H H
 118. S H CD₃ H H CH₃ H H
 119. S H CD(CH₃)₂ H H CH₃ H H
 120. S H CD₂CH(CH₃)₂ H H CH₃ H H
 121. S H H CH₃ H CH₃ H H
 122. S H H CH(CH₃)₂ H CH₃ H H
 123. S H H CH₂CH₃ H CH₃ H H
 124. S H H CH₂CH(CH₃)₂ H CH₃ H H
 125. S H H CH₂C(CH₃)₃ H CH₃ H H
 126. S H H

H CH₃ H H
 127. S H H CH₂CF₃ H CH₃ H H
 128. S H H CH₂CH₂CF₃ H CH₃ H H
 129. S H H CH₂C(CH₃)₂CF₃ H CH₃ H H
 130. S H H CD₃ H CH₃ H H
 131. S H H CD(CH₃)₂ H CH₃ H H
 132. S H H CD₂CH(CH₃)₂ H CH₃ H H
 133. S H H H CH₃ CH₃ H H
 134. S H H H CH(CH₃)₂ CH₃ H H
 135. S H H H CH₂CH₃ CH₃ H H
 136. S H H H CH₂CH(CH₃)₂ CH₃ H H
 137. S H H H CH₂C(CH₃)₃ CH₃ H H
 138. S H H H

CH₃ H H
 139. S H H H CH₂CF₃ CH₃ H H
 140. S H H H CH₂CH₂CF₃ CH₃ H H
 141. S H H H CH₂C(CH₃)₂CF₃ CH₃ H H
 142. S H H H CD₃ CH₃ H H
 143. S H H H CD(CH₃)₂ CH₃ H H
 144. S H H H CD₂CH(CH₃)₂ CH₃ H H
 145. S CH₃ CH₃ H H CH₃ H H
 146. S CH(CH₃)₂ CH(CH₃)₂ H H CH₃ H H
 147. S CH₂CH₃ CH₂CH₃ H H CH₃ H H
 148. S CH₂CH(CH₃)₂ CH₂CH(CH₃)₂ H H CH₃ H H
 149. S CH₂C(CH₃)₃ CH₂C(CH₃)₃ H H CH₃ H H
 150. S

H H CH₃ H H
 151. S CH₂CF₃ CH₂CF₃ H H CH₃ H H
 152. S CH₂CH₂CF₃ CH₂CH₂CF₃ H H CH₃ H H
 153. S CH₂C(CH₃)₂CF₃ CH₂C(CH₃)₂CF₃ H H CH₃ H H
 154. S CD₃ CD₃ H H CH₃ H H
 155. S CD(CH₃)₂ CD(CH₃)₂ H H CH₃ H H
 156. S CD₂CH(CH₃)₂ CD₂CH(CH₃)₂ H H CH₃ H H
 157. S CH₃ H CH₃ H CH₃ H H
 158. S CH(CH₃)₂ H CH(CH₃)₂ H CH₃ H H
 159. S CH₂CH₃ H CH₂CH₃ H CH₃ H H
 160. S CH₂CH(CH₃)₂ H CH₂CH(CH₃)₂ H CH₃ H H
 161. S CH₂C(CH₃)₃ H CH₂C(CH₃)₃ H CH₃ H H
 162. S

H

H CH₃ H H
 163. S CH₂CF₃ H CH₂CF₃ H CH₃ H H
 164. S CH₂CH₂CF₃ H CH₂CH₂CF₃ H CH₃ H H
 165. S CH₂C(CH₃)₂CF₃ H CH₂C(CH₃)₂CF₃ H CH₃ H H
 166. S CD₃ H CD₃ H CH₃ H H
 167. S CD(CH₃)₂ H CD(CH₃)₂ H CH₃ H H
 168. S CD₂CH(CH₃)₂ H CD₂CH(CH₃)₂ H CH₃ H H
 169. S CH₃ H H CH₃ CH₃ H H
 170. S CH(CH₃)₂ H H CH(CH₃)₂ CH₃ H H
 171. S CH₂CH₃ H H CH₂CH₃ CH₃ H H
 172. S CH₂CH(CH₃)₂ H H CH₂CH(CH₃)₂ CH₃ H H
 173. S CH₂C(CH₃)₃ H H CH₂C(CH₃)₃ CH₃ H H
 174. S

H H

CH₃ H H
 175. S CH₂CF₃ H H CH₂CF₃ CH₃ H H
 176. S CH₂CH₂CF₃ H H CH₂CH₂CF₃ CH₃ H H
 177. S CH₂C(CH₃)₂CF₃ H H CH₂C(CH₃)₂CF₃ CH₃ H H
 178. S CD₃ H H CD₃ CH₃ H H
 179. S CD(CH₃)₂ H H CD(CH₃)₂ CH₃ H H
 180. S CD₂CH(CH₃)₂ H H CD₂CH(CH₃)₂ CH₃ H H
 181. S H CH₃ H CH₃ CH₃ H H
 182. S H CH(CH₃)₂ H CH(CH₃)₂ CH₃ H H
 183. S H CH₂CH₃ H CH₂CH₃ CH₃ H H
 184. S H CH₂CH(CH₃)₂ H CH₂CH(CH₃)₂ CH₃ H H
 185. S H CH₂C(CH₃)₃ H CH₂C(CH₃)₃ CH₃ H H
 186. S H

H

CH₃ H H
 187. S H CH₂CF₃ H CH₂CF₃ CH₃ H H
 188. S H CH₂CH₂CF₃ H CH₂CH₂CF₃ CH₃ H H
 189. S H CH₂C(CH₃)₂CF₃ H CH₂C(CH₃)₂CF₃ CH₃ H H
 190. S H CD₃ H CD₃ CH₃ H H
 191. S H CD(CH₃)₂ H CD(CH₃)₂ CH₃ H H
 192. S H CD₂CH(CH₃)₂ H CD₂CH(CH₃)₂ CH₃ H H
 193. S CH₃ H H H H H CH₃
 194. S CH(CH₃)₂ H H H H H CH₃
 195. S CH₂CH₃ H H H H H CH₃
 196. S CH₂CH(CH₃)₂ H H H H H CH₃
 197. S CH₂C(CH₃)₃ H H H H H CH₃
 198. S

H H H H H CH₃
 199. S CH₂CF₃ H H H H H CH₃
 200. S CH₂CH₂CF₃ H H H H H CH₃
 201. S CH₂C(CH₃)₂CF₃ H H H H H CH₃
 202. S CD₃ H H H H H CH₃
 203. S CD(CH₃)₂ H H H H H CH₃
 204. S CD₂CH(CH₃)₂ H H H H H CH₃
 205. S H CH₃ H H H H CH₃
 206. S H CH(CH₃)₂ H H H H CH₃
 207. S H CH₂CH₃ H H H H CH₃
 208. S H CH₂CH(CH₃)₂ H H H H CH₃
 209. S H CH₂C(CH₃)₃ H H H H CH₃
 210. S H

H H H H CH₃
 211. S H CH₂CF₃ H H H H CH₃
 212. S H CH₂CH₂CF₃ H H H H CH₃
 213. S H CH₂C(CH₃)₂CF₃ H H H H CH₃
 214. S H CD₃ H H H H CH₃
 215. S H CD(CH₃)₂ H H H H CH₃
 216. S H CD₂CH(CH₃)₂ H H H H CH₃
 217. S H H CH₃ H H H CH₃
 218. S H H CH(CH₃)₂ H H H CH₃
 219. S H H CH₂CH₃ H H H CH₃
 220. S H H CH₂CH(CH₃)₂ H H H CH₃
 221. S H H CH₂C(CH₃)₃ H H H CH₃
 222. S H H

H H H CH₃
 223. S H H CH₂CF₃ H H H CH₃
 224. S H H CH₂CH₂CF₃ H H H CH₃
 225. S H H CH₂C(CH₃)₂CF₃ H H H CH₃
 226. S H H CD₃ H H H CH₃
 227. S H H CD(CH₃)₂ H H H CH₃
 228. S H H CD₂CH(CH₃)₂ H H H CH₃
 229. S H H H CH₃ H H CH₃
 230. S H H H CH(CH₃)₂ H H CH₃
 231. S H H H CH₂CH₃ H H CH₃
 232. S H H H CH₂CH(CH₃)₂ H H CH₃
 233. S H H H CH₂C(CH₃)₃ H H CH₃
 234. S H H H

H H CH₃
 235. S H H H CH₂CF₃ H H CH₃
 236. S H H H CH₂CH₂CF₃ H H CH₃
 237. S H H H CH₂C(CH₃)₂CF₃ H H CH₃
 238. S H H H CD₃ H H CH₃
 239. S H H H CD(CH₃)₂ H H CH₃
 240. S H H H CD₂CH(CH₃)₂ H H CH₃
 241. S CH₃ CH₃ H H H H CH₃
 242. S CH(CH₃)₂ CH(CH₃)₂ H H H H CH₃
 243. S CH₂CH₃ CH₂CH₃ H H H H CH₃
 244. S CH₂CH(CH₃)₂ CH₂CH(CH₃)₂ H H H H CH₃
 245. S CH₂C(CH₃)₃ CH₂C(CH₃)₃ H H H H CH₃
 246. S

H H H H CH₃
 247. S CH₂CF₃ CH₂CF₃ H H H H CH₃
 248. S CH₂CH₂CF₃ CH₂CH₂CF₃ H H H H CH₃
 249. S CH₂C(CH₃)₂CF₃ CH₂C(CH₃)₂CF₃ H H H H CH₃
 250. S CD₃ CD₃ H H H H CH₃
 251. S CD(CH₃)₂ CD(CH₃)₂ H H H H CH₃
 252. S CD₂CH(CH₃)₂ CD₂CH(CH₃)₂ H H H H CH₃
 253. S CH₃ H CH₃ H H H CH₃
 254. S CH(CH₃)₂ H CH(CH₃)₂ H H H CH₃
 255. S CH₂CH₃ H CH₂CH₃ H H H CH₃
 256. S CH₂CH(CH₃)₂ H CH₂CH(CH₃)₂ H H H CH₃
 257. S CH₂C(CH₃)₃ H CH₂C(CH₃)₃ H H H CH₃
 258. S

H

H H H CH₃
 259. S CH₂CF₃ H CH₂CF₃ H H H CH₃
 260. S CH₂CH₂CF₃ H CH₂CH₂CF₃ H H H CH₃
 261. S CH₂C(CH₃)₂CF₃ H CH₂C(CH₃)₂CF₃ H H H CH₃
 262. S CD₃ H CD₃ H H H CH₃
 263. S CD(CH₃)₂ H CD(CH₃)₂ H H H CH₃
 264. S CD₂CH(CH₃)₂ H CD₂CH(CH₃)₂ H H H CH₃
 265. S CH₃ H H CH₃ H H CH₃
 266. S CH(CH₃)₂ H H CH(CH₃)₂ H H CH₃
 267. S CH₂CH₃ H H CH₂CH₃ H H CH₃
 268. S CH₂CH(CH₃)₂ H H CH₂CH(CH₃)₂ H H CH₃
 269. S CH₂C(CH₃)₃ H H CH₂C(CH₃)₃ H H CH₃
 270. S

H H

H H CH₃
 271. S CH₂CF₃ H H CH₂CF₃ H H CH₃
 272. S CH₂CH₂CF₃ H H CH₂CH₂CF₃ H H CH₃
 273. S CH₂C(CH₃)₂CF₃ H H CH₂C(CH₃)₂CF₃ H H CH₃
 274. S CD₃ H H CD₃ H H CH₃
 275. S CD(CH₃)₂ H H CD(CH₃)₂ H H CH₃
 276. S CD₂CH(CH₃)₂ H H CD₂CH(CH₃)₂ H H CH₃
 277. S H CH₃ H CH₃ H H CH₃
 278. S H CH(CH₃)₂ H CH(CH₃)₂ H H CH₃
 279. S H CH₂CH₃ H CH₂CH₃ H H CH₃
 280. S H CH₂CH(CH₃)₂ H CH₂CH(CH₃)₂ H H CH₃
 281. S H CH₂C(CH₃)₃ H CH₂C(CH₃)₃ H H CH₃
 282. S H

H

H H CH₃
 283. S H CH₂CF₃ H CH₂CF₃ H H CH₃
 284. S H CH₂CH₂CF₃ H CH₂CH₂CF₃ H H CH₃
 285. S H CH₂C(CH₃)₂CF₃ H CH₂C(CH₃)₂CF₃ H H CH₃
 286. S H CD₃ H CD₃ H H CH₃
 287. S H CD(CH₃)₂ H CD(CH₃)₂ H H CH₃
 288. S H CD₂CH(CH₃)₂ H CD₂CH(CH₃)₂ H H CH₃
 289. S CH₃ H H H CH₃ H CH₃
 290. S CH(CH₃)₂ H H H CH₃ H CH₃
 291. S CH₂CH₃ H H H CH₃ H CH₃
 292. S CH₂CH(CH₃)₂ H H H CH₃ H CH₃
 293. S CH₂C(CH₃)₃ H H H CH₃ H CH₃
 294. S

H H H CH₃ H CH₃
 295. S CH₂CF₃ H H H CH₃ H CH₃
 296. S CH₂CH₂CF₃ H H H CH₃ H CH₃
 297. S CH₂C(CH₃)₂CF₃ H H H CH₃ H CH₃
 298. S CD₃ H H H CH₃ H CH₃
 299. S CD(CH₃)₂ H H H CH₃ H CH₃
 300. S CD₂CH(CH₃)₂ H H H CH₃ H CH₃
 301. S H CH₃ H H CH₃ H CH₃
 302. S H CH(CH₃)₂ H H CH₃ H CH₃
 303. S H CH₂CH₃ H H CH₃ H CH₃
 304. S H CH₂CH(CH₃)₂ H H CH₃ H CH₃
 305. S H CH₂C(CH₃)₃ H H CH₃ H CH₃
 306. S H

H H CH₃ H CH₃
 307. S H CH₂CF₃ H H CH₃ H CH₃
 308. S H CH₂CH₂CF₃ H H CH₃ H CH₃
 309. S H CH₂C(CH₃)₂CF₃ H H CH₃ H CH₃
 310. S H CD₃ H H CH₃ H CH₃
 311. S H CD(CH₃)₂ H H CH₃ H CH₃
 312. S H CD₂CH(CH₃)₂ H H CH₃ H CH₃
 313. S H H CH₃ H CH₃ H CH₃
 314. S H H CH(CH₃)₂ H CH₃ H CH₃
 315. S H H CH₂CH₃ H CH₃ H CH₃
 316. S H H CH₂CH(CH₃)₂ H CH₃ H CH₃
 317. S H H CH₂C(CH₃)₃ H CH₃ H CH₃
 318. S H H

H CH₃ H CH₃
 319. S H H CH₂CF₃ H CH₃ H CH₃
 320. S H H CH₂CH₂CF₃ H CH₃ H CH₃
 321. S H H CH₂C(CH₃)₂CF₃ H CH₃ H CH₃
 322. S H H CD₃ H CH₃ H CH₃
 323. S H H CD(CH₃)₂ H CH₃ H CH₃
 324. S H H CD₂CH(CH₃)₂ H CH₃ H CH₃
 325. S H H H CH₃ CH₃ H CH₃
 326. S H H H CH(CH₃)₂ CH₃ H CH₃
 327. S H H H CH₂CH₃ CH₃ H CH₃
 328. S H H H CH₂CH(CH₃)₂ CH₃ H CH₃
 329. S H H H CH₂C(CH₃)₃ CH₃ H CH₃
 330. S H H H

CH₃ H CH₃
 331. S H H H CH₂CF₃ CH₃ H CH₃
 332. S H H H CH₂CH₂CF₃ CH₃ H CH₃
 333. S H H H CH₂C(CH₃)₂CF₃ CH₃ H CH₃
 334. S H H H CD₃ CH₃ H CH₃
 335. S H H H CD(CH₃)₂ CH₃ H CH₃
 336. S H H H CD₂CH(CH₃)₂ CH₃ H CH₃
 337. S CH₃ CH₃ H H CH₃ H CH₃
 338. S CH(CH₃)₂ CH(CH₃)₂ H H CH₃ H CH₃
 339. S CH₂CH₃ CH₂CH₃ H H CH₃ H CH₃
 340. S CH₂CH(CH₃)₂ CH₂CH(CH₃)₂ H H CH₃ H CH₃
 341. S CH₂C(CH₃)₃ CH₂C(CH₃)₃ H H CH₃ H CH₃
 342. S

H H CH₃ H CH₃
 343. S CH₂CF₃ CH₂CF₃ H H CH₃ H CH₃
 344. S CH₂CH₂CF₃ CH₂CH₂CF₃ H H CH₃ H CH₃
 345. S CH₂C(CH₃)₂CF₃ CH₂C(CH₃)₂CF₃ H H CH₃ H CH₃
 346. S CD₃ CD₃ H H CH₃ H CH₃
 347. S CD(CH₃)₂ CD(CH₃)₂ H H CH₃ H CH₃
 348. S CD₂CH(CH₃)₂ CD₂CH(CH₃)₂ H H CH₃ H CH₃
 349. S CH₃ H CH₃ H CH₃ H CH₃
 350. S CH(CH₃)₂ H CH(CH₃)₂ H CH₃ H CH₃
 351. S CH₂CH₃ H CH₂CH₃ H CH₃ H CH₃
 352. S CH₂CH(CH₃)₂ H CH₂CH(CH₃)₂ H CH₃ H CH₃
 353. S CH₂C(CH₃)₃ H CH₂C(CH₃)₃ H CH₃ H CH₃
 354. S

H

H CH₃ H CH₃
 355. S CH₂CF₃ H CH₂CF₃ H CH₃ H CH₃
 356. S CH₂CH₂CF₃ H CH₂CH₂CF₃ H CH₃ H CH₃
 357. S CH₂C(CH₃)₂CF₃ H CH₂C(CH₃)₂CF₃ H CH₃ H CH₃
 358. S CD₃ H CD₃ H CH₃ H CH₃
 359. S CD(CH₃)₂ H CD(CH₃)₂ H CH₃ H CH₃
 360. S CD₂CH(CH₃)₂ H CD₂CH(CH₃)₂ H CH₃ H CH₃
 361. S CH₃ H H CH₃ CH₃ H CH₃
 362. S CH(CH₃)₂ H H CH(CH₃)₂ CH₃ H CH₃
 363. S CH₂CH₃ H H CH₂CH₃ CH₃ H CH₃
 364. S CH₂CH(CH₃)₂ H H CH₂CH(CH₃)₂ CH₃ H CH₃
 365. S CH₂C(CH₃)₃ H H CH₂C(CH₃)₃ CH₃ H CH₃
 366. S

H H

CH₃ H CH₃
 367. S CH₂CF₃ H H CH₂CF₃ CH₃ H CH₃
 368. S CH₂CH₂CF₃ H H CH₂CH₂CF₃ CH₃ H CH₃
 369. S CH₂C(CH₃)₂CF₃ H H CH₂C(CH₃)₂CF₃ CH₃ H CH₃
 370. S CD₃ H H CD₃ CH₃ H CH₃
 371. S CD(CH₃)₂ H H CD(CH₃)₂ CH₃ H CH₃
 372. S CD₂CH(CH₃)₂ H H CD₂CH(CH₃)₂ CH₃ H CH₃
 373. S H CH₃ H CH₃ CH₃ H CH₃
 374. S H CH(CH₃)₂ H CH(CH₃)₂ CH₃ H CH₃
 375. S H CH₂CH₃ H CH₂CH₃ CH₃ H CH₃
 376. S H CH₂CH(CH₃)₂ H CH₂CH(CH₃)₂ CH₃ H CH₃
 377. S H CH₂C(CH₃)₃ H CH₂C(CH₃)₃ CH₃ H CH₃
 378. S H

H

CH₃ H CH₃
 379. S H CH₂CF₃ H CH₂CF₃ CH₃ H CH₃
 380. S H CH₂CH₂CF₃ H CH₂CH₂CF₃ CH₃ H CH₃
 381. S H CH₂C(CH₃)₂CF₃ H CH₂C(CH₃)₂CF₃ CH₃ H CH₃
 382. S H CD₃ H CD₃ CH₃ H CH₃
 383. S H CD(CH₃)₂ H CD(CH₃)₂ CH₃ H CH₃
 384. S H CD₂CH(CH₃)₂ H CD₂CH(CH₃)₂ CH₃ H CH₃
 385. S CH₃ H H H CH₃ F CH₃
 386. S CH(CH₃)₂ H H H CH₃ F CH₃
 387. S CH₂CH₃ H H H CH₃ F CH₃
 388. S CH₂CH(CH₃)₂ H H H CH₃ F CH₃
 389. S CH₂C(CH₃)₃ H H H CH₃ F CH₃
 390. S

H H H CH₃ F CH₃
 391. S CH₂CF₃ H H H CH₃ F CH₃
 392. S CH₂CH₂CF₃ H H H CH₃ F CH₃
 393. S CH₂C(CH₃)₂CF₃ H H H CH₃ F CH₃
 394. S CD₃ H H H CH₃ F CH₃
 395. S CD(CH₃)₂ H H H CH₃ F CH₃
 396. S CD₂CH(CH₃)₂ H H H CH₃ F CH₃
 397. S H CH₃ H H CH₃ F CH₃
 398. S H CH(CH₃)₂ H H CH₃ F CH₃
 399. S H CH₂CH₃ H H CH₃ F CH₃
 400. S H CH₂CH(CH₃)₂ H H CH₃ F CH₃
 401. S H CH₂C(CH₃)₃ H H CH₃ F CH₃
 402. S H

H H CH₃ F CH₃
 403. S H CH₂CF₃ H H CH₃ F CH₃
 404. S H CH₂CH₂CF₃ H H CH₃ F CH₃
 405. S H CH₂C(CH₃)₂CF₃ H H CH₃ F CH₃
 406. S H CD₃ H H CH₃ F CH₃
 407. S H CD(CH₃)₂ H H CH₃ F CH₃
 408. S H CD₂CH(CH₃)₂ H H CH₃ F CH₃
 409. S H H CH₃ H CH₃ F CH₃
 410. S H H CH(CH₃)₂ H CH₃ F CH₃
 411. S H H CH₂CH₃ H CH₃ F CH₃
 412. S H H CH₂CH(CH₃)₂ H CH₃ F CH₃
 413. S H H CH₂C(CH₃)₃ H CH₃ F CH₃
 414. S H H

H CH₃ F CH₃
 415. S H H CH₂CF₃ H CH₃ F CH₃
 416. S H H CH₂CH₂CF₃ H CH₃ F CH₃
 417. S H H CH₂C(CH₃)₂CF₃ H CH₃ F CH₃
 418. S H H CD₃ H CH₃ F CH₃
 419. S H H CD(CH₃)₂ H CH₃ F CH₃
 420. S H H CD₂CH(CH₃)₂ H CH₃ F CH₃
 421. S H H H CH₃ CH₃ F CH₃
 422. S H H H CH(CH₃)₂ CH₃ F CH₃
 423. S H H H CH₂CH₃ CH₃ F CH₃
 424. S H H H CH₂CH(CH₃)₂ CH₃ F CH₃
 425. S H H H CH₂C(CH₃)₃ CH₃ F CH₃
 426. S H H H

CH₃ F CH₃
 427. S H H H CH₂CF₃ CH₃ F CH₃
 428. S H H H CH₂CH₂CF₃ CH₃ F CH₃
 429. S H H H CH₂C(CH₃)₂CF₃ CH₃ F CH₃
 430. S H H H CD₃ CH₃ F CH₃
 431. S H H H CD(CH₃)₂ CH₃ F CH₃
 432. S H H H CD₂CH(CH₃)₂ CH₃ F CH₃
 433. S CH₃ CH₃ H H CH₃ F CH₃
 434. S CH(CH₃)₂ CH(CH₃)₂ H H CH₃ F CH₃
 435. S CH₂CH₃ CH₂CH₃ H H CH₃ F CH₃
 436. S CH₂CH(CH₃)₂ CH₂CH(CH₃)₂ H H CH₃ F CH₃
 437. S CH₂C(CH₃)₃ CH₂C(CH₃)₃ H H CH₃ F CH₃
 438. S

H H CH₃ F CH₃
 439. S CH₂CF₃ CH₂CF₃ H H CH₃ F CH₃
 440. S CH₂CH₂CF₃ CH₂CH₂CF₃ H H CH₃ F CH₃
 441. S CH₂C(CH₃)₂CF₃ CH₂C(CH₃)₂CF₃ H H CH₃ F CH₃
 442. S CD₃ CD₃ H H CH₃ F CH₃
 443. S CD(CH₃)₂ CD(CH₃)₂ H H CH₃ F CH₃
 444. S CD₂CH(CH₃)₂ CD₂CH(CH₃)₂ H H CH₃ F CH₃
 445. S CH₃ H CH₃ H CH₃ F CH₃
 446. S CH(CH₃)₂ H CH(CH₃)₂ H CH₃ F CH₃
 447. S CH₂CH₃ H CH₂CH₃ H CH₃ F CH₃
 448. S CH₂CH(CH₃)₂ H CH₂CH(CH₃)₂ H CH₃ F CH₃
 449. S CH₂C(CH₃)₃ H CH₂C(CH₃)₃ H CH₃ F CH₃
 450. S

H

H CH₃ F CH₃
 451. S CH₂CF₃ H CH₂CF₃ H CH₃ F CH₃
 452. S CH₂CH₂CF₃ H CH₂CH₂CF₃ H CH₃ F CH₃
 453. S CH₂C(CH₃)₂CF₃ H CH₂C(CH₃)₂CF₃ H CH₃ F CH₃
 454. S CD₃ H CD₃ H CH₃ F CH₃
 455. S CD(CH₃)₂ H CD(CH₃)₂ H CH₃ F CH₃
 456. S CD₂CH(CH₃)₂ H CD₂CH(CH₃)₂ H CH₃ F CH₃
 457. S CH₃ H H CH₃ CH₃ F CH₃
 458. S CH(CH₃)₂ H H CH(CH₃)₂ CH₃ F CH₃
 459. S CH₂CH₃ H H CH₂CH₃ CH₃ F CH₃
 460. S CH₂CH(CH₃)₂ H H CH₂CH(CH₃)₂ CH₃ F CH₃
 461. S CH₂C(CH₃)₃ H H CH₂C(CH₃)₃ CH₃ F CH₃
 462. S

H H

CH₃ F CH₃
 463. S CH₂CF₃ H H CH₂CF₃ CH₃ F CH₃
 464. S CH₂CH₂CF₃ H H CH₂CH₂CF₃ CH₃ F CH₃
 465. S CH₂C(CH₃)₂CF₃ H H CH₂C(CH₃)₂CF₃ CH₃ F CH₃
 466. S CD₃ H H CD₃ CH₃ F CH₃
 467. S CD(CH₃)₂ H H CD(CH₃)₂ CH₃ F CH₃
 468. S CD₂CH(CH₃)₂ H H CD₂CH(CH₃)₂ CH₃ F CH₃
 469. S H CH₃ H CH₃ CH₃ F CH₃
 470. S H CH(CH₃)₂ H CH(CH₃)₂ CH₃ F CH₃
 471. S H CH₂CH₃ H CH₂CH₃ CH₃ F CH₃
 472. S H CH₂CH(CH₃)₂ H CH₂CH(CH₃)₂ CH₃ F CH₃
 473. S H CH₂C(CH₃)₃ H CH₂C(CH₃)₃ CH₃ F CH₃
 474. S H

H

CH₃ F CH₃
 475. S H CH₂CF₃ H CH₂CF₃ CH₃ F CH₃
 476. S H CH₂CH₂CF₃ H CH₂CH₂CF₃ CH₃ F CH₃
 477. S H CH₂C(CH₃)₂CF₃ H CH₂C(CH₃)₂CF₃ CH₃ F CH₃
 478. S H CD₃ H CD₃ CH₃ F CH₃
 479. S H CD(CH₃)₂ H CD(CH₃)₂ CH₃ F CH₃
 480. S H CD₂CH(CH₃)₂ H CD₂CH(CH₃)₂ CH₃ F CH₃
 481. S CD₃ H H H CD₃ H H
 482. S CD(CH₃)₂ H H H CD₃ H H
 483. S CD₂CH(CH₃)₂ H H H CD₃ H H
 484. S H CD₃ H H CD₃ H H
 485. S H CD(CH₃)₂ H H CD₃ H H
 486. S H CD₂CH(CH₃)₂ H H CD₃ H H
 487. S H H CD₃ H CD₃ H H
 488. S H H CD(CH₃)₂ H CD₃ H H
 489. S H H CD₂CH(CH₃)₂ H CD₃ H H
 490. S H H H CD₃ CD₃ H H
 491. S H H H CD(CH₃)₂ CD₃ H H
 492. S H H H CD₂CH(CH₃)₂ CD₃ H H
 493. S CD₃ CD₃ H H CD₃ H H
 494. S CD(CH₃)₂ CD(CH₃)₂ H H CD₃ H H
 495. S CD₂CH(CH₃)₂ CD₂CH(CH₃)₂ H H CD₃ H H
 496. S CD₃ H CD₃ H CD₃ H H
 497. S CD(CH₃)₂ H CD(CH₃)₂ H CD₃ H H
 498. S CD₂CH(CH₃)₂ H CD₂CH(CH₃)₂ H CD₃ H H
 499. S CD₃ H H CD₃ CD₃ H H
 500. S CD(CH₃)₂ H H CD(CH₃)₂ CD₃ H H
 501. S CD₂CH(CH₃)₂ H H CD₂CH(CH₃)₂ CD₃ H H
 502. S H CD₃ H CD₃ CD₃ H H
 503. S H CD(CH₃)₂ H CD(CH₃)₂ CD₃ H H
 504. S H CD₂CH(CH₃)₂ H CD₂CH(CH₃)₂ CD₃ H H
 505. S CD₃ H H H H H CD₃
 506. S CD(CH₃)₂ H H H H H CD₃
 507. S CD₂CH(CH₃)₂ H H H H H CD₃
 508. S H CD₃ H H H H CD₃
 509. S H CD(CH₃)₂ H H H H CD₃
 510. S H CD₂CH(CH₃)₂ H H H H CD₃
 511. S H H CD₃ H H H CD₃
 512. S H H CD(CH₃)₂ H H H CD₃
 513. S H H CD₂CH(CH₃)₂ H H H CD₃
 514. S H H H CD₃ H H CD₃
 515. S H H H CD(CH₃)₂ H H CD₃
 516. S H H H CD₂CH(CH₃)₂ H H CD₃
 517. S CD₃ CD₃ H H H H CD₃
 518. S CD(CH₃)₂ CD(CH₃)₂ H H H H CD₃
 519. S CD₂CH(CH₃)₂ CD₂CH(CH₃)₂ H H H H CD₃
 520. S CD₃ H CD₃ H H H CD₃
 521. S CD(CH₃)₂ H CD(CH₃)₂ H H H CD₃
 522. S CD₂CH(CH₃)₂ H CD₂CH(CH₃)₂ H H H CD₃
 523. S CD₃ H H CD₃ H H CD₃
 524. S CD(CH₃)₂ H H CD(CH₃)₂ H H CD₃
 525. S CD₂CH(CH₃)₂ H H CD₂CH(CH₃)₂ H H CD₃
 526. S H CD₃ H CD₃ H H CD₃
 527. S H CD(CH₃)₂ H CD(CH₃)₂ H H CD₃
 528. S H CD₂CH(CH₃)₂ H CD₂CH(CH₃)₂ H H CD₃
 529. S CD₃ H H H CD₃ H CD₃
 530. S CD(CH₃)₂ H H H CD₃ H CD₃
 531. S CD₂CH(CH₃)₂ H H H CD₃ H CD₃
 532. S H CD₃ H H CD₃ H CD₃
 533. S H CD(CH₃)₂ H H CD₃ H CD₃
 534. S H CD₂CH(CH₃)₂ H H CD₃ H CD₃
 535. S H H CD₃ H CD₃ H CD₃
 536. S H H CD(CH₃)₂ H CD₃ H CD₃
 537. S H H CD₂CH(CH₃)₂ H CD₃ H CD₃
 538. S H H H CD₃ CD₃ H CD₃
 539. S H H H CD(CH₃)₂ CD₃ H CD₃
 540. S H H H CD₂CH(CH₃)₂ CD₃ H CD₃
 541. S CD₃ CD₃ H H CD₃ H CD₃
 542. S CD(CH₃)₂ CD(CH₃)₂ H H CD₃ H CD₃
 543. S CD₂CH(CH₃)₂ CD₂CH(CH₃)₂ H H CD₃ H CD₃
 544. S CD₃ H CD₃ H CD₃ H CD₃
 545. S CD(CH₃)₂ H CD(CH₃)₂ H CD₃ H CD₃
 546. S CD₂CH(CH₃)₂ H CD₂CH(CH₃)₂ H CD₃ H CD₃
 547. S CD₃ H H CD₃ CD₃ H CD₃
 548. S CD(CH₃)₂ H H CD(CH₃)₂ CD₃ H CD₃
 549. S CD₂CH(CH₃)₂ H H CD₂CH(CH₃)₂ CD₃ H CD₃
 550. S H CD₃ H CD₃ CD₃ H CD₃
 551. S H CD(CH₃)₂ H CD(CH₃)₂ CD₃ H CD₃
 552. S H CD₂CH(CH₃)₂ H CD₂CH(CH₃)₂ CD₃ H CD₃
 553. S CD₃ H H H CD₃ F CD₃
 554. S CD(CH₃)₂ H H H CD₃ F CD₃
 555. S CD₂CH(CH₃)₂ H H H CD₃ F CD₃
 556. S H CD₃ H H CD₃ F CD₃
 557. S H CD(CH₃)₂ H H CD₃ F CD₃
 558. S H CD₂CH(CH₃)₂ H H CD₃ F CD₃
 559. S H H CD₃ H CD₃ F CD₃
 560. S H H CD(CH₃)₂ H CD₃ F CD₃
 561. S H H CD₂CH(CH₃)₂ H CD₃ F CD₃
 562. S H H H CD₃ CD₃ F CD₃
 563. S H H H CD(CH₃)₂ CD₃ F CD₃
 564. S H H H CD₂CH(CH₃)₂ CD₃ F CD₃
 565. S CD₃ CD₃ H H CD₃ F CD₃
 566. S CD(CH₃)₂ CD(CH₃)₂ H H CD₃ F CD₃
 567. S CD₂CH(CH₃)₂ CD₂CH(CH₃)₂ H H CD₃ F CD₃
 568. S CD₃ H CD₃ H CD₃ F CD₃
 569. S CD(CH₃)₂ H CD(CH₃)₂ H CD₃ F CD₃
 570. S CD₂CH(CH₃)₂ H CD₂CH(CH₃)₂ H CD₃ F CD₃
 571. S CD₃ H H CD₃ CD₃ F CD₃
 572. S CD(CH₃)₂ H H CD(CH₃)₂ CD₃ F CD₃
 573. S CD₂CH(CH₃)₂ H H CD₂CH(CH₃)₂ CD₃ F CD₃
 574. S H CD₃ H CD₃ CD₃ F CD₃
 575. S H CD(CH₃)₂ H CD(CH₃)₂ CD₃ F CD₃
 576. S H CD₂CH(CH₃)₂ H CD₂CH(CH₃)₂ CD₃ F CD₃
 577. Se CH₃ H H H H H H
 578. Se CH(CH₃)₂ H H H H H H
 579. Se CH₂CH₃ H H H H H H
 580. Se CH₂CH(CH₃)₂ H H H H H H
 581. Se CH₂C(CH₃)₃ H H H H H H
 582. Se

H H H H H H
 583. Se CH₂CF₃ H H H H H H
 584. Se CH₂CH₂CF₃ H H H H H H
 585. Se CH₂C(CH₃)₂CF₃ H H H H H H
 586. Se CD₃ H H H H H H
 587. Se CD(CH₃)₂ H H H H H H
 588. Se CD₂CH(CH₃)₂ H H H H H H
 589. Se H CH₃ H H H H H
 590. Se H CH(CH₃)₂ H H H H H
 591. Se H CH₂CH₃ H H H H H
 592. Se H CH₂CH(CH₃)₂ H H H H H
 593. Se H CH₂C(CH₃)₃ H H H H H
 594. Se H

H H H H H
 595. Se H CH₂CF₃ H H H H H
 596. Se H CH₂CH₂CF₃ H H H H H
 597. Se H CH₂C(CH₃)₂CF₃ H H H H H
 598. Se H CD₃ H H H H H
 599. Se H CD(CH₃)₂ H H H H H
 600. Se H CD₂CH(CH₃)₂ H H H H H
 601. Se H H CH₃ H H H H
 602. Se H H CH(CH₃)₂ H H H H
 603. Se H H CH₂CH₃ H H H H
 604. Se H H CH₂CH(CH₃)₂ H H H H
 605. Se H H CH₂C(CH₃)₃ H H H H
 606. Se H H

H H H H
 607. Se H H CH₂CF₃ H H H H
 608. Se H H CH₂CH₂CF₃ H H H H
 609. Se H H CH₂C(CH₃)₂CF₃ H H H H
 610. Se H H CD₃ H H H H
 611. Se H H CD(CH₃)₂ H H H H
 612. Se H H CD₂CH(CH₃)₂ H H H H
 613. Se H H H CH₃ H H H
 614. Se H H H CH(CH₃)₂ H H H
 615. Se H H H CH₂CH₃ H H H
 616. Se H H H CH₂CH(CH₃)₂ H H H
 617. Se H H H CH₂C(CH₃)₃ H H H
 618. Se H H H

H H H
 619. Se H H H CH₂CF₃ H H H
 620. Se H H H CH₂CH₂CF₃ H H H
 621. Se H H H CH₂C(CH₃)₂CF₃ H H H
 622. Se H H H CD₃ H H H
 623. Se H H H CD(CH₃)₂ H H H
 624. Se H H H CD₂CH(CH₃)₂ H H H
 625. Se CH₃ CH₃ H H H H H
 626. Se CH(CH₃)₂ CH(CH₃)₂ H H H H H
 627. Se CH₂CH₃ CH₂CH₃ H H H H H
 628. Se CH₂CH(CH₃)₂ CH₂CH(CH₃)₂ H H H H H
 629. Se CH₂C(CH₃)₃ CH₂C(CH₃)₃ H H H H H
 630. Se

H H H H H
 631. Se CH₂CF₃ CH₂CF₃ H H H H H
 632. Se CH₂CH₂CF₃ CH₂CH₂CF₃ H H H H H
 633. Se CH₂C(CH₃)₂CF₃ CH₂C(CH₃)₂CF₃ H H H H H
 634. Se CD₃ CD₃ H H H H H
 635. Se CD(CH₃)₂ CD(CH₃)₂ H H H H H
 636. Se CD₂CH(CH₃)₂ CD₂CH(CH₃)₂ H H H H H
 637. Se CH₃ H CH₃ H H H H
 638. Se CH(CH₃)₂ H CH(CH₃)₂ H H H H
 639. Se CH₂CH₃ H CH₂CH₃ H H H H
 640. Se CH₂CH(CH₃)₂ H CH₂CH(CH₃)₂ H H H H
 641. Se CH₂C(CH₃)₃ H CH₂C(CH₃)₃ H H H H
 642. Se

H

H H H H
 643. Se CH₂CF₃ H CH₂CF₃ H H H H
 644. Se CH₂CH₂CF₃ H CH₂CH₂CF₃ H H H H
 645. Se CH₂C(CH₃)₂CF₃ H CH₂C(CH₃)₂CF₃ H H H H
 646. Se CD₃ H CD₃ H H H H
 647. Se CD(CH₃)₂ H CD(CH₃)₂ H H H H
 648. Se CD₂CH(CH₃)₂ H CD₂CH(CH₃)₂ H H H H
 649. Se CH₃ H H CH₃ H H H
 650. Se CH(CH₃)₂ H H CH(CH₃)₂ H H H
 651. Se CH₂CH₃ H H CH₂CH₃ H H H
 652. Se CH₂CH(CH₃)₂ H H CH₂CH(CH₃)₂ H H H
 653. Se CH₂C(CH₃)₃ H H CH₂C(CH₃)₃ H H H
 654. Se

H H

H H H
 655. Se CH₂CF₃ H H CH₂CF₃ H H H
 656. Se CH₂CH₂CF₃ H H CH₂CH₂CF₃ H H H
 657. Se CH₂C(CH₃)₂CF₃ H H CH₂C(CH₃)₂CF₃ H H H
 658. Se CD₃ H H CD₃ H H H
 659. Se CD(CH₃)₂ H H CD(CH₃)₂ H H H
 660. Se CD₂CH(CH₃)₂ H H CD₂CH(CH₃)₂ H H H
 661. Se H CH₃ H CH₃ H H H
 662. Se H CH(CH₃)₂ H CH(CH₃)₂ H H H
 663. Se H CH₂CH₃ H CH₂CH₃ H H H
 664. Se H CH₂CH(CH₃)₂ H CH₂CH(CH₃)₂ H H H
 665. Se H CH₂C(CH₃)₃ H CH₂C(CH₃)₃ H H H
 666. Se H

H

H H H
 667. Se H CH₂CF₃ H CH₂CF₃ H H H
 668. Se H CH₂CH₂CF₃ H CH₂CH₂CF₃ H H H
 669. Se H CH₂C(CH₃)₂CF₃ H CH₂C(CH₃)₂CF₃ H H H
 670. Se H CD₃ H CD₃ H H H
 671. Se H CD(CH₃)₂ H CD(CH₃)₂ H H H
 672. Se H CD₂CH(CH₃)₂ H CD₂CH(CH₃)₂ H H H
 673. Se CH₃ H H H CH₃ H H
 674. Se CH(CH₃)₂ H H H CH₃ H H
 675. Se CH₂CH₃ H H H CH₃ H H
 676. Se CH₂CH(CH₃)₂ H H H CH₃ H H
 677. Se CH₂C(CH₃)₃ H H H CH₃ H H
 678. Se

H H H CH₃ H H
 679. Se CH₂CF₃ H H H CH₃ H H
 680. Se CH₂CH₂CF₃ H H H CH₃ H H
 681. Se CH₂C(CH₃)₂CF₃ H H H CH₃ H H
 682. Se CD₃ H H H CH₃ H H
 683. Se CD(CH₃)₂ H H H CH₃ H H
 684. Se CD₂CH(CH₃)₂ H H H CH₃ H H
 685. Se H CH₃ H H CH₃ H H
 686. Se H CH(CH₃)₂ H H CH₃ H H
 687. Se H CH₂CH₃ H H CH₃ H H
 688. Se H CH₂CH(CH₃)₂ H H CH₃ H H
 689. Se H CH₂C(CH₃)₃ H H CH₃ H H
 690. Se H

H H CH₃ H H
 691. Se H CH₂CF₃ H H CH₃ H H
 692. Se H CH₂CH₂CF₃ H H CH₃ H H
 693. Se H CH₂C(CH₃)₂CF₃ H H CH₃ H H
 694. Se H CD₃ H H CH₃ H H
 695. Se H CD(CH₃)₂ H H CH₃ H H
 696. Se H CD₂CH(CH₃)₂ H H CH₃ H H
 697. Se H H CH₃ H CH₃ H H
 698. Se H H CH(CH₃)₂ H CH₃ H H
 699. Se H H CH₂CH₃ H CH₃ H H
 700. Se H H CH₂CH(CH₃)₂ H CH₃ H H
 701. Se H H CH₂C(CH₃)₃ H CH₃ H H
 702. Se H H

H CH₃ H H
 703. Se H H CH₂CF₃ H CH₃ H H
 704. Se H H CH₂CH₂CF₃ H CH₃ H H
 705. Se H H CH₂C(CH₃)₂CF₃ H CH₃ H H
 706. Se H H CD₃ H CH₃ H H
 707. Se H H CD(CH₃)₂ H CH₃ H H
 708. Se H H CD₂CH(CH₃)₂ H CH₃ H H
 709. Se H H H CH₃ CH₃ H H
 710. Se H H H CH(CH₃)₂ CH₃ H H
 711. Se H H H CH₂CH₃ CH₃ H H
 712. Se H H H CH₂CH(CH₃)₂ CH₃ H H
 713. Se H H H CH₂C(CH₃)₃ CH₃ H H
 714. Se H H H

CH₃ H H
 715. Se H H H CH₂CF₃ CH₃ H H
 716. Se H H H CH₂CH₂CF₃ CH₃ H H
 717. Se H H H CH₂C(CH₃)₂CF₃ CH₃ H H
 718. Se H H H CD₃ CH₃ H H
 719. Se H H H CD(CH₃)₂ CH₃ H H
 720. Se H H H CD₂CH(CH₃)₂ CH₃ H H
 721. Se CH₃ CH₃ H H CH₃ H H
 722. Se CH(CH₃)₂ CH(CH₃)₂ H H CH₃ H H
 723. Se CH₂CH₃ CH₂CH₃ H H CH₃ H H
 724. Se CH₂CH(CH₃)₂ CH₂CH(CH₃)₂ H H CH₃ H H
 725. Se CH₂C(CH₃)₃ CH₂C(CH₃)₃ H H CH₃ H H
 726. Se

H H CH₃ H H
 727. Se CH₂CF₃ CH₂CF₃ H H CH₃ H H
 728. Se CH₂CH₂CF₃ CH₂CH₂CF₃ H H CH₃ H H
 729. Se CH₂C(CH₃)₂CF₃ CH₂C(CH₃)₂CF₃ H H CH₃ H H
 730. Se CD₃ CD₃ H H CH₃ H H
 731. Se CD(CH₃)₂ CD(CH₃)₂ H H CH₃ H H
 732. Se CD₂CH(CH₃)₂ CD₂CH(CH₃)₂ H H CH₃ H H
 733. Se CH₃ H CH₃ H CH₃ H H
 734. Se CH(CH₃)₂ H CH(CH₃)₂ H CH₃ H H
 735. Se CH₂CH₃ H CH₂CH₃ H CH₃ H H
 736. Se CH₂CH(CH₃)₂ H CH₂CH(CH₃)₂ H CH₃ H H
 737. Se CH₂C(CH₃)₃ H CH₂C(CH₃)₃ H CH₃ H H
 738. Se

H

H CH₃ H H
 739. Se CH₂CF₃ H CH₂CF₃ H CH₃ H H
 740. Se CH₂CH₂CF₃ H CH₂CH₂CF₃ H CH₃ H H
 741. Se CH₂C(CH₃)₂CF₃ H CH₂C(CH₃)₂CF₃ H CH₃ H H
 742. Se CD₃ H CD₃ H CH₃ H H
 743. Se CD(CH₃)₂ H CD(CH₃)₂ H CH₃ H H
 744. Se CD₂CH(CH₃)₂ H CD₂CH(CH₃)₂ H CH₃ H H
 745. Se CH₃ H H CH₃ CH₃ H H
 746. Se CH(CH₃)₂ H H CH(CH₃)₂ CH₃ H H
 747. Se CH₂CH₃ H H CH₂CH₃ CH₃ H H
 748. Se CH₂CH(CH₃)₂ H H CH₂CH(CH₃)₂ CH₃ H H
 749. Se CH₂C(CH₃)₃ H H CH₂C(CH₃)₃ CH₃ H H
 750. Se

H H

CH₃ H H
 751. Se CH₂CF₃ H H CH₂CF₃ CH₃ H H
 752. Se CH₂CH₂CF₃ H H CH₂CH₂CF₃ CH₃ H H
 753. Se CH₂C(CH₃)₂CF₃ H H CH₂C(CH₃)₂CF₃ CH₃ H H
 754. Se CD₃ H H CD₃ CH₃ H H
 755. Se CD(CH₃)₂ H H CD(CH₃)₂ CH₃ H H
 756. Se CD₂CH(CH₃)₂ H H CD₂CH(CH₃)₂ CH₃ H H
 757. Se H CH₃ H CH₃ CH₃ H H
 758. Se H CH(CH₃)₂ H CH(CH₃)₂ CH₃ H H
 759. Se H CH₂CH₃ H CH₂CH₃ CH₃ H H
 760. Se H CH₂CH(CH₃)₂ H CH₂CH(CH₃)₂ CH₃ H H
 761. Se H CH₂C(CH₃)₃ H CH₂C(CH₃)₃ CH₃ H H
 762. Se H

H

CH₃ H H
 763. Se H CH₂CF₃ H CH₂CF₃ CH₃ H H
 764. Se H CH₂CH₂CF₃ H CH₂CH₂CF₃ CH₃ H H
 765. Se H CH₂C(CH₃)₂CF₃ H CH₂C(CH₃)₂CF₃ CH₃ H H
 766. Se H CD₃ H CD₃ CH₃ H H
 767. Se H CD(CH₃)₂ H CD(CH₃)₂ CH₃ H H
 768. Se H CD₂CH(CH₃)₂ H CD₂CH(CH₃)₂ CH₃ H H
 769. Se CH₃ H H H H H CH₃
 770. Se CH(CH₃)₂ H H H H H CH₃
 771. Se CH₂CH₃ H H H H H CH₃
 772. Se CH₂CH(CH₃)₂ H H H H H CH₃
 773. Se CH₂C(CH₃)₃ H H H H H CH₃
 774. Se

H H H H H CH₃
 775. Se CH₂CF₃ H H H H H CH₃
 776. Se CH₂CH₂CF₃ H H H H H CH₃
 777. Se CH₂C(CH₃)₂CF₃ H H H H H CH₃
 778. Se CD₃ H H H H H CH₃
 779. Se CD(CH₃)₂ H H H H H CH₃
 780. Se CD₂CH(CH₃)₂ H H H H H CH₃
 781. Se H CH₃ H H H H CH₃
 782. Se H CH(CH₃)₂ H H H H CH₃
 783. Se H CH₂CH₃ H H H H CH₃
 784. Se H CH₂CH(CH₃)₂ H H H H CH₃
 785. Se H CH₂C(CH₃)₃ H H H H CH₃
 786. Se H

H H H H CH₃
 787. Se H CH₂CF₃ H H H H CH₃
 788. Se H CH₂CH₂CF₃ H H H H CH₃
 789. Se H CH₂C(CH₃)₂CF₃ H H H H CH₃
 790. Se H CD₃ H H H H CH₃
 791. Se H CD(CH₃)₂ H H H H CH₃
 792. Se H CD₂CH(CH₃)₂ H H H H CH₃
 793. Se H H CH₃ H H H CH₃
 794. Se H H CH(CH₃)₂ H H H CH₃
 795. Se H H CH₂CH₃ H H H CH₃
 796. Se H H CH₂CH(CH₃)₂ H H H CH₃
 797. Se H H CH₂C(CH₃)₃ H H H CH₃
 798. Se H H

H H H CH₃
 799. Se H H CH₂CF₃ H H H CH₃
 800. Se H H CH₂CH₂CF₃ H H H CH₃
 801. Se H H CH₂C(CH₃)₂CF₃ H H H CH₃
 802. Se H H CD₃ H H H CH₃
 803. Se H H CD(CH₃)₂ H H H CH₃
 804. Se H H CD₂CH(CH₃)₂ H H H CH₃
 805. Se H H H CH₃ H H CH₃
 806. Se H H H CH(CH₃)₂ H H CH₃
 807. Se H H H CH₂CH₃ H H CH₃
 808. Se H H H CH₂CH(CH₃)₂ H H CH₃
 809. Se H H H CH₂C(CH₃)₃ H H CH₃
 810. Se H H H

H H CH₃
 811. Se H H H CH₂CF₃ H H CH₃
 812. Se H H H CH₂CH₂CF₃ H H CH₃
 813. Se H H H CH₂C(CH₃)₂CF₃ H H CH₃
 814. Se H H H CD₃ H H CH₃
 815. Se H H H CD(CH₃)₂ H H CH₃
 816. Se H H H CD₂CH(CH₃)₂ H H CH₃
 817. Se CH₃ CH₃ H H H H CH₃
 818. Se CH(CH₃)₂ CH(CH₃)₂ H H H H CH₃
 819. Se CH₂CH₃ CH₂CH₃ H H H H CH₃
 820. Se CH₂CH(CH₃)₂ CH₂CH(CH₃)₂ H H H H CH₃
 821. Se CH₂C(CH₃)₃ CH₂C(CH₃)₃ H H H H CH₃
 822. Se

H H H H CH₃
 823. Se CH₂CF₃ CH₂CF₃ H H H H CH₃
 824. Se CH₂CH₂CF₃ CH₂CH₂CF₃ H H H H CH₃
 825. Se CH₂C(CH₃)₂CF₃ CH₂C(CH₃)₂CF₃ H H H H CH₃
 826. Se CD₃ CD₃ H H H H CH₃
 827. Se CD(CH₃)₂ CD(CH₃)₂ H H H H CH₃
 828. Se CD₂CH(CH₃)₂ CD₂CH(CH₃)₂ H H H H CH₃
 829. Se CH₃ H CH₃ H H H CH₃
 830. Se CH(CH₃)₂ H CH(CH₃)₂ H H H CH₃
 831. Se CH₂CH₃ H CH₂CH₃ H H H CH₃
 832. Se CH₂CH(CH₃)₂ H CH₂CH(CH₃)₂ H H H CH₃
 833. Se CH₂C(CH₃)₃ H CH₂C(CH₃)₃ H H H CH₃
 834. Se

H

H H H CH₃
 835. Se CH₂CF₃ H CH₂CF₃ H H H CH₃
 836. Se CH₂CH₂CF₃ H CH₂CH₂CF₃ H H H CH₃
 837. Se CH₂C(CH₃)₂CF₃ H CH₂C(CH₃)₂CF₃ H H H CH₃
 838. Se CD₃ H CD₃ H H H CH₃
 839. Se CD(CH₃)₂ H CD(CH₃)₂ H H H CH₃
 840. Se CD₂CH(CH₃)₂ H CD₂CH(CH₃)₂ H H H CH₃
 841. Se CH₃ H H CH₃ H H CH₃
 842. Se CH(CH₃)₂ H H CH(CH₃)₂ H H CH₃
 843. Se CH₂CH₃ H H CH₂CH₃ H H CH₃
 844. Se CH₂CH(CH₃)₂ H H CH₂CH(CH₃)₂ H H CH₃
 845. Se CH₂C(CH₃)₃ H H CH₂C(CH₃)₃ H H CH₃
 846. Se

H H

H H CH₃
 847. Se CH₂CF₃ H H CH₂CF₃ H H CH₃
 848. Se CH₂CH₂CF₃ H H CH₂CH₂CF₃ H H CH₃
 849. Se CH₂C(CH₃)₂CF₃ H H CH₂C(CH₃)₂CF₃ H H CH₃
 850. Se CD₃ H H CD₃ H H CH₃
 851. Se CD(CH₃)₂ H H CD(CH₃)₂ H H CH₃
 852. Se CD₂CH(CH₃)₂ H H CD₂CH(CH₃)₂ H H CH₃
 853. Se H CH₃ H CH₃ H H CH₃
 854. Se H CH(CH₃)₂ H CH(CH₃)₂ H H CH₃
 855. Se H CH₂CH₃ H CH₂CH₃ H H CH₃
 856. Se H CH₂CH(CH₃)₂ H CH₂CH(CH₃)₂ H H CH₃
 857. Se H CH₂C(CH₃)₃ H CH₂C(CH₃)₃ H H CH₃
 858. Se H

H

H H CH₃
 859. Se H CH₂CF₃ H CH₂CF₃ H H CH₃
 860. Se H CH₂CH₂CF₃ H CH₂CH₂CF₃ H H CH₃
 861. Se H CH₂C(CH₃)₂CF₃ H CH₂C(CH₃)₂CF₃ H H CH₃
 862. Se H CD₃ H CD₃ H H CH₃
 863. Se H CD(CH₃)₂ H CD(CH₃)₂ H H CH₃
 864. Se H CD₂CH(CH₃)₂ H CD₂CH(CH₃)₂ H H CH₃
 865. Se CH₃ H H H CH₃ H CH₃
 866. Se CH(CH₃)₂ H H H CH₃ H CH₃
 867. Se CH₂CH₃ H H H CH₃ H CH₃
 868. Se CH₂CH(CH₃)₂ H H H CH₃ H CH₃
 869. Se CH₂C(CH₃)₃ H H H CH₃ H CH₃
 870. Se

H H H CH₃ H CH₃
 871. Se CH₂CF₃ H H H CH₃ H CH₃
 872. Se CH₂CH₂CF₃ H H H CH₃ H CH₃
 873. Se CH₂C(CH₃)₂CF₃ H H H CH₃ H CH₃
 874. Se CD₃ H H H CH₃ H CH₃
 875. Se CD(CH₃)₂ H H H CH₃ H CH₃
 876. Se CD₂CH(CH₃)₂ H H H CH₃ H CH₃
 877. Se H CH₃ H H CH₃ H CH₃
 878. Se H CH(CH₃)₂ H H CH₃ H CH₃
 879. Se H CH₂CH₃ H H CH₃ H CH₃
 880. Se H CH₂CH(CH₃)₂ H H CH₃ H CH₃
 881. Se H CH₂C(CH₃)₃ H H CH₃ H CH₃
 882. Se H

H H CH₃ H CH₃
 883. Se H CH₂CF₃ H H CH₃ H CH₃
 884. Se H CH₂CH₂CF₃ H H CH₃ H CH₃
 885. Se H CH₂C(CH₃)₂CF₃ H H CH₃ H CH₃
 886. Se H CD₃ H H CH₃ H CH₃
 887. Se H CD(CH₃)₂ H H CH₃ H CH₃
 888. Se H CD₂CH(CH₃)₂ H H CH₃ H CH₃
 889. Se H H CH₃ H CH₃ H CH₃
 890. Se H H CH(CH₃)₂ H CH₃ H CH₃
 891. Se H H CH₂CH₃ H CH₃ H CH₃
 892. Se H H CH₂CH(CH₃)₂ H CH₃ H CH₃
 893. Se H H CH₂C(CH₃)₃ H CH₃ H CH₃
 894. Se H H

H CH₃ H CH₃
 895. Se H H CH₂CF₃ H CH₃ H CH₃
 896. Se H H CH₂CH₂CF₃ H CH₃ H CH₃
 897. Se H H CH₂C(CH₃)₂CF₃ H CH₃ H CH₃
 898. Se H H CD₃ H CH₃ H CH₃
 899. Se H H CD(CH₃)₂ H CH₃ H CH₃
 900. Se H H CD₂CH(CH₃)₂ H CH₃ H CH₃
 901. Se H H H CH₃ CH₃ H CH₃
 902. Se H H H CH(CH₃)₂ CH₃ H CH₃
 903. Se H H H CH₂CH₃ CH₃ H CH₃
 904. Se H H H CH₂CH(CH₃)₂ CH₃ H CH₃
 905. Se H H H CH₂C(CH₃)₃ CH₃ H CH₃
 906. Se H H H

CH₃ H CH₃
 907. Se H H H CH₂CF₃ CH₃ H CH₃
 908. Se H H H CH₂CH₂CF₃ CH₃ H CH₃
 909. Se H H H CH₂C(CH₃)₂CF₃ CH₃ H CH₃
 910. Se H H H CD₃ CH₃ H CH₃
 911. Se H H H CD(CH₃)₂ CH₃ H CH₃
 912. Se H H H CD₂CH(CH₃)₂ CH₃ H CH₃
 913. Se CH₃ CH₃ H H CH₃ H CH₃
 914. Se CH(CH₃)₂ CH(CH₃)₂ H H CH₃ H CH₃
 915. Se CH₂CH₃ CH₂CH₃ H H CH₃ H CH₃
 916. Se CH₂CH(CH₃)₂ CH₂CH(CH₃)₂ H H CH₃ H CH₃
 917. Se CH₂C(CH₃)₃ CH₂C(CH₃)₃ H H CH₃ H CH₃
 918. Se

H H CH₃ H CH₃
 919. Se CH₂CF₃ CH₂CF₃ H H CH₃ H CH₃
 920. Se CH₂CH₂CF₃ CH₂CH₂CF₃ H H CH₃ H CH₃
 921. Se CH₂C(CH₃)₂CF₃ CH₂C(CH₃)₂CF₃ H H CH₃ H CH₃
 922. Se CD₃ CD₃ H H CH₃ H CH₃
 923. Se CD(CH₃)₂ CD(CH₃)₂ H H CH₃ H CH₃
 924. Se CD₂CH(CH₃)₂ CD₂CH(CH₃)₂ H H CH₃ H CH₃
 925. Se CH₃ H CH₃ H CH₃ H CH₃
 926. Se CH(CH₃)₂ H CH(CH₃)₂ H CH₃ H CH₃
 927. Se CH₂CH₃ H CH₂CH₃ H CH₃ H CH₃
 928. Se CH₂CH(CH₃)₂ H CH₂CH(CH₃)₂ H CH₃ H CH₃
 929. Se CH₂C(CH₃)₃ H CH₂C(CH₃)₃ H CH₃ H CH₃
 930. Se

H

H CH₃ H CH₃
 931. Se CH₂CF₃ H CH₂CF₃ H CH₃ H CH₃
 932. Se CH₂CH₂CF₃ H CH₂CH₂CF₃ H CH₃ H CH₃
 933. Se CH₂C(CH₃)₂CF₃ H CH₂C(CH₃)₂CF₃ H CH₃ H CH₃
 934. Se CD₃ H CD₃ H CH₃ H CH₃
 935. Se CD(CH₃)₂ H CD(CH₃)₂ H CH₃ H CH₃
 936. Se CD₂CH(CH₃)₂ H CD₂CH(CH₃)₂ H CH₃ H CH₃
 937. Se CH₃ H H CH₃ CH₃ H CH₃
 938. Se CH(CH₃)₂ H H CH(CH₃)₂ CH₃ H CH₃
 939. Se CH₂CH₃ H H CH₂CH₃ CH₃ H CH₃
 940. Se CH₂CH(CH₃)₂ H H CH₂CH(CH₃)₂ CH₃ H CH₃
 941. Se CH₂C(CH₃)₃ H H CH₂C(CH₃)₃ CH₃ H CH₃
 942. Se

H H

CH₃ H CH₃
 943. Se CH₂CF₃ H H CH₂CF₃ CH₃ H CH₃
 944. Se CH₂CH₂CF₃ H H CH₂CH₂CF₃ CH₃ H CH₃
 945. Se CH₂C(CH₃)₂CF₃ H H CH₂C(CH₃)₂CF₃ CH₃ H CH₃
 946. Se CD₃ H H CD₃ CH₃ H CH₃
 947. Se CD(CH₃)₂ H H CD(CH₃)₂ CH₃ H CH₃
 948. Se CD₂CH(CH₃)₂ H H CD₂CH(CH₃)₂ CH₃ H CH₃
 949. Se H CH₃ H CH₃ CH₃ H CH₃
 950. Se H CH(CH₃)₂ H CH(CH₃)₂ CH₃ H CH₃
 951. Se H CH₂CH₃ H CH₂CH₃ CH₃ H CH₃
 952. Se H CH₂CH(CH₃)₂ H CH₂CH(CH₃)₂ CH₃ H CH₃
 953. Se H CH₂C(CH₃)₃ H CH₂C(CH₃)₃ CH₃ H CH₃
 954. Se H

H

CH₃ H CH₃
 955. Se H CH₂CF₃ H CH₂CF₃ CH₃ H CH₃
 956. Se H CH₂CH₂CF₃ H CH₂CH₂CF₃ CH₃ H CH₃
 957. Se H CH₂C(CH₃)₂CF₃ H CH₂C(CH₃)₂CF₃ CH₃ H CH₃
 958. Se H CD₃ H CD₃ CH₃ H CH₃
 959. Se H CD(CH₃)₂ H CD(CH₃)₂ CH₃ H CH₃
 960. Se H CD₂CH(CH₃)₂ H CD₂CH(CH₃)₂ CH₃ H CH₃
 961. Se CH₃ H H H CH₃ F CH₃
 962. Se CH(CH₃)₂ H H H CH₃ F CH₃
 963. Se CH₂CH₃ H H H CH₃ F CH₃
 964. Se CH₂CH(CH₃)₂ H H H CH₃ F CH₃
 965. Se CH₂C(CH₃)₃ H H H CH₃ F CH₃
 966. Se

H H H CH₃ F CH₃
 967. Se CH₂CF₃ H H H CH₃ F CH₃
 968. Se CH₂CH₂CF₃ H H H CH₃ F CH₃
 969. Se CH₂C(CH₃)₂CF₃ H H H CH₃ F CH₃
 970. Se CD₃ H H H CH₃ F CH₃
 971. Se CD(CH₃)₂ H H H CH₃ F CH₃
 972. Se CD₂CH(CH₃)₂ H H H CH₃ F CH₃
 973. Se H CH₃ H H CH₃ F CH₃
 974. Se H CH(CH₃)₂ H H CH₃ F CH₃
 975. Se H CH₂CH₃ H H CH₃ F CH₃
 976. Se H CH₂CH(CH₃)₂ H H CH₃ F CH₃
 977. Se H CH₂C(CH₃)₃ H H CH₃ F CH₃
 978. Se H

H H CH₃ F CH₃
 979. Se H CH₂CF₃ H H CH₃ F CH₃
 980. Se H CH₂CH₂CF₃ H H CH₃ F CH₃
 981. Se H CH₂C(CH₃)₂CF₃ H H CH₃ F CH₃
 982. Se H CD₃ H H CH₃ F CH₃
 983. Se H CD(CH₃)₂ H H CH₃ F CH₃
 984. Se H CD₂CH(CH₃)₂ H H CH₃ F CH₃
 985. Se H H CH₃ H CH₃ F CH₃
 986. Se H H CH(CH₃)₂ H CH₃ F CH₃
 987. Se H H CH₂CH₃ H CH₃ F CH₃
 988. Se H H CH₂CH(CH₃)₂ H CH₃ F CH₃
 989. Se H H CH₂C(CH₃)₃ H CH₃ F CH₃
 990. Se H H

H CH₃ F CH₃
 991. Se H H CH₂CF₃ H CH₃ F CH₃
 992. Se H H CH₂CH₂CF₃ H CH₃ F CH₃
 993. Se H H CH₂C(CH₃)₂CF₃ H CH₃ F CH₃
 994. Se H H CD₃ H CH₃ F CH₃
 995. Se H H CD(CH₃)₂ H CH₃ F CH₃
 996. Se H H CD₂CH(CH₃)₂ H CH₃ F CH₃
 997. Se H H H CH₃ CH₃ F CH₃
 998. Se H H H CH(CH₃)₂ CH₃ F CH₃
 999. Se H H H CH₂CH₃ CH₃ F CH₃
 1000. Se H H H CH₂CH(CH₃)₂ CH₃ F CH₃
 1001. Se H H H CH₂C(CH₃)₃ CH₃ F CH₃
 1002. Se H H H

CH₃ F CH₃
 1003. Se H H H CH₂CF₃ CH₃ F CH₃
 1004. Se H H H CH₂CH₂CF₃ CH₃ F CH₃
 1005. Se H H H CH₂C(CH₃)₂CF₃ CH₃ F CH₃
 1006. Se H H H CD₃ CH₃ F CH₃
 1007. Se H H H CD(CH₃)₂ CH₃ F CH₃
 1008. Se H H H CD₂CH(CH₃)₂ CH₃ F CH₃
 1009. Se CH₃ CH₃ H H CH₃ F CH₃
 1010. Se CH(CH₃)₂ CH(CH₃)₂ H H CH₃ F CH₃
 1011. Se CH₂CH₃ CH₂CH₃ H H CH₃ F CH₃
 1012. Se CH₂CH(CH₃)₂ CH₂CH(CH₃)₂ H H CH₃ F CH₃
 1013. Se CH₂C(CH₃)₃ CH₂C(CH₃)₃ H H CH₃ F CH₃
 1014. Se

H H CH₃ F CH₃
 1015. Se CH₂CF₃ CH₂CF₃ H H CH₃ F CH₃
 1016. Se CH₂CH₂CF₃ CH₂CH₂CF₃ H H CH₃ F CH₃
 1017. Se CH₂C(CH₃)₂CF₃ CH₂C(CH₃)₂CF₃ H H CH₃ F CH₃
 1018. Se CD₃ CD₃ H H CH₃ F CH₃
 1019. Se CD(CH₃)₂ CD(CH₃)₂ H H CH₃ F CH₃
 1020. Se CD₂CH(CH₃)₂ CD₂CH(CH₃)₂ H H CH₃ F CH₃
 1021. Se CH₃ H CH₃ H CH₃ F CH₃
 1022. Se CH(CH₃)₂ H CH(CH₃)₂ H CH₃ F CH₃
 1023. Se CH₂CH₃ H CH₂CH₃ H CH₃ F CH₃
 1024. Se CH₂CH(CH₃)₂ H CH₂CH(CH₃)₂ H CH₃ F CH₃
 1025. Se CH₂C(CH₃)₃ H CH₂C(CH₃)₃ H CH₃ F CH₃
 1026. Se

H

H CH₃ F CH₃
 1027. Se CH₂CF₃ H CH₂CF₃ H CH₃ F CH₃
 1028. Se CH₂CH₂CF₃ H CH₂CH₂CF₃ H CH₃ F CH₃
 1029. Se CH₂C(CH₃)₂CF₃ H CH₂C(CH₃)₂CF₃ H CH₃ F CH₃
 1030. Se CD₃ H CD₃ H CH₃ F CH₃
 1031. Se CD(CH₃)₂ H CD(CH₃)₂ H CH₃ F CH₃
 1032. Se CD₂CH(CH₃)₂ H CD₂CH(CH₃)₂ H CH₃ F CH₃
 1033. Se CH₃ H H CH₃ CH₃ F CH₃
 1034. Se CH(CH₃)₂ H H CH(CH₃)₂ CH₃ F CH₃
 1035. Se CH₂CH₃ H H CH₂CH₃ CH₃ F CH₃
 1036. Se CH₂CH(CH₃)₂ H H CH₂CH(CH₃)₂ CH₃ F CH₃
 1037. Se CH₂C(CH₃)₃ H H CH₂C(CH₃)₃ CH₃ F CH₃
 1038. Se

H H

CH₃ F CH₃
 1039. Se CH₂CF₃ H H CH₂CF₃ CH₃ F CH₃
 1040. Se CH₂CH₂CF₃ H H CH₂CH₂CF₃ CH₃ F CH₃
 1041. Se CH₂C(CH₃)₂CF₃ H H CH₂C(CH₃)₂CF₃ CH₃ F CH₃
 1042. Se CD₃ H H CD₃ CH₃ F CH₃
 1043. Se CD(CH₃)₂ H H CD(CH₃)₂ CH₃ F CH₃
 1044. Se CD₂CH(CH₃)₂ H H CD₂CH(CH₃)₂ CH₃ F CH₃
 1045. Se H CH₃ H CH₃ CH₃ F CH₃
 1046. Se H CH(CH₃)₂ H CH(CH₃)₂ CH₃ F CH₃
 1047. Se H CH₂CH₃ H CH₂CH₃ CH₃ F CH₃
 1048. Se H CH₂CH(CH₃)₂ H CH₂CH(CH₃)₂ CH₃ F CH₃
 1049. Se H CH₂C(CH₃)₃ H CH₂C(CH₃)₃ CH₃ F CH₃
 1050. Se H

H

CH₃ F CH₃
 1051. Se H CH₂CF₃ H CH₂CF₃ CH₃ F CH₃
 1052. Se H CH₂CH₂CF₃ H CH₂CH₂CF₃ CH₃ F CH₃
 1053. Se H CH₂C(CH₃)₂CF₃ H CH₂C(CH₃)₂CF₃ CH₃ F CH₃
 1054. Se H CD₃ H CD₃ CH₃ F CH₃
 1055. Se H CD(CH₃)₂ H CD(CH₃)₂ CH₃ F CH₃
 1056. Se H CD₂CH(CH₃)₂ H CD₂CH(CH₃)₂ CH₃ F CH₃
 1057. Se CD₃ H H H CD₃ H H
 1058. Se CD(CH₃)₂ H H H CD₃ H H
 1059. Se CD₂CH(CH₃)₂ H H H CD₃ H H
 1060. Se H CD₃ H H CD₃ H H
 1061. Se H CD(CH₃)₂ H H CD₃ H H
 1062. Se H CD₂CH(CH₃)₂ H H CD₃ H H
 1063. Se H H CD₃ H CD₃ H H
 1064. Se H H CD(CH₃)₂ H CD₃ H H
 1065. Se H H CD₂CH(CH₃)₂ H CD₃ H H
 1066. Se H H H CD₃ CD₃ H H
 1067. Se H H H CD(CH₃)₂ CD₃ H H
 1068. Se H H H CD₂CH(CH₃)₂ CD₃ H H
 1069. Se CD₃ CD₃ H H CD₃ H H
 1070. Se CD(CH₃)₂ CD(CH₃)₂ H H CD₃ H H
 1071. Se CD₂CH(CH₃)₂ CD₂CH(CH₃)₂ H H CD₃ H H
 1072. Se CD₃ H CD₃ H CD₃ H H
 1073. Se CD(CH₃)₂ H CD(CH₃)₂ H CD₃ H H
 1074. Se CD₂CH(CH₃)₂ H CD₂CH(CH₃)₂ H CD₃ H H
 1075. Se CD₃ H H CD₃ CD₃ H H
 1076. Se CD(CH₃)₂ H H CD(CH₃)₂ CD₃ H H
 1077. Se CD₂CH(CH₃)₂ H H CD₂CH(CH₃)₂ CD₃ H H
 1078. Se H CD₃ H CD₃ CD₃ H H
 1079. Se H CD(CH₃)₂ H CD(CH₃)₂ CD₃ H H
 1080. Se H CD₂CH(CH₃)₂ H CD₂CH(CH₃)₂ CD₃ H H
 1081. Se CD₃ H H H H H CD₃
 1082. Se CD(CH₃)₂ H H H H H CD₃
 1083. Se CD₂CH(CH₃)₂ H H H H H CD₃
 1084. Se H CD₃ H H H H CD₃
 1085. Se H CD(CH₃)₂ H H H H CD₃
 1086. Se H CD₂CH(CH₃)₂ H H H H CD₃
 1087. Se H H CD₃ H H H CD₃
 1088. Se H H CD(CH₃)₂ H H H CD₃
 1089. Se H H CD₂CH(CH₃)₂ H H H CD₃
 1090. Se H H H CD₃ H H CD₃
 1091. Se H H H CD(CH₃)₂ H H CD₃
 1092. Se H H H CD₂CH(CH₃)₂ H H CD₃
 1093. Se CD₃ CD₃ H H H H CD₃
 1094. Se CD(CH₃)₂ CD(CH₃)₂ H H H H CD₃
 1095. Se CD₂CH(CH₃)₂ CD₂CH(CH₃)₂ H H H H CD₃
 1096. Se CD₃ H CD₃ H H H CD₃
 1097. Se CD(CH₃)₂ H CD(CH₃)₂ H H H CD₃
 1098. Se CD₂CH(CH₃)₂ H CD₂CH(CH₃)₂ H H H CD₃
 1099. Se CD₃ H H CD₃ H H CD₃
 1100. Se CD(CH₃)₂ H H CD(CH₃)₂ H H CD₃
 1101. Se CD₂CH(CH₃)₂ H H CD₂CH(CH₃)₂ H H CD₃
 1102. Se H CD₃ H CD₃ H H CD₃
 1103. Se H CD(CH₃)₂ H CD(CH₃)₂ H H CD₃
 1104. Se H CD₂CH(CH₃)₂ H CD₂CH(CH₃)₂ H H CD₃
 1105. Se CD₃ H H H CD₃ H CD₃
 1106. Se CD(CH₃)₂ H H H CD₃ H CD₃
 1107. Se CD₂CH(CH₃)₂ H H H CD₃ H CD₃
 1108. Se H CD₃ H H CD₃ H CD₃
 1109. Se H CD(CH₃)₂ H H CD₃ H CD₃
 1110. Se H CD₂CH(CH₃)₂ H H CD₃ H CD₃
 1111. Se H H CD₃ H CD₃ H CD₃
 1112. Se H H CD(CH₃)₂ H CD₃ H CD₃
 1113. Se H H CD₂CH(CH₃)₂ H CD₃ H CD₃
 1114. Se H H H CD₃ CD₃ H CD₃
 1115. Se H H H CD(CH₃)₂ CD₃ H CD₃
 1116. Se H H H CD₂CH(CH₃)₂ CD₃ H CD₃
 1117. Se CD₃ CD₃ H H CD₃ H CD₃
 1118. Se CD(CH₃)₂ CD(CH₃)₂ H H CD₃ H CD₃
 1119. Se CD₂CH(CH₃)₂ CD₂CH(CH₃)₂ H H CD₃ H CD₃
 1120. Se CD₃ H CD₃ H CD₃ H CD₃
 1121. Se CD(CH₃)₂ H CD(CH₃)₂ H CD₃ H CD₃
 1122. Se CD₂CH(CH₃)₂ H CD₂CH(CH₃)₂ H CD₃ H CD₃
 1123. Se CD₃ H H CD₃ CD₃ H CD₃
 1124. Se CD(CH₃)₂ H H CD(CH₃)₂ CD₃ H CD₃
 1125. Se CD₂CH(CH₃)₂ H H CD₂CH(CH₃)₂ CD₃ H CD₃
 1126. Se H CD₃ H CD₃ CD₃ H CD₃
 1127. Se H CD(CH₃)₂ H CD(CH₃)₂ CD₃ H CD₃
 1128. Se H CD₂CH(CH₃)₂ H CD₂CH(CH₃)₂ CD₃ H CD₃
 1129. Se CD₃ H H H CD₃ F CD₃
 1130. Se CD(CH₃)₂ H H H CD₃ F CD₃
 1131. Se CD₂CH(CH₃)₂ H H H CD₃ F CD₃
 1132. Se H CD₃ H H CD₃ F CD₃
 1133. Se H CD(CH₃)₂ H H CD₃ F CD₃
 1134. Se H CD₂CH(CH₃)₂ H H CD₃ F CD₃
 1135. Se H H CD₃ H CD₃ F CD₃
 1136. Se H H CD(CH₃)₂ H CD₃ F CD₃
 1137. Se H H CD₂CH(CH₃)₂ H CD₃ F CD₃
 1138. Se H H H CD₃ CD₃ F CD₃
 1139. Se H H H CD(CH₃)₂ CD₃ F CD₃
 1140. Se H H H CD₂CH(CH₃)₂ CD₃ F CD₃
 1141. Se CD₃ CD₃ H H CD₃ F CD₃
 1142. Se CD(CH₃)₂ CD(CH₃)₂ H H CD₃ F CD₃
 1143. Se CD₂CH(CH₃)₂ CD₂CH(CH₃)₂ H H CD₃ F CD₃
 1144. Se CD₃ H CD₃ H CD₃ F CD₃
 1145. Se CD(CH₃)₂ H CD(CH₃)₂ H CD₃ F CD₃
 1146. Se CD₂CH(CH₃)₂ H CD₂CH(CH₃)₂ H CD₃ F CD₃
 1147. Se CD₃ H H CD₃ CD₃ F CD₃
 1148. Se CD(CH₃)₂ H H CD(CH₃)₂ CD₃ F CD₃
 1149. Se CD₂CH(CH₃)₂ H H CD₂CH(CH₃)₂ CD₃ F CD₃
 1150. Se H CD₃ H CD₃ CD₃ F CD₃
 1151. Se H CD(CH₃)₂ H CD(CH₃)₂ CD₃ F CD₃
 1152. Se H CD₂CH(CH₃)₂ H CD₂CH(CH₃)₂ CD₃ F CD₃.


20. The compound of claim 19, wherein the compound is Compound x having the formula M(L_(Ai))₂(L_(Cj)); wherein x=13(i−1)+j, i is an integer from 1 to 1152, and j is an integer from 1 to 13; and wherein L_(Cj) is selected from the group consisting of: 